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At least 181 records · Page 10

Effectiveness of various organometallics as antiwear additives in mineral oil

Sliding friction experiments were conducted with 1045 steel contacting 302 stainless steel and lubricated with various organometallics in mineral oil. Auger emission spectroscopy was used to determine the element present in the wear contact zone. The results indicate that there are organometallics which are as effective an antiwear additives as the commonly used zinc dialkyl dithiophosphate. These include dimethyl cadmium, triphenyl lead thiomethoxide, and triphenyl tin chloride. The additives were examined in concentrations to 1 weight percent. With dimethyl cadmium at concentrations of 0.5 weight percent and above, cadmium was detected in the contact zone. Coincident with the detection of cadmium, a marked decrease in the friction coefficient was observed. All additives examined reduced friction, but only the aforementioned reduced wear to a level comparable to that observed with zinc dialkyl dithiophosphate.

Buckley, D. H.↗

Helical grip for the cable cars of San Francisco

A helical cable car grip to minimize high maintenance costs of San Francisco's cable car operation is presented. The grip establishes a rolling contact between the cable and grip to reduce sliding friction and associated cable wear. The design, development, and testing of the helical cable car grip are described.

Peyran, R. J.↗

Auger spectroscopy analysis of lubrication with zinc dialkyldithiophosphate of several metal combinations in sliding contact

Sliding friction experiments were conducted with aluminum and other riders rubbing on disks of various elemental metals in the presence of a thin film of zinc dialkyldithiophosphate (ZDP). Auger emission spectroscopy was used to in situ monitor the changes in surface chemistry with rubbing under various loads. The metal disks examined included iron, titanium, rhodium, tungsten, molybdenum, and copper. For equivalent films of ZDP the film is a more effective lubricant for some metals than it is for others. The important active element in the compound varies with the metal lubricated and is a function of metal chemistry. The zinc in the ZDP is susceptible to electron beam induced desorption.

Buckley, D. H.↗

Improved Cable Grip Reduces Wear

Improved cable grip reduces wear due to sliding friction between cable and gripping surfaces. Drive wheels are grooved with a helical pattern that meshes with the lay of cable, analogous to a worm gear. Cable is gripped between drive wheels and guide rollers, and cable pull is exerted on the grip when drive wheels are slowed by hydraulic clutches. Cable grip may be applicable to cable-operated systems, such as ore trams in mines, overhead cable cars and ski lifts.

Peyran, R. J.↗

The effect of oxygen concentration on the boundary-lubricating characteristics of a C ether and a polyphenyl ether to 300 C

Ball-on-disk sliding friction experiments were carried out at 17 m/min (100 rev/min) to investigate the effect of oxygen concentration varying from 20% (air) to 0.001% (nitrogen) on the boundary-lubricating characteristics of an unformulated C ether in the temperature range 20-300 C. Results were then compared with those obtained for a five-ring polyphenylether in air and in nitrogen. The C ether yielded lower wear and lower friction coefficients than a five-ring polyphenylether in both air and nitrogen over most of the temperature range. Friction polymer was observed around the wear scars of most test specimens, with much greater quantities of friction polymer produced in a low-oxygen environment. Thus, with respect to friction polymer production, the C ether behaved very much like the polyphenylether.

Jones, W. R., Jr.↗

Transmission Efficiency Measurements and Correlations with Physical Characteristics of the Lubricant

Data from helicopter transmission efficiency tests were compared to physical properties of the eleven lubricants used in those tests. The tests were conducted with the OH-58 helicopter main rotor transmission. Efficiencies ranged from 98.3 to 98.8 percent. The data was examined for correlation of physical properties with efficiency. There was a reasonable correlation of efficiency with absolute viscosity if the viscosity was first corrected for temperature and pressure in the lubricated contact. Between lubricants, efficiency did not correlate well with viscosity at atmospheric pressure. Between lubricants, efficiency did not correlate well with calculated lubricant film forming capacity. Bench type sliding friction and wear measurements could not be correlated to transmission efficiency and component wear.

Coy, J. J.↗

Formation of high molecular weight products from benzene during boundary lubrication

High molecular weight products were detected on the wear track of an iron disk at the end of a sliding friction and wear test using benzene as a lubricant. Size exclusion chromagography in conjunction with UV analysis gave evidence that the high molecular weight products are polyphenyl ether type substances. Organic electrochemistry was used to elucidate the possible surface reaction mechanisms.

Morales, W.↗

Sliding seal materials for adiabatic engines

The sliding friction coefficients and wear rates of promising carbide, oxide, and nitride materials were measured under temperature, environmental, velocity, loading conditions that are representative of the adiabatic engine environment. In order to provide guidance needed to improve materials for this application, the program stressed fundamental understanding of the mechanisms involved in friction and wear. Microhardness tests were performed on the candidate materials at elevated temperatures, and in atmospheres relevant to the piston seal application, and optical and electron microscopy were used to elucidate the micromechanisms of wear following wear testing. X-ray spectroscopy was used to evaluate interface/environment interactions which seemed to be important in the friction and wear process. Electrical effects in the friction and wear processes were explored in order to evaluate the potential usefulness of such effects in modifying the friction and wear rates in service. However, this factor was found to be of negligible significance in controlling friction and wear.

Lankford, J.↗

Creep of Ice: Further Studies

Frictional sliding experiments conducted to study crustal behavior on the icy Galilean satellites are described as well as the microstructural aspects of ice flow. An improved heat exchanger and computer control of temperature are being used to explore the lower regimes of strain rate. A preliminary measurement of the strengths of some of the higher pressure polymorphs of ice was obtained and is considered.

Heard, H. C.↗

Creep of ice: Further studies

Detailed studies have been done of ice creep as related to the icy satellites, Ganymede and Callisto. Included were: (1) the flow of high-pressure water ices II, III, and V, and (2) frictional sliding of ice I sub h. Work was also begun on the study of the effects of impurities on the flow of ice. Test results are summarized.

Heard, H. C.↗

Deep-focus earthquakes and recycling of water into the earth's mantle

For more than 50 years, observations of earthquakes to depths of 100 to 650 kilometers inside earth have been enigmatic: at these depths, rocks are expected to deform by ductile flow rather than brittle fracturing or frictional sliding on fault surfaces. Laboratory experiments and detailed calculations of the pressures and temperatures in seismically active subduction zones indicate that this deep-focus seismicity could originate from dehydration and high-pressure structural instabilities occurring in the hydrated part of the lithosphere that sinks into the upper mantle. Thus, seismologists may be mapping the recirculation of water from the oceans back into the deep interior of the planet.

Meade, Charles↗

Interfacial shear behavior of sapphire-reinforced NiAl composites

The interfacial shear behavior in near-equiatomic NiAl reinforced by sapphire filaments has been examined at room temperature using a fiber pushout test technique. The load-displacement data indicate a large variability in the initial interface failure stress, although reverse push behavior indicates a comparatively constant interfacial sliding friction stress. The observed behavior suggests that the presence of asperities on the fiber surfaces and nonuniformities in fiber diameter require constrained plastic flow within the NiAl matrix in order for interfacial shear to occur. The location, shape, severity, and distribution of fiber asperities as well as the uniformity of fiber diameter are critical to the interfacial shear process.

Moose, C. A.↗

Development of BEM for ceramic composites

BEST-CMS (boundary element solution technology - composite modeling system) is an advanced engineering system for the micro-analysis of fiber composite structures. BEST-CMS is based upon the boundary element program BEST3D which was developed for NASA by Pratt and Whitney Aircraft and the State University of New York at Buffalo under contract NAS3-23697. BEST-CMS presently has the capabilities for elastostatic analysis, steady-state and transient heat transfer analysis, steady-state and transient concurrent thermoelastic analysis, and elastoplastic and creep analysis. The fibers are assumed to be perfectly bonded to the composite matrix, or in the case of static or steady-state analysis, the fibers may be assumed to have spring connections, thermal resistance, and/or frictional sliding between the fibers and the composite matrix. The primary objective of this user's manual is to provide an overview of all BEST-CMS capabilities, along with detailed descriptions of the input data requirements. In the next chapter, a brief review of the theoretical background is presented for each analysis category. Then, chapter three discusses the key aspects of the numerical implementation, while chapter four provides a tutorial for the beginning BEST-CMS user. The heart of the manual, however, is in chapter five, where a complete description of all data input items is provided. Within this chapter, the individual entries are grouped on a functional basis for a more coherent presentation. Chapter six includes sample problems and should be of considerable assistance to the novice. Chapter seven includes capsules of a number of fiber-composite analysis problems that have been solved using BEST-CMS. This chapter is primarily descriptive in nature and is intended merely to illustrate the level of analysis that is possible within the present BEST-CMS system. Chapter eight contains a detail description of the BEST-CMS Neutral File which is helpful in writing an interface between BEST-CMS and any graphic post-processor program. Finally, all pertinent references are listed in chapter nine.

Henry, D. P.↗

Physical and Tribological Characteristics of Ion-Implanted Diamond Films

Unidirectional sliding friction experiments were conducted with a natural, polished diamond pin in contact with both as-deposited and carbon-ion-implanted diamond films in ultrahigh vacuum. Diamond films were deposited on silicon, silicon carbide, and silicon nitride by microwave-plasma-assisted chemical vapor deposition. The as-deposited diamond films were impacted with carbon ions at an accelerating energy of 60 keV and a current density of 50 micron A/cm(exp 2) for approximately 6 min, resulting in a dose of 1.2 x 10(exp 17) carbon ions/cm(exp 2). The results indicate that the carbon ion implantation produced a thin surface layer of amorphous, nondiamond carbon. The nondiamond carbon greatly decreased both friction and wear of the diamond films. The coefficients of friction for the carbon-ion-implanted, fine-grain diamond films were less than 0.1, factors of 20 to 30 lower than those for the as-deposited, fine-grain diamond films. The coefficients of friction for the carbon-ion-implanted, coarse-grain diamond films were approximately 0.35, a factor of five lower than those for the as-deposited, coarse-grain diamond films. The wear rates for the carbon-ion-implanted, diamond films were on the order of 10(exp -6) mm(exp 3)/Nm, factors of 30 to 80 lower than that for the as-deposited diamond films, regardless of grain size. The friction of the carbon-ion-implanted diamond films was greatly reduced because the amorphous, nondiamond carbon, which had a low shear strength, was restricted to the surface layers (less than 0.1 micron thick) and because the underlying diamond materials retained their high hardness. In conclusion, the carbon-ion-implanted, fine-grain diamond films can be used effectively as wear resistant, self-lubricating coatings for ceramics, such as silicon nitride and silicon carbide, in ultrahigh vacuum.

Miyoshi, K.↗

Off axis loading of silicon carbide fibers in a titanium aluminide matrix

Silicon carbide SCS-6 fibers in a Ti24A1 + 11Nb matrix were subjected to off axis loading in a 'thin-slice' pushout test, resulting in various combinations of shear, radial compression, and tension along the fibers as a function of orientation angle. The load necessary for debonding decreased as the orientation angle increased, whereas the average frictional sliding stress after 60 s of sliding remained relatively constant for orientation angles less than 30 deg. Analyses of the specimen bending stresses and of the contact stresses by finite element modeling and thin plate theory are presented.

Kennefick, C. M.↗

The isostatic state of Mead crater

We have analyzed high-resolution Magellan Doppler tracking data over Mead crater, using both line-of-sight and spherical harmonic methods, and have found a negative gravity anomaly of about 4-5 mgal (at spacecraft altitude, 182 km). This is consistent with no isostatic compensation of the present topography; the uncertainty in the analysis allows perhaps as much as 30% compensation at shallow dpeths (approximately 25 km). This is similar to observations of large craters on Earth, which are not generally compensated, but contrasts with at least some lunar basins which are inferred to have large Moho uplifts and corresponding positive Bouguer anomalies. An uncompensated load of this size requires a lithosphere with an effective elastic lithosphere thickness greater than 30 km. In order for the crust-mantle boundary not to have participated in the deformation associated with the collapse of the transient cavity during the creation of the crater, the yield strength near the top of the mantle must have been significantly higher on Earth and Venus than on the Moon at the time of basin formation. This might be due to increased strength against frictional sliding at the higher confining pressures within the larger planets. Alternatively, the thinner crusts of Earth and Venus compared to that of the Moon may result in higher creep strength of the upper mantle at shallower depths.

Banerdt, W. B.↗

Computing Contact Stresses In Gear Teeth

Improved method of computing contact stresses in gear teeth accounts for complicating effects like those of static and sliding friction. Provides iterative procedure for determination of contact region and nodal contact forces along with contact stresses. Method based on equations and computational procedure incorporating these effects routinely.

Oswald, Fred B.↗

Effects of Fiber Content on Mechanical Properties of CVD SiC Fiber-Reinforced Strontium Aluminosilicate Glass-Ceramic Composites

Unidirectional CVD SiC(f)(SCS-6) fiber-reinforced strontium aluminosilicate (SAS) glass-ceramic matrix composites containing various volume fractions, approximately 16 to 40 volume %, of fibers were fabricated by hot pressing at 1400 C for 2 h under 27.6 MPa. Monoclinic celsian, SrAl2Si2O8, was the only crystalline phase formed, with complete absence of the undesired hexacelsian phase, in the matrix. Room temperature mechanical properties were measured in 3-point flexure. The matrix microcracking stress and the ultimate strength increased with increase in fiber volume fraction, reached maximum values for V(sub f) approximately equal to 0.35, and degraded at higher fiber loadings. This degradation in mechanical properties is related to the change in failure mode, from tensile at lower V(sub f) to interlaminar shear at higher fiber contents. The extent of fiber loading did not have noticeable effect on either fiber-matrix debonding stress, or frictional sliding stress at the interface. The applicability of micromechanical models in predicting the mechanical properties of the composites was also examined. The currently available theoretical models do not appear to be useful in predicting the values of the first matrix cracking stress, and the ultimate strength of the SCS-6/SAS composites.

Bansal, Narottam P.↗