Space charge effects in a vacuum thermionic diode
Temperature effects on thermionic diode with space charge model including emitter and accumulator electrode emissions
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Temperature effects on thermionic diode with space charge model including emitter and accumulator electrode emissions
The work done to fabricate Marchuk plasma discharge tubes for measurement of the cesiated emission of lanthanum hexaboride and thoriated tungsten electrodes is described. A photon counting pyrometer was completed and is to be calibrated with a gold standard.
Energy-efficient and sustainable technologies are necessary to lower energy and carbon footprints. Many technologies are being pursued to meet the increasing energy demand in buildings. An attractive option is efficient utilization of available energy resources, including renewables, to support current and future building energy needs while targeting grid resiliency, energy, and environmental security at an affordable cost via on-site cogeneration-based approaches. This must include energy-efficient technologies with lower greenhouse gas emissions and optimized cost, performance, and reliability. This paper presents the economic and environmental benefits associated with power technologies such as thermionics and solid oxide fuel cells. Hybrid configurations consisting of heat pumps, power systems, and renewable photovoltaics in cogeneration and trigeneration modes of operation are presented. The role of such technologies in lowering CO2 emissions while improving energy resiliency and serving the needs of underprivileged communities is discussed. The key barriers of affordability and potential solutions for large-scale implementation of these promising technologies are reviewed. Case studies demonstrating the influence of power rating, electrical efficiency, design configuration, carbon dioxide intensity of the grid, and fuel on annual greenhouse gas emissions are presented for residential and commercial buildings.
Preignition volt-ampere curves for thermionic cesium diodes exhibiting nonsaturation characteristics under low temperature and electron-rich emission conditions
Although considerable interest has been shown in the space-charge analysis of low-pressure (collisionless case) thermionic diodes, there is a conspicuous lack in the presentation of results in a way that allows direct comparison with experiment. The current-voltage curve of this report was, therefore, computed for a typical case within the realm of experimental interest. The model employed in this computation is shown in Fig. 1 and is defined by the limiting potential distributions [curves (a) and (b)]. Curve (a) represents the potential V as a monotonic function of position with a slope of zero at the anode; curve (b) is similarly monotonic with a slope of zero at the cathode. It is assumed that by a continuous variation of the anode voltage, the potential distributions vary continuously from one limiting form to the other. Although solutions for infinitely spaced electrodes show that spatically oscillatory potential distributions may exist, they have been neglected in this computation.
Current out-of-core emphases allow converter material and design freedoms previously prohibited by in-core nucleonic and geometric restrictions. As a result, potential improvements indicate possibilities for severalfold increases in efficiencies. The new TEC-ART program concentrated initially on low-work function collectors and interelectrode-loss reduction and revealed much in a short time. This new emission capability coupled with improved collectors that maintain performance with emitter-vapor deposit accumulations are requisites for efficient, enduring thermionic converters.
A power-efficient, miniature, easily manufactured, reservoir-type barium-dispenser thermionic cathode has been developed that offers the significant advantages of simultaneous high electron-emission current density (>2 A/sq cm) and very long life (>100,000 hr of continuous operation) when compared with the commonly used impregnated-type barium-dispenser cathodes. Important applications of this cathode are a wide variety of microwave and millimeter-wave vacuum electronic devices, where high output power and reliability (long life) are essential. We also expect it to enable the practical development of higher purveyance electron guns for lower voltage and more reliable device operation. The low cathode heater power and reduced size and mass are expected to be particularly beneficial in traveling-wave-tube amplifiers (TWTA's) for space communications, where future NASA mission requirements include smaller onboard spacecraft systems, higher data transmission rates (high frequency and output power) and greater electrical efficiency.
Converter's collector electrode has uniform low work-function surface and operates at sufficiently low temperature to produce negligible electron emission. Emitter electrode has main region which has intermediate work-function and auxiliary region which has relatively high work-function surface.
The NASA applied research and technology (ART) program for thermionic energy conversion (TEC) is progressing effectively. Current out-of-core emphases allow converter material and design freedoms previously prohibited by in-core nucleonic and geometric restrictions. As a result, potential improvements indicate possibilities for severalfold increases in efficiencies. The new TEC-ART program concentrated initially on low-work-function collectors and interelectrode-loss reduction and revealed much in a short time. For example, arc-drop studies verified the necessity of stable emitters that operate well with little or no adsorbed cesium. This new emission capability coupled with improved collectors that maintain performance with emitter-vapor deposit accumulations are requisites for efficient, enduring thermionic converters. The accomplishments and contributors in these areas are discussed.
Work performed on this contract was primarily for the evaluation of selected electrode materials for thermionic energy converters. The original objective was to characterize selected nickel based superalloys up to temperatures of 1400 K. It was found that an early selection, Inconel 800 produced a high vapor pressure which interfered with the vacuum emission measurements. The program then shifted to two other areas. The first area was to obtain emission from the superalloys in a cesiated atmosphere. The cesium plasma helps to suppress the vaporization interference. The second area involved characterization of the Lanthanum-Boron series as thermionic emitters. These final two areas resulted in three journal publications which are attached to this report.
This paper presents evaluation of a variety of thermionic converter configurations to obtain improved efficiency. A variable-spacing diode using an iridium emitter gave emission properties comparable to platinum, but the power output from a sintered LaB6 collector diode was not consistent with its work function. Reflectivities above 0.5 were measured at thermal energies on oxygenated-cesiated surfaces using a field emission retarding potential gun. Performance of converters with structured electrodes and the characteristics of a pulsed triode were studied as a function of emitter, collector, cesium reservoir, interelectrode spacing, xenon pressure, and pulsing parameters.
Femtosecond (fs) laser-based 4D ultrafast electron microscopy (UEM) commonly makes use of photoelectron emission from a source material in the electron gun region of an otherwise conventional TEM. For TEMs equipped with thermionic guns, the source material is often LaB 6 , the same as used for thermionic operation. Here, such thermionic-based UEMs have proven useful for applications requiring large electron fluxes (i.e., high beam currents) often at the expense of beam coherence and brightness, which is especially important for single-shot nanosecond applications. Importantly, for fs-based UEMs, beam currents can be controlled over a broad range of parameter space through the properties of the fs laser and the photon pulses produced therefrom.
NASA LeRC has a broad, active cathode technology development program in which both experimental and theoretical studies are being employed to further development of thermionic cathodes for use as electron sources in vacuum devices for communications and other space applications. One important type of thermionic cathode under development is the alkaline-earth oxide-coated (BaO, SrO, CaO) cathode. Significant improvements in the emission characteristics of this cathode have been obtained through modification of the chemical composition and morphology of the oxide coating, with the best result thus far coming from the addition of In2O3 and Sc2O3. Whereas the In2O3 produces a finer, more uniform particle structure, the exact chemical state and role of the Sc2O3 in the emission enhancement is unknown. The purpose of this cooperative agreement is to combine the studies of the surface chemistry and electron emission at NASA LeRC of chemically modified oxide coatings with a study of the thermochemistry and crystal structure using X-ray diffraction equipment and expertise at Clark Atlanta University (CAU). The study at CAU is intended to provide the description and understanding of the structure and thermochemistry needed for further improvement and optimization of the modified coatings. A description of the experimental procedure, preliminary X-ray diffraction test results, together with the design of an ultrahigh vacuum chamber necessary for high temperature thermochemistry studies will be presented.
This project has characterized the bulk emission properties of carbon nanotube (CNT) forest cathodes fabricated with varied geometries. The overall goal of the project has been to evaluate CNT forest cathodes as a potential replacement for thermionic cathodes currently used in accelerator systems.
Prospective missions requiring large power supplies that might be satisfied with space nuclear reactors (SNR) are discussed, along with design concepts and problems and other potential high-power space systems. Having a minimum economic output of 10 kWe, SNR seem well-suited as the power sources for DBS systems, space-based ATC systems manned planetary missions, an expanding Space Station, materials processing, and outer planets missions. SNR avoid the large area problems of solar cell arrays, short lifetimes of thermionic converters, and vibration and heat control in Stirling engines. Design problems exist for SNR in the heat transfer and rejection systems, radioactive emissions and degradation of reactor materials, and size. The latter is a function of Shuttle payload constaints and raises the possibility of having to load the fuel while in orbit. The earliest operational date of SNRs is projected for the early 1990s, if progress is good in the current SP-100 program.
Improved reservoir cathode serves as intense source of electrons required for high-frequency and often high-output-power, linear-beam tubes, for which long operating lifetime important consideration. High emission-current densities obtained through use of emitting surface of relatively-low effective work function and narrow work-function distribution, consisting of coat of W/Os deposited by sputtering. Lower operating temperatures and enhanced electron emission consequently possible.
Experiments conducted on the ATS 5 and ATS 6 which have demonstrated the feasibility of modifying or clamping the environmentally induced potential of these spacecraft are described. The results of these experiments indicate that a thermionic electron source is capable of replacing photo-emitted electrons during eclipse. However, the utility of this type of device is limited if its emission is suppressed by local electric fields. On the other hand, it is shown that a plasma source will not only serve as a substitute for photo-emitted electrons but will also suppress differential charging of isolated elements of the spacecraft which would tend to suppress electron emission. This later device is therefore capable of clamping the potential of a spacecraft without special considerations of its coupling to the ambient plasma.
Auger spectroscopy has been used to evaluate the properties of 'good' and 'poor' impregnated tungsten cathodes used in high-power microwave wave tubes. The results were interpreted to analyze failure modes in cathodes removed from TWT's because of poor emission characteristics. Most of the poor cathodes evaluated in this program were obtained from fabricated electron guns that had been employed and discarded from the 200-W TWT tubes developed for the Communication Technology Satellite program. The results of these measurements have shown there are at least two types of failure modes that one observes with poor cathodes. They are (1) chemical contamination of the cathode surface and (2) low partial layer barium coverage of the cathode surface.