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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Updates to a Preliminary Probabilistic Performance Assessment Model for Radiological and Chemical Contamination at the West Valley Site, New York - 20420

The New York State Energy Research and Development Authority (NYSERDA) is the owner of the Western New York Nuclear Service Center (WNYNSC), a 1,351-ha site located approximately 48 km south of Buffalo, New York. In 1962, Nuclear Fuel Services, Inc. (NFS) entered into agreements with the Atomic Energy Commission and New York State to construct the first commercial reprocessing plant of nuclear fuel in the United States at the WNYNSC. NFS built and operated the spent fuel reprocessing plant and waste disposal facilities, processing 640 Mg (640 metric tons) of spent nuclear fuel from 1966 to 1972 under an Atomic Energy Commission license. Nuclear fuel reprocessing operations halted in 1972 and never restarted, leaving behind radioactive and chemical wastes. The U.S. Department of Energy (DOE) was required to complete certain waste management activities under the West Valley Demonstration Project (WVDP) Act of 1980 including decommissioning of WVDP facilities. As collaborating agencies, NYSERDA and the DOE are tasked with making decisions about decommissioning and risk reduction for the West Valley Site. Neptune and Company, Inc. (Neptune) was contracted to develop a probabilistic performance assessment (PPA) model to assist the agencies in their decision making process for decommissioning the WVDP and WNYNSC. One important tool that is needed in order to inform the decision-making process is a science-based model of the West Valley Site that evaluates potential future consequences for human health and the environment. This forms the core of the spatial domain of the West Valley PPA Model. The PPA Model, developed using the GoldSim system modeling software, is a tool intended to provide support for decision making that evaluates uncertainty, in a manner that is transparent, defensible, and robust. The PPA Model includes contaminant transport and health effects components, and is organized around geographically-grouped contaminated facilities. These include the waste disposal areas licensed by the U.S. Nuclear Regulatory Commission and the State of New York, a waste tank farm for storage of high level radioactive waste resulting from reprocessing operations, and several areas contaminated with radioactive and chemical constituents. The PPA Model evaluates contaminant transport from these sources to points of exposure across the site and into receiving surface waters and sediments. Hypothetical people and wildlife could be exposed to contamination at these locations, and the effects of these exposures are evaluated. Contaminant transport processes to be evaluated in the PPA Model include groundwater and surface water transport, contaminant translocation by plants and animals, diffusion, and erosion. The evaluation of exposures to people in this preliminary model is limited to a resident farmer scenario, and ecological assessment is performed at the level of a screening analysis. The results of these preliminary evaluations inform future model developments. PPA Model results are subjected to sensitivity analysis in order to determine those pathways and parameters that are most significant in influencing the results. This information allows analysts and decision makers to focus on those aspects of Site behavior and processes. With this information, the decision makers can drive informed, defensible decisions regarding decommissioning of the Site. This paper includes an update of the information presented at WM2019 [1]. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

California Trees Seasonally Use Augmented Water Sources: Water Isotope Tracking in a Groundwater‐Dependent Ecosystem

Sustainable groundwater management must account for the needs of groundwater dependent ecosystems. To understand the relationship of ecosystems and seasonal water use, we studied the stable isotope composition (δ 18 O and δ 2 H) of water in streamside trees in a semi-arid streamside environment (Livermore, California, USA). We sampled seven trees at two sites every other month from April 2024 through April 2025 for tree xylem stable water isotope signatures. These data were compared to potential source waters: precipitation, imported surface water, soil water and regional groundwaters. Large daily precipitation events were found to be isotopically similar to regional groundwater and were thus treated as one water source. A Bayesian mixing model using stable water isotopes was used to determine the ratios of these three potential source waters (small daily precipitation events, groundwater/large daily precipitation events and imported water) present in tree xylem water. On average, tree water sources include 32% imported water (SD = 9%), 35% small daily precipitation events (SD = 10%) and 33% groundwater (SD = 3%), with significant seasonal variation (t summer-winter = 30.8, p < 0.01), particularly drawing more imported water (more than 55%) in the summer. While small daily precipitation events contribute only 10% of the total precipitation in our dataset, it represents a third of water used by trees. In addition, while these ecosystems are designated as groundwater dependent ecosystems, the trees use approximately one third imported water and even more during dry summer months. This approach provides water managers with a practical tool for quantifying ecosystem water needs, supporting data-driven decisions and regulatory compliance. While California's Sustainable Groundwater Management Act emphasizes supporting groundwater dependent ecosystems, it allows flexibility in demonstrating benefits. In conclusion, our methodology provides a way to document that management actions (such as managed aquifer recharge with imported water) deliver measurable co-benefits to GDEs.

Geosciences↗
DOE OSTI2021

Membrane-Confined Iron Oxychloride Nanocatalysts for Highly Efficient Heterogeneous Fenton Water Treatment

Heterogeneous advanced oxidation processes (AOPs) allow for the destruction of aqueous organic pollutants via oxidation by hydroxyl radicals ( • OH). However, practical treatment scenarios suffer from the low availability of short-lived • OH in aqueous bulk, due to both mass transfer limitations and quenching by water constituents, such as natural organic matter (NOM). In this work, we overcome these challenges by loading iron oxychloride catalysts within the pores of a ceramic ultrafiltration membrane, resulting in an internal heterogeneous Fenton reaction that can degrade organics in complex water matrices with pH up to 6.2. With • OH confined inside the nanopores (~ 20 nm), this membrane reactor completely removed various organic pollutants with water fluxes of up to 100 L m –2 h –1 (equivalent to a retention time of 10 s). This membrane, with a pore size that excludes NOM (>300 kDa), selectively exposed smaller organics to •OH within the pores under confinement and showed excellent resiliency to representative water matrices (simulated surface water and sand filtration effluent samples). Moreover, the membrane exhibited sustained AOPs (>24 h) and could be regenerated for multiple cycles. Our results suggest the feasibility of exploiting ultrafiltration membrane-based AOP platforms for organic pollutant degradation in complex water scenarios.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Delineation of endorheic drainage basins in the MERIT-Plus dataset for 5 and 15 minute upscaled river networks

Abstract The MERIT-Hydro networks re-gridded by the Iterative Hydrography Upscaling (IHU) algorithm do not retain exo- or endorheic basin attributes from the original data. Here we developed methods to assign such attributes to those and any other digital river networks. The motivation is that endorheic inland drainage basins are essential for hydrologic modelling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. First, we create basin attributes that explicitly label endorheic and exorheic catchments by the criteria of direct or hidden connectivity to the ocean without changing their flow direction grid. In the second step we alter the delineation of endorheic basins by the merging algorithm that eliminates small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion and topology of the inland basins. The data was validated using the Water Balance Model by comparing volume of endorheic inland depressions with modelled water accumulation in their inland lakes.

58 GEOSCIENCES↗
DOE OSTI2020

GCAM v4.3 SSP-RCP-GCM Output Products

Supplemental dataset to: Graham N.T., M.I. Hejazi, M. Chen, E. Davies, J.A. Edmonds, S.H. Kim, and S. Turner, et al. 2020. "Humans drive future water scarcity changes across all Shared Socioeconomic Pathways." Environmental Research Letters 15, no. 1:Article No. 014007. PNNL-SA-151297. doi:10.1088/1748-9326/ab639b This analysis makes deterministic classifications of how, when water resources are limited and constrained, the human and climate systems interact. The relative effects of both systems on water scarcity are quantified at global and basin scales across 15 global futures that include five different socioeconomic conditions (the Shared Socioeconomic Pathways, SSPs) and four different climatic conditions (the Representative Concentration Pathways, RCPs). These 15 scenarios are used to first analyze a 'Human Alone' component by isolating the human impact on future scarcity. This is accomplished by holding all climate variables to their 2005 levels while altering socioeconomic growth and technological change. General circulation model (GCM) derived climate impacts for five models are applied to establish 75 'Human and Climate' scenarios which allows for the quantification of climate impacts. Climatic impacts to water supply, agricultural productivity and change, hydropower availability, and building energy demands are applied from 5 different bias-corrected GCMs to make a suite of 75 climate runs. By subtracting the human derived impacts from the 'Human Alone' scenarios, from the 'Human and Climate' scenarios the climate impact is isolated. First, the drivers of future water scarcity are evaluated by isolating the impacts that both humans and climate have while accounting for feedbacks between humans, energy, and land. Secondly, the simultaneous impacts that human and climate systems have on water scarcity are analyzed by determining whether each system is increasing or decreasing scarcity in all global water basins. Below we describe the GCAM model, the scenario components, climate derived impacts, and the calculations of scarcity changes and attribution. This study uses the global change assessment model (GCAM), with inclusions of water constraints to both renewable and nonrenewable sources of water, to investigate the relative contributions of climate and human systems on water scarcity regionally and globally under a wide range of scenarios. GCAM links socioeconomics, the energy system, land-use change, climate, and the water sector. GCAM is a market-equilibrium model that allows for prices to be adjusted within each time step to ensure that the supply and demand of goods and services remains equilibrated at each time step allowing for simultaneous market clearing across sectors. This study accounts for a limited supply of water by employing cost resource curves across all 235 basins that follow a logit formulation to determine the share of each water source (renewable surface water, nonrenewable groundwater, and desalinated water) needed to meet the water demands within all basins. As depletion of various water sources increases the extraction price increases, which leads to compounding price increases on the goods and services that require higher-priced water sources.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2022

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗
DOE OSTI2023

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗
DOE OSTI2023

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗
DOE OSTI2023

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗
DOE OSTI2020

HarDWR - Raw Water Rights Records

A dataset within the Harmonized Database of Western U.S. Water Rights (HarDWR). For a detailed description of the database, please see the meta-record v2.0. Changelog v2.0 - Switched source data from collecting records from each state independently to using the WestDAAT dataset v1.0 - Initial public release Description In order to hold a water right in the western United States, an entity, (e.g., an individual, corporation, municipality, sovereign government, or non-profit) must register a physical document with the state's water regulatory agency. State water agencies each maintain their own database containing all registered water right documents within the state, along with relevant metadata such as the point of diversion and place of use of the water. All western U.S. states have digitized their individual water rights databases, as well as geospatial data defining the areas in which water rights are managed. Each state maintains and provides their own water rights data in accordance with individual state regulations and standards. In addition, while all states make their water rights publicly available, each provides their records in unique formats, meaning that file types, field availability, and terms vary from state to state. This leads to additional challenges to managing resources which cross state lines, or conducting consistent multi-state water analyses. For the first version of HarDWR, we collected the water rights databases from 11 Western States of the United States. In order to preform regional analyses with the collected data, the raw records had to be harmonized into one single format. The Water Data Exchange (WaDE) is a program dedicated to the sharing of water-related data for the Western U.S. in a singular consistent format. Created by the Western States Water Council (WSWC) to facilitate the collection and dissemination of water data among WSWC's member states and the public, WaDE provides an important service for those interested in water resource planning and management in their focus region. Of the services which WaDE provides, the one of the most interesting is the WestDAAT dataset, which is a collection of water rights data provided by the 18 WSWC member states that have been standardized into a single format, much like we had done on a more limited scale with HarDWR v1. For this version of HarDWR we decided to use WestDAAT, specifically a snapshot created in Feburary 2024, as our water rights source data. A full explanation of the benefits gained from this switch can be found in the description of the updated Harmonized Water Rights Records v2.0, but in short it has allowed us to focus more of our efforts on answering research questions and gaining a more realistic understanding of how water rights are allocated. For more information on how the data for WestDAAT was collected, please see the WaDE data summary. Terms of Use While WaDE works directly with the state agencies to collect and standardize the water rights records, the ultimate authority for the water rights data remains the individual states. Each state, and their respective water right authorities, have made their water right records available for non-commercial reference uses. In addition, the states make no guarantees as to the completeness, accuracy, or timeliness of their respective databases, let alone the modifications which we, the authors of this paper, have made to the collected records. None of the states should be held liable for using this data outside of its intended use. As several of the states update their water rights databases daily, the information provided here is not the latest possible, and should not be used for legal purposes. WestDAAT itself has irregular updates. Additional questions about the data the source states provided should be directed to the respective state agencies (see methods.csv and organization.csv files described below). In addition, although data was presented here was not collected directly from the states, several states requested specifically worked disclaimers when sharing their data. These disclaimers are included here as an acknowledgement from where the water rights data is primarily sourced. Colorado: "The data made available here has been modified for use from its original source, which is the State of Colorado. THE STATE OF COLORADO MAKES NO REPRESENTATIONS OR WARRANTY AS TO THE COMPLETENESS, ACCURACY, TIMELINESS, OR CONTENT OF ANY DATA MADE AVAILABLE THROUGH THIS SITE. THE STATE OF COLORADO EXPRESSLY DISCLAIMS ALL WARRANTIES, WHETHER EXPRESS OR IMPLIED, INCLUDING ANY IMPLIED WARRANTIES OF MERCHANTABILITY, OR FITNESS FOR A PARTICULAR PURPOSE. The data is subject to change as modifications and updates are complete. It is understood that the information contained in the Web feed is being used at one's own risk." Montana: "The Montana State Library provides this product/service for informational purposes only. The Library did not produce it for, nor is it suitable for legal, engineering, or surveying purposes. Consumers of this information should review or consult the primary data and information sources to ascertain the viability of the information for their purposes. The Library provides these data in good faith but does not represent or warrant its accuracy, adequacy, or completeness. In no event shall the Library be liable for any incorrect results or analysis; any direct, indirect, special, or consequential damages to any party; or any lost profits arising out of or in connection with the use or the inability to use the data or the services provided. The Library makes these data and services available as a convenience to the public, and for no other purpose. The Library reserves the right to change or revise published data and/or services at any time." Oregon: "This product is for informational purposes and may not have been prepared for, or be suitable for legal, engineering, or surveying purposes. Users of this information should review or consult the primary data and information sources to ascertain the usability of the information." File Descriptions The unmodified February, 2024 WestDAAT snapshot is composed of nine files. Below is a brief description of each file, as well as how they were utilized for HarDWR. WaDEDataDictionaryTerms.xlsx: As the file's name implies, this is a data dictionary for all of the below named files. This file describes the column names for each of the following files, with the exception of citation.txt which does not have any columns. The descriptions for each file are divided by tab,with the same name as their associated file, within this document. allocationamount.csv: The "main" file of the group, it contains the water right records for each state. Of particular note, each water right is broken down into one or more water allocations. Allocations may be withdrawn from one or more locations, or even multiple allocations associated with a particular location. This is a more subtle and realistic representation of how water is used than what was available in the first version of HarDWR. For the records from some states, this can mean that multiple allocations listed under a single right will appear as rows within this file. citation.txt: A combination of contact information for WaDE personnel, disclaimer about how the data should be used, and guidelines for citing WestDAAT. methods.csv: A file describing the source and method by which WaDE collected water rights data from each state. organization.csv: A file listing the water rights authoritative agencies for each state. sites.csv: This file provides the geographic, and other descriptors, of the physical location of allocations, called 'sites'. To reiterate, it is possible for one allocation to be associated with multiple sites, as well as one site to be associated with multiple allocations. The two descriptors which we were most interested in where the site's coordinates, as well as whether the site was classified as a Point of Diversion (POD) or a Place of Use (POU). As a general rule, PODs are geographic points, while POUs are areas typically represented as property boundaries or irregularly shaped polygons. sites_pouGeometry.csv: For those allocations with a POU site, this file contains the defining points for the associated polygons. variables.csv: A file describing the units in which an allocation's water amount is reported within WestDAAT. This information is essentially a repeat of the 'AllocationFlow_CFS' and 'AllocationVolume_AF' columns within allocationamount.csv, at least for our purposes. watersources: This file describes the source of water from which each site extracts from. For our purposes, this table was used to determine whether the water came from Surface Water, Groundwater, or Unspecified Water.

Lisk, Matthew↗
DOE OSTI2023

Stable water isotopes and tritium data from porewater at Elkhorn Slough

Salt marshes are dynamic hydrologic systems where terrestrial groundwater, terrestrial surface water, and seawater mix due to bi-directional flows and pressure gradients. Due to the counteracting terrestrial and marine forcings that control these environments, we do not comprehensively understand water fluxes in these complex coastal systems. To understand the water sources, flow directions, and velocities in salt marsh porewater, we collected geochemical tracers across a hillslope-to-salt marsh continuum in a salt marsh experiencing daily inundation of estuarine surface water (SW) from tides and mixing of fresh seasonal groundwater. The experimental transect is located at the Elkhorn Slough National Estuarine Research Reserve.Here we present a data table (.csv) with the results of electrical conductivity, stable water isotopes, and tritium in porewater across several elevations in the hillslope-to-salt marsh continuum (information in the data set). We analyzed the stable water isotope samples by cavity ring-down spectroscopy in a Picarro L2130-i at the University of California Santa Cruz (accuracy of 0.025‰ and 0.1‰ for δ18O and δ2H, respectively). We measured the electric conductivity of the samples with an Orion Star™ A329 multiparameter meter (0.5% accuracy, Thermo Fisher Scientific, Massachusetts, USA). We analyzed 3H samples at Lawrence Livermore National Laboratory by helium-3 accumulation (Clarke et al., 1976; Surano et al., 1992).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Flow Directions and Ages of Subsurface Water in a Salt Marsh System Constrained by Isotope Tracing

Salt marshes are dynamic hydrologic systems where terrestrial groundwater, terrestrial surface water, and seawater mix due to bi-directional flows and pressure gradients. Due to the counteracting terrestrial and marine forcings that control these environments, we do not comprehensively understand water fluxes in these complex coastal systems. To understand the water sources, flow directions, and velocities in salt marsh porewater, we employed a combination of geochemical tracers and analytical models across a hillslope-to-salt marsh continuum in a salt marsh experiencing daily inundation of estuarine surface water (SW) from tides and mixing of fresh seasonal groundwater. We used tritium ( 3 H) as a hydrologic tracer to assess porewater ages and stable water isotope ($\delta$ 2 H and $\delta$ 18 O) analyses to separate isotopically distinct estuarine and terrestrial groundwater across different depths and landscape positions in the study transect. We employed electrical conductivity to constrain the role of source mixing and evapotranspiration in salt marsh hydrology. Salinity and stable isotopes revealed that transpiration, rather than evaporation, increased subsurface water salinity to concentrations above estuarine SW during summer. Elevated salinity at depth indicated that salt marsh subsurface water is recharged during the dry growing season. Seasonal recharge patterns drive long-term deep subsurface water dynamics across the salt marsh, with 3 H ages of 3–7 years, and daily tidal cycles drive short-term shallow porewater dynamics with 3 H ages of 0 ± 3.6 years. Furthermore, our conceptual understanding of the spatiotemporal changes in SW-subsurface water interactions at the terrestrial-marine interface quantifies the hydrological constraints we are missing to improve our understanding of biogeochemical cycles within the salt marsh.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Use of Stable Mercury Isotopes to Assess Mercury and Methylmercury Transformation and Transport across Critical Interfaces from the Molecular to the Watershed Scale (Final Report)

This project titled “Use of Stable Mercury Isotopes to Assess Mercury and Methylmercury Transformation and Transport across Critical Interfaces from the Molecular to the Watershed Scale” represents a collaborative effort between the University of Michigan (Jason Demers, PI) and Oak Ridge National Laboratory (Scott Brooks, co-I). Much has been learned about mercury (Hg) cycling in stream ecosystems, and East Fork Poplar Creek (EFPC) in particular, through decades of previous research. Nevertheless, some of the most fundamental questions regarding the sources of bioavailable Hg and its transformation to toxic methylmercury (MeHg) have remained unanswered. These fundamental questions include: (1) what are the sources and biogeochemical processes that lead to the input of dissolved Hg to stream water across critical subsurface interfaces within stream ecosystems, and EFPC in particular? and (2) what are the sources and biogeochemical processes that control the production and fate of bioaccumulative MeHg within stream ecosystems, and in EFPC in particular? To address these fundamental questions, our project aimed to couple laboratory experiments and field observations, both utilizing natural abundance Hg stable isotope techniques, to identify the processes responsible for generating mobile, bioavailable dissolved Hg from recalcitrant legacy sources within critical subsurface zones (e.g., streambed hyporheic zone, riparian floodplain subsurface). We used the isotopic signature of this bioavailable dissolved Hg to track its mobilization across these critical interfaces in order to link diffuse subsurface sources of dissolved Hg with increases in surface water dissolved Hg flux measured at the watershed scale. Additionally, our research aimed to determine the isotopic composition of MeHg within these same critical subsurface zones. We directly assessed the isotopic composition of MeHg within biota in order to gain insight into which subsurface sources of inorganic Hg and toxic MeHg are available for bioaccumulation within the EFPC ecosystem. Net fluxes of dissolved Hg along the flow path of EFPC were shown to vary spatially and temporally. In the Upper EFPC, within the Y12 boundary, stream water flux of dissolved Hg consistently decreased between the outfall and the downstream boundary of Y12 (57% ± 29%, 1SD). Within the Upper EFPC, an assessment of Hg isotopic composition suggested that losses were strongly reaction-driven, although isotopic diagnostics did not conform to any known processes. Downstream of Y12, in the upper reach of the Lower EFPC, dissolved Hg fluxes tended to increase during the dormant season (net gain of 11-120%), and decrease during the growing season (net loss of 23% +/- 18%, 1SD). In the downstream-most reach of Lower EFPC, dissolved Hg fluxes increased by 12-108% in 9 out of 10 monthly assessments. Overall, diffuse fluxes from the non-Y12 watershed accounted for 34% (+/- 17%, 1SD) of all dissolved Hg exported during base flow. Within Lower EFPC, an assessment of Hg isotopic composition was consistent with the contribution of diffuse Hg inputs from high-concentration hotspots within riparian floodplains and streambed hyporheic pore water. To investigate remobilization of recalcitrant Hg from legacy sediment sources, we developed procedures that coupled isotopic analysis with sequential extractions of streambed sediment. We found that the proportion of weakly-bound Hg within EFPC streambed sediment was relatively small, but could still account for a large proportion of the annual flux of dissolved Hg from EFPC. These sequential extractions also showed that this weakly-bound Hg fraction could be replenished from the much larger fraction of recalcitrant Hg in sediment. The isotopic composition of these weakly-bound and remobilized recalcitrant Hg fractions within the sediment was consistent with high-concentration dissolved Hg hotspots within hyporheic pore water. Thus, this research provided novel evidence that legacy mercury sources within streambed sediment could provide an ongoing contribution of dissolved Hg to surface waters. Finally, we developed new methods for the direct determination of the MeHg isotopic composition of organisms, which allowed a more direct evaluation of inorganic Hg and MeHg sources accumulating in the food web. We found that fish and aquatic invertebrates in both EFPC and a regional background site obtained inorganic Hg and MeHg from multiple isotopically distinct sources, including sediment, suspended particulates, and periphyton. Photodemethylation was found to be an important reaction influencing MeHg dynamics at both sites. However, the balance of microbial methylation and demethylation processes differed between the two streams, with fractionation resulting from methylation and demethylation processes being relatively in balance within the regional background site, whereas microbial methylation appeared to be dominant over microbial demethylation within the EFPC ecosystem. Broadly, the application of Hg isotopic analysis in this study led to numerous novel insights regarding the biogeochemical cycling of Hg in stream ecosystems. This research project promoted the development of two new approaches, including the coupling of sequential extractions with Hg isotopic analysis to assess remobilization of recalcitrant Hg within sediments, and a new method for the isotopic analysis of MeHg isolated from environmental samples. Both of these efforts represent advances in capacity for the field of mercury isotopic analysis and environmental assessment. Overall, this study demonstrates that the application of Hg stable isotope techniques continues to provide new insights into the biogeochemical cycling of Hg in complex aquatic environments, both within the EFPC and beyond.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Cation Data for the East River Watershed, Colorado (2014-2025)

This data package contains mean values for cation concentration for water samples taken from the East River Watershed in Colorado. Inductively coupled plasma mass spectrometry (ICP-MS) has been used to measure the concentrations of elements of interest simultaneously for the East River Watershed, Colorado groundwater and surface water samples to inform insights on the biogeochemistry processes within the watershed. The East River is part of the Watershed Function Scientific Focus Area (WFSFA) located in the Upper Colorado River Basin, United States. For samples collected prior to 06-16-2021, the instrumentation, Elan DRC II, PerkinElmer SCIEX, automatically switches among the three models necessary to analyze all 37 elements. These 37 elements include: (1) Lithium (Li), Beryllium (Be), Boron (B), Sodium (Na), Magnesium (Mg), Aluminium (Al), Silicon (Si), Phosphorus (P), Titanium (Ti), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Germanium (Ge), Arsenic (As), Rubidium (Rb), Strontium (Sr), Zirconium (Zr), Molybdenum (Mo), Silver (Ag), Cadmium (Cd), Tin (Sn), Antimony (Sb), Caesium (Cs), Barium (Ba), Europium (Eu), Lead (Pb), Thorium (Th), Uranium (U) using standard model, argon Ar as reaction gas, (2) Potassium (K), Calcium (Ca), Vanadium (V), Chromium (Cr), Manganese (Mn), Iron (Fe) using dynamic reaction cell (DRC) model, ammonia NH3 as reaction gas, and (3) Phosphorus (P) and Selenium (Se) using DRC model, oxygen O2 as reaction gas. Note for the samples with higher concentrations of chloride (Cl-), asenic (As) concentrations were analysed with DRC model (oxygen O2 as reaction gas) to avoid the interference of chloride. For samples collected on and after 06-16-2021, an advanced Agilent 8900 triple quadrupole inductively coupled plasma mass spectrometry system (Agilent 8900 QQQ ICP-MS, Agilent Technologies) has been used to measure the concentrations of interested 36 elements simultaneously for environmental samples, including (1) Lithium (Li), Beryllium (Be) and Boron (B) using standard no gas mode, (2) Sodium (Na), Magnesium (Mg), Aluminium (Al) Phosphorus (P), Potassium (K), Chromium (Cr), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Germanium (Ge), Arsenic (As), Rubidium (Rb), Strontium (Sr), Zirconium (Zr), Molybdenum (Mo), Silver (Ag), Cadmium (Cd), Tin (Sn), Antimony (Sb), Cesium (Cs), Barium (Ba), Europium (Eu), Lead (Pb), Thorium (Th) and Uranium (U) using standard helium (He) collision mode, (3) Titanium (Ti) and Vanadium (V) using high Energy (HEHe) helium (He) collision mode, and (4) Silicon (Si), Calcium (Ca) and Selenium (Se) using standard H2 reaction mode. All samples were prepared/diluted with 2% (v/v) ultrapure nitric acid in Milli-Q water (18.2 mega ohm-cm), and analyzed under a rigorous quality assurance and quality control (QA/QC) process. This data package contains (1) a zip file (cation_data_2014_2025.zip) containing a total of 5,849 files: 5.848 data files of cation data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v6_20260901_flmd.csv) file that lists each file contained in the dataset with associated metadata; (3) a data dictionary (v6_20260901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type; (4) PDF and docx files for the detemination of Method Detection Limits (MDLs) for ICP-MS PerkinElmer DRC II instrumentation (Detemination_of_Method_Detection_Limits__MDLs__for_ICP_MS__PerkinElmer_Elan_DRC_II__LBL_Bldg74_Lab214D) for samples before November 2021; (5) PDF and docx files for the determination of MDLs for ICP-MS Agilent 8900 QQQ instrumentation (ICP_MS_Analysis_detection_limits_and_QA_QC_WenmingDong_updated_2026-08-06) for samples November 2021 and onward. Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 113 locations containing cation data. Update on 2021-04-11: Added Detemination of Method Detection Limits (MDLs) for ICP-MS document, which can be accessed as a PDF or with Microsoft Word. Update on 2022-06-10: versioned updates to this dataset was made along with these changes: (1) updated cation data for all locations up to 2021-12-31, (2) removal of units from column headers in datafiles, (3) added row underneath headers to contain units of variables, (4) removed suffix and prefix on two variables (“aqberylliumion_asberyllium” and “aqlithiumion_aslithium”), (5) added -9999 for empty numerical cells, and (6) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-01-05. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-10-16. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Updated versions of the PDF and docx files for determination of MDLs for ICP-MS data were added to this dataset for samples starting in November 2021. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available cation data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available cation data was added, up until the end of WY2025 (September 30, 2025). Updated versions, as of 2026-08-06, of the PDF and docx files for determination of MDLs for ICP-MS data were added to this dataset for samples starting in November 2021.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Quantifying Groundwater Response and Uncertainty in Beaver‐Influenced Mountainous Floodplains Using Machine Learning‐Based Model Calibration

Abstract Beavers ( Castor canadensis ) alter river corridor hydrology by creating ponds and inundating floodplains, and thereby improving surface water storage. However, the impact of inundation on groundwater, particularly in mountainous alluvial floodplains with permeable gravel/cobble layers overlain by a soil layer, remains uncertain. Numerical modeling across various floodplain structures considers topographic and sediment complexity and multidirectional flow, linking inundation to groundwater response. This study develops a model‐data integration workflow to address uncertainty in groundwater response to beaver‐induced inundations in a mountainous alluvial floodplain in the Upper Colorado River Basin. Uncertain factors include seasonal hydrologic dynamics, hydraulic conductivities, floodplain structures, and meteorological forcings. We employed an ensemble of groundwater models, based on geophysical and hydrologic data, with machine learning‐based calibration using a neural density estimator. This allowed us to quantify the vertical flux from the soil layer to the permeable gravel bed, the down‐valley underflow within the gravel bed, and their ratios. Results show a significant increase in the vertical flux relative to down‐valley underflow, from 2 during dry pond periods to 20 during wet periods, serving as an analogy for conditions without and with beaver ponds. The study highlights the influence of floodplain structure on groundwater storage, water balance, and water quality impacted by beaver ponds. A thick gravel bed layer, with a large down‐valley underflow, minimizes the effect of beaver‐induced inundation on water quality. We emphasize the need for field‐scale measurements of floodplain structure and improved characterization of evapotranspiration changes to reduce uncertainty in groundwater response. Plain Language Summary Beavers change the flow of water in river corridors by creating ponds, expanding wetlands, and flooding floodplains. This increases surface water area, promotes plant growth, and enhances biodiversity. However, the impact of this flooding on groundwater flow is not well understood, especially in mountainous areas with gravel layers where water moves easily beneath soil. In this study, we used numerical modeling to investigate how beaver ponds influence groundwater in a mountainous floodplain of the Upper Colorado River Basin. We adapted a machine learning method to validate our numerical models using multiple field data sets. Our findings show that beaver ponds significantly increase vertical water flow from the soil to the gravel during wet periods, compared to when the ponds are fully drained. The study also highlights the importance of floodplain structure in controlling both water flow in gravel layers along the river direction and vertical flow from the soil to the gravel with the presence of beavers. To reduce uncertainty in groundwater response, we emphasize the need for more field‐scale measurements of floodplain structure, hydraulic properties, and evapotranspiration changes. Key Points Floodplain structures and hydraulic conductivities are important for groundwater response with beaver ponds in mountainous floodplains Large down‐valley underflow in permeability‐stratified floodplains reduces beaver‐induced impacts on groundwater storage and water quality Machine learning‐based model calibration methods are effective for estimating posterior distributions of groundwater model parameters

Wang, Lijing↗
DOE OSTI2024

The Influence of Air‐Sea CO 2 Disequilibrium on Carbon Sequestration by the Ocean's Biological Pump

Abstract The ocean's biological carbon pump (BCP) affects the Earth's climate by sequestering CO 2 away from the atmosphere for decades to millennia. One primary control on the amount of carbon sequestered by the biological pump is air‐sea CO 2 disequilibrium, which is controlled by the rate of air‐sea CO 2 exchange and the residence time of CO 2 in surface waters. Here, we use a data‐assimilated model of the soft tissue BCP to quantify carbon sequestration inventories and time scales from remineralization in the water column to equilibration with the atmosphere. We find that air‐sea CO 2 disequilibrium enhances the global biogenic carbon inventory by ∼35% and its sequestration time by ∼70 years compared to identical calculations made assuming instantaneous air‐sea CO 2 exchange. Locally, the greatest enhancement occurs in the subpolar Southern Ocean, where air‐sea disequilibrium increases sequestration times by up to 600 years and the biogenic dissolved inorganic carbon inventory by >100% in the upper ocean. Contrastingly, in deep‐water formation regions of the North Atlantic and Antarctic margins, where biological production creates undersaturated surface waters which are subducted before fully equilibrating with the atmosphere, air‐sea CO 2 disequilibrium decreases the depth‐integrated sequestration inventory by up to ∼150%. The global enhancement of carbon sequestration by air‐sea disequilibrium is particularly important for carbon respired in deep waters that upwell in the Southern Ocean. These results highlight the importance of accounting for air‐sea CO 2 disequilibrium when evaluating carbon sequestration by the biological pump and for assessing the efficacy of ocean‐based CO 2 removal methods.

Environmental Sciences & Ecology↗
DOE OSTI2022

Geologic Disposal Safety Assessment (GDSA) Biosphere Model Development

The Spent Fuel and Waste Science and Technology Campaign of the U.S. Department of Energy Office of Nuclear Energy, Office of Spent Fuel and Waste Disposition is conducting research and development on geologic disposal of spent nuclear fuel and high-level nuclear waste. This work includes the Geologic Disposal Safety Assessment (GDSA) program which is charged with development of generic deep geologic repository concepts and system performance assessment models. One part of the GDSA framework is the development of a biosphere model capable of assessing doses to potential receptors exposed to radionuclides released from geologic disposal sites. As part of the GDSA framework, a biosphere model compatible with the PFLOTRAN massively parallel subsurface flow and reactive transport code is under development. The PFLOTRAN model provides the radionuclide source term for the biosphere model. The GDSA Biosphere model then assesses the potential movement of radionuclides through the surface biosphere and the subsequent exposure to a human receptor living in the biosphere. The biosphere model includes pathways originating from the groundwater as well as pathways originating from surface water bodies that have a water exchange with a contaminated groundwater body. The pathways for human exposure include consumption of drinking water, irrigated crops, meat animals, aquatic vegetation, and animals, etc.; external exposure from irrigated ground surfaces, surface water bodies, recreational activities, etc.; and inadvertent exposures such as ingestion of contaminated soils or shower water, etc. The GDSA Biosphere model was designed to be flexible and generic in order to accommodate a variety of different sites and climate states. This presentation will present the on the purpose, design, and development progress of the GDSA Biosphere Model.

GDSA, biosphere, repository↗