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At least 181 records · Page 10

Control of Slag Carryover from the BOF Vessel During Tapping: BOF Cold Model Studies

In a modern integrated steel plant, slag-free tapping during transfer of liquid steel from the BOF vessel to the ladle is prerequisite to produce ultraclean steel for high-end critical applications. The present investigation aims to examine the drain vortices during the liquid steel tapping process. The tapping experiments were conducted in a geometrical down-scaled Perspex BOF cold model, which was more akin to the industrial practice than the other geometries previously reported in the literature. The study highlights the influence of the complex BOF shape on drain vortices during the tapping process. It is observed that vorticity behavior during liquid steel tapping from the BOF vessel is different from the earlier observations reported for the teeming process. The parametric study of the tapping process and its analysis confirmed that the threshold height for drain vortices is strongly influenced by the nozzle diameter (ND) and marginally influenced by the residual inertia of the liquid. The carryover ratio (COR) for the water-oil experiments is in agreement with the values obtained in industrial practice. Yield loss tends to increase with the increase in ND. The onset of drain vortices in the presence of overlying phase (oil/slag) during the BOF tapping process could be principally controlled by the vessel design. The physical properties of the overlying phase had negligible influence on the drain vortices. The critical times for vortex and drain sink formation were predicted based on dimensional analysis coupled with the mathematical formulation for the tapping process. A strategy to control the slag carryover during the tapping process in industry is also discussed and postulated based on the understanding developed from water modeling experiments.

36 MATERIALS SCIENCE↗

Effect of Nozzle Port Angle on Transient Flow and Surface Slag Behavior During Continuous Steel-Slab Casting

Undesirable flow variations can cause severe instabilities at the interface between liquid mold flux and molten steel across the mold top-region during continuous steel casting, resulting in surface defects in the final products. A three-dimensional Large Eddy Simulation (LES) model using the volume of fluid method for the slag and molten steel phases is validated with plant measurements, and applied to gain new insights into the effects of nozzle port angle on transient flow, top slag/steel interface movement, and slag behavior during continuous slab casting under nominally steady conditions. Upward-angled ports produce a single-roll flow pattern with lower surface velocity, due to rapid momentum dissipation of the spreading jet. However, strong jet wobbling from the port leads to greater interface variations. Severe level drops allow easy entrapment of liquid flux by the solidifying steel shell at the meniscus. Sudden level rises may also be detrimental, leading to overflow of the solidified meniscus region. Downward-angled ports produce a classic double-roll pattern with less jet turbulence and a more stable interface everywhere except near the narrow faces. Finally, the flow patterns, surface velocity, and level predicted from the validated LES model are compared with steady-state standard k-ε model predictions.

36 MATERIALS SCIENCE↗

Reaction Mechanism and Kinetics of Boron Removal from Molten Silicon via CaO-SiO{sub 2}-CaCl{sub 2} Slag Treatment and Ammonia Injection

To improve the boron-removal efficiency of metallurgical-grade silicon by increasing the reaction rate, a combined method with the 30 mol pct CaO-23.3 mol pct SiO{sub 2}-46.7 mol pct CaCl{sub 2} slag treatment and ammonia injection at 1723 K to 1823 K was proposed. For 1 hour and at 1823 K, the maximum removal efficiency of boron was 98 pct, and the final boron concentration in silicon decreased to 1.5 ppmw by the present method without the introduction of the iron catalyst. A kinetic model was also established to clarify the reaction mechanism and rate-limiting steps of this complicated boron-removal process. In this model, the rate-limiting step is the mass transfer of boron oxide at the interface between the slag and silicon phase.

36 MATERIALS SCIENCE↗

A Kinetic Study Investigating the Carbothermic Recovery of Chromium from a Stainless-Steel Slag

In 2018, the stainless-steel industry produced > 10 million tons of slag, which for the most part was landfilled because of chromium oxide contamination. Long-term studies indicate a possible formation of soluble hexavalent chromium, which is classified as carcinogenic. Recent research focuses on the development of a treatment technology to recover chromium from the slag into a ferroalloy, producing an oxidic material that can be utilized in the construction industry. To date, there has been no literature dealing with the kinetics of a carbothermic treatment process to result in a model to predict the necessary treatment time. The present article fills this gap by investigating the reduction kinetics of chromium oxide of a process close to practical applications. Based on experimental measurements, a model has been developed to predict the necessary treatment time to reach a specific final chromium concentration as a function of the starting concentration and required process temperature in the range between 1600 °C and 1700 °C. Finally, presented findings can serve as a guideline to develop kinetic models in similar pyrometallurgical recovery processes.

36 MATERIALS SCIENCE↗

Accurate Density Calculation for Molten Slags in SiO{sub 2}-Al{sub 2}O{sub 3}-CaO-MgO-‘FeO’-‘Fe{sub 2}O{sub 3}’ Systems

A simple and accurate density calculation model for molten slags containing iron oxides in SiO{sub 2}-Al{sub 2}O{sub 3}-CaO-MgO-‘FeO’-‘Fe{sub 2}O{sub 3}’ systems is established in the present study, by extending a previous model developed for SiO{sub 2}-Al{sub 2}O{sub 3}-CaO-MgO systems. To quantitate the iron oxides in slags, a new method is proposed to recalculate all the iron oxides as ‘FeO’ and ‘Fe{sub 2}O{sub 3},’ which represent the iron oxides in equilibrium with metallic iron and the air atmosphere, respectively. This method is essentially different from most of the other models that dealt with ferrous (FeO) and ferric (Fe{sub 2}O{sub 3}) iron oxides. A total of 860 experimental data points for iron oxide-containing melts are critically collected for the optimization of the model parameters. The model achieves an excellent agreement with literature values with an average error of 1.96 pct and an overall absolute error of 0.092 g/cm{sup 3}. The compositional dependences from unary to multicomponent systems are discussed using the present model. The results show that the densities always increase with the increasing ‘FeO’ or ‘Fe{sub 2}O{sub 3},’ and the substitution of ‘FeO’ by ‘Fe{sub 2}O{sub 3}’ will cause a decrease in density. In the multicomponent systems, SiO{sub 2} tends to have a larger impact on the density of ‘Fe{sub 2}O{sub 3}’-containing systems compared with ‘FeO’-containing systems.

36 MATERIALS SCIENCE↗

Influence of the composition of cement kiln dust on its interaction with fly ash and slag

Cement kiln dust (CKD), a by-product of the cement industry, contains significant amounts of alkali, free lime, chloride and sulfate. Wide variation reported in the chemical composition of CKDs limits their potential application as a sustainable binder component in concrete. In the current study, the performance of two different CKDs as components in a novel binder is evaluated. Several binders are developed by blending CKDs with fly ash or slag. Binders with 70% CKD were prepared at a water-to-binder ratio of 0.4, and heat-cured at 75 °C to accelerate the strength development. The hydration progress was monitored using X-ray diffraction, and morphological examination was performed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Ettringite and calcium aluminosilicate hydrate (C-A-S-H) were identified as the main hydration products in the hardened binder system. Strength development of CKD-based binder was found to be significantly influenced by its free lime and sulfate contents. -- Highlights: •Interaction of cement kiln dust with fly ash and slag was explored. •CKD with higher free lime and sulfate content increased the strength of binder. •C-S-H like reaction gel with fibrillar morphology is observed in CKD-based binders.

36 MATERIALS SCIENCE↗

Isothermal calorimetry and in-situ XRD study of the NaOH activated fly ash, metakaolin and slag

Much is unknown about the reaction processes responsible for the formation and polycondensation of geopolymers and other alkali activated materials. In this work, isothermal calorimeter and in-situ XRD were adopted to study the heat and mineral evolution of NaOH activated fly ash, metakaolin and ground granulated blast furnace slag. Both activator concentration and temperature have profound influences on duration of exothermal geopolymerization peaks. NaOH activated fly ash is more temperature dependable, with much higher activation energy than metakaolin and slag. The dissolution of source precursor is rapid and the formation of new phases can be detected by the end of the initial dissolution period. The in-situ XRD measurement together with the PONKCS analysis method promotes quantitative estimation of amorphous evolution during alkali activation.

36 MATERIALS SCIENCE↗

Moisture transport and sorption in cement based materials containing slag or silica fume

This paper presents the moisture dependency of moisture transport and moisture fixation in mortars with OPC, slag and silica fume. Water vapor desorption isotherms were measured with gravimetric methods and the moisture dependency of moisture transport was investigated with cup-tests. The results show an ongoing evolution of water vapor desorption isotherms from eight months to four years. The evolution is more pronounced for mortars containing slag. The results also show that there is a significant difference in moisture dependency of the moisture transport properties above 70% relative humidity; some mortars exhibit a clear moisture dependency in moisture transport whereas others do not. At a relative humidity below 70%, the water to binder ratio is more decisive for moisture transport than the type of binder. These results are of value for service-life models, where they represent important input data, and for understanding the evolution of the microstructure at later ages.

36 MATERIALS SCIENCE↗

Rheology of activated phosphorus slag with lime and alkaline salts

The present study aimed to determine the rheological behavior of activated phosphorus slag (AAPS) with a combination of Ca(OH){sub 2} and Na{sub 2}CO{sub 3} (CNC activator) or Na{sub 2}SO{sub 4} (CNS activator) compared to OPC paste. The findings showed that the rheology of AAPS pastes fit with the Herschel-Bulkley model and behaved like a shear-thinning fluid. The AAPS pastes rheology is affected by concentration and nature of activator. The shear stress in AAPS pastes was lower than OPC paste, and increased with increasing the activator concentration. In early ages, reaction products of PS/CNC pastes included calcite-type compounds with the formed gel while gypsum compounds formed in the PS/CNS pastes. This resulted in higher shear stress and lower workability for PS/CNC pastes compared to PS/CNS pastes. The formed gel due to interaction between Ca{sup 2+} ions of CNC activator and Si{sup 4+} ions of Phosphorus slag caused an increase in the shear stress for PS/CNC during the time.

36 MATERIALS SCIENCE↗

Early reactivity of sodium silicate-activated slag pastes and its impact on rheological properties

The fast loss of fluidity of sodium silicate-activated slag (SS-AAS) systems have been widely studied in the literature. In this study, the rheology of these cements has been correlated with the evolution of the reaction products formed over time. For this purpose, a combination of experimental characterization techniques, to study the pore solution composition and microstructure of SS-AAS pastes and thermodynamic calculations have been applied. The initial precipitation of ill-defined N-A-S-H and C-N-A-S-H producta leads to a fast increase of the storage modulus after 40 min of reaction. These products are formed from the reaction of the Na{sup +} ions and silicate ions of the activator with the Ca{sup 2+} and aluminate species dissolved from the slag. However, when a shear is applied, the structure breaks down and fluidity is recovered, that infers that the attractive forces between the particles are low at the early stages of hydration.

36 MATERIALS SCIENCE↗

Comparison of liquid absorption-release of superabsorbent polymers in alkali-activated slag and Portland cement systems: An NMR study combined with additional methods

In this study, {sup 1}H low-field NMR was used to compare the liquid absorption-release behaviour of superabsorbent polymers (SAPs) in Portland cement (PC) paste, NaOH-activated slag (SH-AAS) paste, and water glass-activated slag (WG-AAS) paste. The liquid absorption of SAPs in the PC paste was lower than that in the SH-AAS paste and the WG-AAS paste. The liquid release was also faster, which was mainly due to the higher Ca{sup 2+} concentration in the pore fluid of the PC system. In the AAS system, although the Ca{sup 2+} concentration in the pore fluid was low, the Na{sup +} concentration was much higher than that in the PC system due to the activator. The Ca{sup 2+} in the PC system is an important factor affecting the swelling of SAPs, while in the AAS system, the swelling limitation of SAPs is the result of the combined effects of Ca{sup 2+} and Na{sup +}, with Na{sup +} being dominant.

36 MATERIALS SCIENCE↗

Coordination environment of Si in calcium silicate hydrates, silicate minerals, and blast furnace slags: A XANES database

Understanding the silicate polymerization of calcium silicate hydrate (C-S-H) gel and its crystalline polymorphs is important in cement science. NMR can determine Si environments, but the measurement can be time-consuming and provides no spatial information. X-ray absorption near-edge structure (XANES) spectroscopy is a fast tool for probing Si coordination, possibly with spatial information. However, there lacks an understanding of Si K-edge XANES spectra of cement-related silicate phases. Here, a Si K-edge XANES spectral database of nanocrystalline C-S-H, C-S-H minerals, blast-furnace slags, and metakaolin is provided. Si K-edge of C-S-H minerals shifts to higher energies with higher polymerized Si and lower CaSi connectivity in the Si second nearest neighbor shell. Si K-edge energy shows weak correlations with Ca/Si ratio, average SiO bond length, and SiO{sub 4} distortion due to the structural complexity of silicates. The substitution of Al for Si shifts the Si K-edge of tobermorite and slags to higher energies.

36 MATERIALS SCIENCE↗

Experimental evidence for the acceleration of slag hydration in blended cements by the addition of CaCl2

Cements with high substitution rates of ground granulated blast furnace slags (GGBS) have the potential to significantly lower CO{sub 2} emissions of concrete, but their early age strength is often below those of traditional OPC cements. One way of mitigating this drawback is to use accelerating admixtures. In this study, the effect of CaCl{sub 2} additions on the hydration of blended cements was investigated by measuring compressive strength, porosity, heat release and propagation of ultrasound in blends containing 70 wt% of GGBS. The onset of formation of aluminate phases was monitored using in-situ XRD. The effect of CaCl{sub 2} on slag hydration was isolated by replacing GGBS by an inert quartz filler. Results showed that compressive strength values at one, two and seven days were increased by 50% by the CaCl{sub 2} addition. The increases in compressive strength corresponded to a reduction in pore space. GGBS hydration contributed to the heat development, structuration and compressive strength of the blended cements from 15 h. The addition of CaCl{sub 2} led to an earlier onset of the GGBS reaction, at around 10 h, and increased the rate of GGBS hydration during the first seven days. The time of onset of the GGBS contribution was also the moment when AFm precipitation started. In CaCl{sub 2}-containing blends, Cl was incorporated in AFm.

36 MATERIALS SCIENCE↗

Autogenous shrinkage and hydration property of alkali activated slag pastes containing superabsorbent polymer

In this paper, the superabsorbent polymer (SAP) was applied as internal curing agent to study its effect on the autogenous shrinkage and hydration property of alkali activated slag (AAS) pastes. Liquid absorption and release processes of SAP in AAS pastes were characterized by {sup 1}H nuclear magnetic resonance ({sup 1}H NMR). Moreover, the microstructure and mechanical strength of AAS pastes containing SAP were also revealed. The results showed that the autogenous shrinkage of AAS pastes containing SAP was reduced by about 80.6%, 72.1% and 72.6%, respectively as the silicate modulus (Ms) increased from 0.8 to 1.4. The addition of SAP delayed the second exothermic peak, but increased the cumulative heat of AAS pastes. In addition, internal curing by SAP could promote the generation of C-A-S-H gels and hydrotalcite-like phases and increase the reaction degree of slag, particularly for AAS pastes with higher Ms, being attributed to the continuous release of entrained water and alkali activator solutions in SAP with the increase of hydration time. Furthermore, the addition of SAP would increase capillary pore size and pore volume of AAS pastes, and thus lead to the decrease of compressive strength.

36 MATERIALS SCIENCE↗

A microstructural investigation of a Na2SO4 activated cement-slag blend

The reactivity and early strength of cement:slag binders is usefully enhanced by the addition of sodium sulfate though the underlying mechanisms of the relationship between the enhanced hydration reactions and the structural aspects of the strength behavior remain unclear. In this study, microstructural development in the presence of Na{sub 2}SO{sub 4} was investigated utilizing mercury intrusion porosimetry (MIP), NMR relaxometry, and XRD. Increased rates of early strength development and decreased rates of late strength development due to the presence of added Na{sub 2}SO{sub 4} were linked to effects on capillary porosity refinement. While degree of hydration at later age was shown to have been lower in the presence of Na{sub 2}SO{sub 4}, and may have been responsible for the higher capillary porosity, a clear alteration in the pathway of microstructural development had occurred with inhibition to hydration of the slag component due to earlier microstructural development proposed.

36 MATERIALS SCIENCE↗

Effect of the inherent alkalis of alkali activated slag on the risk of alkali silica reaction

Alkali silica reaction (ASR) occurred in the alkali activated slag (AAS) concrete was evaluated by a revised mortar prism method. The mortars were made of blast furnace slags activated by alkali silicate solution possessing different modulus (0.5, 0.75, 1 and 2) as well as cations (sodium and potassium) and standard sand with a volume replacement of 25 vol% by borosilicate glass beads. Their changes in length and dynamic elastic modulus were monitored up to 7 months. The results showed that ASR has taken place among some mortars, which were evident under both light microscopy and electron microscopy with EDX analysis. The results also revealed that high alkali content did promote the risk of ASR but the degradation due to ASR was affected in a much more complex way.

36 MATERIALS SCIENCE↗

Performance of fly ash concrete with ferronickel slag fine aggregate against alkali-silica reaction and chloride diffusion

Ferronickel slag (FNS) is an industrial by-product of ferronickel alloy production at a high temperature which can be a promising potential to be used as fine aggregate to produce more sustainable concrete. In this study, the performance of concrete containing ferronickel slag sand and fly ash relating to alkali-silica reaction (ASR) and chloride contamination was investigated. ASR-induced expansion, chloride diffusion resistance, and chloride binding capacity of FNS concrete were determined through concrete prism tests (CPT), accelerated diffusion test, and bulk diffusion test. Thermogravimetric analysis (TGA) was conducted to measure the amount of Portlandite and Friedel's salt in concrete. Concrete with 50 wt% FNS sand as fine natural aggregate replacement and 25 wt% of cement replacement by fly ash showed a remarkable potential to be used not only as a low-carbon concrete with comparable mechanical properties to conventional concrete but also with a better performance against ASR and chloride contamination.

36 MATERIALS SCIENCE↗

Critical role of slags in pitting corrosion of additively manufactured stainless steel in simulated seawater

Abstract Pitting corrosion in seawater is one of the most difficult forms of corrosion to identify and control. A workhorse material for marine applications, 316L stainless steel (316L SS) is known to balance resistance to pitting with good mechanical properties. The advent of additive manufacturing (AM), particularly laser powder bed fusion (LPBF), has prompted numerous microstructural and mechanical investigations of LPBF 316L SS; however, the origins of pitting corrosion on as-built surfaces is unknown, despite their utmost importance for certification of LPBF 316L SS prior to fielding. Here, we show that Mn-rich silicate slags are responsible for pitting of the as-built LPBF material in sodium chloride due to their introduction of deleterious defects such as cracks or surface oxide heterogeneities. In addition, we explain how slags are formed in the liquid metal and deposited at the as-built surfaces using high-fidelity melt pool simulations. Our work uncovers how LPBF changes surface oxides due to rapid solidification and high-temperature oxidation, leading to fundamentally different pitting corrosion mechanisms.

36 MATERIALS SCIENCE↗