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At least 181 records · Page 10

Mineralogy and Ar-39 - Ar-40 of an old pristine basalt: Thermal history of the HED parent body

Previous investigations of mineral chemistry and Rb-Sr and Sm-Nd ages indicated that clast,84 from eucrite Yamato 75011 had preserved the pristine nature of its initial crystallization during an early stage of the HED parent body. Microscale mineralogy and Ar-39-Ar-40 ages of this clast, however, revealed local disturbance of microtextures and partially reset ages. This evidence suggests that, in addition to initial crystallization and rapid cooling, the Y75011,84 clast experienced shock deformation, reheating of short duration at higher temperature, and brecciation. These characteristics suggest two or more impact events. Fe-rich olivine filling fractures in pyroxene may have been introduced during the accompanying shock fracturing. The inferred Ar-39-Ar-40 degassing ages for Y75011 matrix and clast, 84 are 3.94 +/- 0.04 Ga and 3.98 +/- 0.03 Ga, respectively. The suggested degassing age for a clast from Y790020, believed to be paired with Y75011, is approximately 4.03 Ga, but could be younger. We consider it likely that all three samples experienced a common degassing event 3.95 +/- 0.05 Ga ago, but we cannot rule out two or more events spaced over a approximately 0.1 Ga interval. Higher temperature extractions of the two clast samples show significantly older apparent ages up to approximately 4.5 Ga and suggest that the time/temperature regime of this event was not sufficient to degas Ar totally. Most likely, the K-Ar ages were reset by thermal metamorphism associated with one or more impact events associated with shock fracturing, formation of Fe-rich olivine veins, and/or meteorite brecciation. The pyroxene annealing that commonly occurs in many eucrites is likely to be a much earlier process than the impact-produced textural changes and reset K-Ar ages observed in these meteorites. The existence of mineralogical and chronological evidence for metamorphism in an otherwise pristine eucrite suggests that the HED parent body experienced an extensive degree of early cratering.

Takeda, Hiroshi↗

Neodymium, strontium and chromium isotopic studies of the LEW86010 and Angra dos Reis meteorites and the chronology of the angrite parent body

Neodymium, stontium, and chromium isotopic studies of the LEW86010 angrite established its absolute age and the formation interval between its crystallization and condensation of Allende CAIs from the solar nebula. Pyroxene and phosphate were found to contain approximately 8% of its Sm and Nd inventory. A conventional Sm-147-Nd-143 isochron yielded an age of 4.53 +/- 0.04 Ga (2 sigma and Epsilon(sub Nd sup 143)) = 0.45 +/- 1.1. An Sm-146-Nd-142 isochron gives initial Sm-146/Sm-144 = 0.0076 +/- 0.0009 and Epsilon (sub Nd sup 142) = -2.5 +/- 0.4. The Rb-Sr analyses give initial Sr-87/Sr-86 Iota(sub Sr sup 87) = 0.698972 +/- 8 and 0.698970 +/- 18 for LEW and ADOR, respectively, relative to Sr-87/Sr-86 = 0.71025 for NBS987. The difference, Delta Iota(sub Sr Sup 87), between Iota (sub sr sup 87) for the angrites and literature values for Allende CAIs, corresponds to approximately Ma of growth in a solar nebula with a CI chondrite value of Rb-87/Sr-86 = 0.91, or approximately 5 Ma in a nebula with solar photospheric Rb-87/Sr-86 = 1.51. Excess Cr-53 from extinct Mn-53(t(sub 1/2) = 3.7 Ma)in LEW86010 corresponds to initial Mn-53/Mn-55 = 4.4 +/- 1.0 x 10(exp -5) for the inclusions as previously reported by the Paris group (Birck and Allegre, 1988). The Sm-146/Sm-144 value found for LEW86010 corresponds to solar system initial (Sm-146/Sm-144) = 0.0080 +/- 0.0009 for crystallization 8 Ma after Allende, the difference between Pb-Pb ages of angrites and Allende, or 0.0086 +/- 0.0009 for crystallation 18 Ma after Allende, using the Mn-Cr formation interval. The isotopic data are discussed in the context of a model in which an undifferentiated 'chondritic' parent body formed from the solar nebula approximately Ma after Allende CAIs and subsequently underwent differentiation accompanied by loss of volatiles. Parent bodies with Rb/Sr similar to that of CI, CM, or CO chondrites could satisfy the Cr and Sr isotopic systematics. If the angrite parent body had Rb/Sr similar to that of CV meteorites, it would have to form slightly later, approximately 2.6 Ma after the CAIs, to satisfy the Sr and CR isotopic systematics.

Nyquist, L. E.↗

Comparative FeNi and Silicate Chronology in Portales Valley

Re-Os and U-Pb data on Portales Valley suggest an early formation for the metal and silicates. These two chronometers and Rb-Sr and Sm-Nd require a young disturbance. This is inconsistent with the 39 Ar-40 Ar age and in need of clarification.

Chen, J. H.↗

Chronology and Petrology of Silicates From IIE Iron Meteorites: Evidence of a Complex Parent Body Evolution

IIE iron meteorites contain silicate inclusions whose characteristics suggest a parent body similar to that of H-chondrites. However, these silicates show a wide range of alteration, ranging from Netschadvo and Techado, whose inclusions are little altered. to highly differentiated silicates like-those in Kodaikanal, Weekeroo Station and Colomera, which have lost metal and sulfur and are enriched in feldspar. We find these inclusions to show varying degrees of shock alteration. Because only a limited amount of data on - isotopic ages of HE silicates were available, we made Ar-39 - Ar-40 age determinations of Watson, Techado, miles Colomera, and Sombrerete. Watson has an Ar-Ar age of 3.653 +/- 0.012 Gyr, similar to previously reported ages for Kodaikanal and Netschadvo. We suggest that the various determined radiometric ages of these three meteorites were probably reset by a common impact event. The space exposure ages for these three meteorites are also similar to each other and are considerably younger than exposure ages of other IIEs. Ar-39 - Ar-40 ages inferred for the other four meteorites analyzed are considerably older than Watson and are: Techado =4.49 +/- 0.01 Gyr, Miles =4.412 +/- 0.016 Gyr, Colomera =4.469 +/- 0.012 Gyr, and Sombrerete =4.535 +/- 0.005 Gyr. These ages are in fair agreement with previously reported Rb-Sr isochron ages for Colomera and Weekeroo Station. Although several mechanisms to form HE meteorites previously were suggested, it is not obvious that a single mechanism could produce a suite of meteorites with very different degrees of silicate differentiation and with isotopic ages that differ by >0.8 Gyr. We suggest that those IIEs with older isotopic ages are a product of partial melting and differentiation within the parent body, followed by mixing of silicate and metal while both were relatively hot. Netschadvo and Watson may have formed by this same process or by impact mixing about 4.5 Gyr ago, but their isotopic ages were subsequently reset by shock heating. Kodaikanal apparently is required to have formed more recently, in which case impact melting and differentiation seems the only viable process. We see no compelling reasons to believe that IIE silicate and metal derived from different parent bodies or that the parent body of IIEs was the same as that of H-chondrites.

Bogard, Donald D.↗

Radiometric Ages of Martian Meteorites compared to Martian Surfaces Ages

The surprisingly young Rb-Sr age of the Shergotty meteorite contributed to early suggestions that it might be of martian origin. their redox state and oxygen isotopic compositions linked the shergottites to the clino-pyroxenite nakhlites and the dunite Chassigny, causing them to be grouped as SNC meteorites. These characteristics, but especially the similarity of the elemental and isotopic compositions of gases trapped in shergottites to those of the martian atmosphere, have caused the martian origin of the SNC and related meteorites to be widely accepted. Although the young ages were one of the early hints of a martian origin for the SNC meteorites, their interpretation has remained somewhat ambiguous. We will review the radiometric ages of the martian meteorites and attempt to place them into the context of martian surface ages.

Nyquist, L. E.↗

Age of EET79001B and Implications for Shergottite Origins

A precise Rb-Sr age of 174+/-3 Ma was determined for EET79001B. A Sm-Nd age of 169+/-23 Ma also was determined, but the Nd isotopic systematics are disturbed. This disturbance is attributed to incomplete isotopic equilibration during petrogenesis. Additional information is contained in the original extended abstract.

Nyquist, L. E.↗

Crystallization and Alteration Ages of the Antarctic Nakhlite Yamato 000593

Nakhlites are unbrecciated, olivine-bearing clinopyroxenites that probably came from Mars. A total of eight nakhlites have been identified, including five recent finds: two samples (104 g and 456 g) from the hot desert of Morocco (NWA 817 and NWA 998), and three samples, a total weight of approx.15 kg, from the Yamato Mountains of Antarctica (Y000593, Y000749 and Y000802). Preliminary isotopic results for Y000593 have been given by Shih et al.. In this report, we present Rb-Sr and Sm-Nd isochron data for Y000593 and discuss the age correlation with other nakhlites and the timing of aqueous alteration on Mars.

Musawa, K.↗

Ar-39 - Ar-40 Dating of Two Angrites and Two Brachnites

Angrites are a rare group (approx.7 known) of igneous meteorites with basalt-like composition, which probably derive from a relatively small parent body that differs from those of other igneous meteorites. Angrites show evidence for extinct Mn-53, Sm-146, and Pu-244, and precise U-Pb, and Pb-Pb ages of 4.558 Gyr for two angrites define the time of early parent body differentiation. The S-147 - Nd-143 ages of two angrites range between 4.53+/-0.04 and 4.56+/-0.04 Gyr, but no Ar-39 - Ar-40 or Rb-Sr ages have been reported. Most angrites show no evidence for either shock brecciation or metamorphism.

Garrison, Daniel↗

Lunar and Planetary Science XXXV: Martian Meteorites: Chemical Weathering

The session "Martian Meteorites: Chemical Weathering" included the following reports:Chemical Weathering Records of Martian Soils Preserved in the Martian Meteorite EET79001; Synchrotron X-Ray Diffraction Analysis of Meteorites in Thin Section: Preliminary Results; A Survey of Olivine Alteration Products Using Raman Spectroscopy; and Rb-Sr and Sm-Nd Isotope Systematics of Shergottite NWA 856: Crystallization Age and Implications for Alteration of Hot Desert SNC Meteorites.

Source record↗

Cosmic Ray Exposure Ages, Ar-Ar Ages, and the Origin and History of Eucrites

HED meteorites likely formed at different depths on the large asteroid 4-Vesta, but passed through Vesta-derived, km-sized intermediary bodies (Vestoids), before arriving at Earth. Most eucrites and diogenites (and all howardites) are brecciated, and impact heating disturbed or reset the K-Ar ages (and some Rb-Sr ages) of most eucrites in the time period of approx. 3.4 - 4.1 Gyr ago. Some basaltic eucrites and most cumulate eucrites, however, are not brecciated. We recently showed that the Ar-39 - Ar-40 ages for several of these eucrites tightly cluster about a value of 4.48 +/- 0.02 Gyr, and we argue that this time likely represents a single large impact event on Vesta, which ejected these objects from depth and quenched their temperatures. A different parent body has been suggested for cumulate eucrites, although the Ar-Ar ages argue for a common parent. Similarities in the cosmic-ray (space) exposure ages for basaltic eucrites and diogenites also have been used to infer a common parent body for some HEDs. Here we present CRE ages of several cumulate and unbrecciated basaltic (UB) eucrites and compare these with CRE ages of other HEDs. This comparison also has some interesting implications for the relative locations of various HED types on Vesta and/or the Vestoids.

Wakefield, Kelli↗

Geology and geochemistry of paleosols developed on the Hekpoort Basalt, Pretoria Group, South Africa

The Hekpoort paleosols comprise a regional paleoweathering horizon developed on 2.224 +/- 0.021 Ga basaltic andesite lavas at the top of the Hekpoort Formation of the Pretoria Group, Transvaal Supergroup, South Africa. In five separate profiles, from outcrops along road cuts near Waterval Onder and the Daspoort Tunnel and in three drill cores from the Bank Break Area (BB3, BB8, and BB14), the top of the paleosol is a sericite-rich zone. The sericite zone grades downward into a chlorite-rich zone. In core BB8 and in the road cut at the Daspoort Tunnel, we sampled the underlying or parent basaltic andesite into which the chlorite zone grades. We did not obtain samples of the parent material at Waterval Onder and in cores BB3 and BB14, but chemical analyses indicate that the chlorite and sericite zones in these profiles derive from underlying lavas similar to the ones we sampled in core BB8 and at the Daspoort Tunnel. The presence of apparent rip-up clasts of the paleosol in the overlying ironstones of the Strubenkop Formation in the cores from Bank Break makes it very unlikely that most of the alteration was a result of interactions with hydrothermal fluids. Desiccation cracks at the top of the paleosol that were filled with sand during the deposition of the overlying sediments at Waterval Onder point to a subaerial weathering origin. Very little, if any, Al, Ti, Zr, V, or Cr moved a discernible distance during weathering of any of the five profiles. The vertical distribution of Fe, Mg, Mn, Ni, and Co indicates that these elements were largely removed from the top of the soil during weathering. The overall abundance of these elements in each of the profiles indicates that a significant fraction of the complement lost from the top subsequently reprecipitated in the lower portion of the soil as constituents of an Fe2(+) -rich smectite. The loss of Fe from the top of the soil during weathering of the Hekpoort paleosols indicates that atmospheric PO2 was less than 8 x 10(-4) atm about 2.22 Ga. Fe2(+) -rich smectite should only precipitate during soil formation if atmospheric PCO2 is less than or equal to 2 x 10(-2) atm (Rye, Kuo, and Holland, 1995). Ca and Na were largely lost during weathering. Some Na was apparently added to the sericite zone in cores BB3, BB8, and BB14 after weathering. All five profiles are enriched in K and Rb, and most are enriched in Ba. The distribution of these elements indicates that they all were added during post-weathering hydrothermal metasomatism. Rb-Sr analysis of the paleosol at the Daspoort Tunnel indicates that metasomatism last affected that profile 1.925 +/- 0.032 Ga (Macfarlane and Holland, 1991).

Non-NASA Center↗

Crystallization Age of NWA 1460 Shergottite: Paradox Revisited

We have determined the Rb-Sr age of basaltic shergottite NWA 1460 to be 312 +/- 3 Ma, and the Sm-Nd age to be 352 +/- 30 Ma. The initial Sr and Nd isotopic compositions of NWA 1460 suggest it is an earlier melting product of a Martian mantle source region similar to those of the Iherzolitic shergottites and basaltic shergottite EETA79001, lithology B. The new ages of NWA 1460 and other recently analyzed Martian meteorites leads us to reexamine the paradox that most of the Martian meteorites appear to be younger from the majority of the Martian surface. This paradox continues to pose a challenge to determining a reliable Martian chronology.

Nyquist, L. E.↗

Ar-Ar Ages of Nakhlites Y000593, NWA998, and Nakhla and CRE Ages of NWA998

The seven known Martian nakhlites are Nakhla, Lafayette, Governador Valadares, and four recent finds from hot and cold deserts: MIL03346 from the Transantarctic Mountains, a paired group from the Yamato Mountains (Y000593, Y000749, and Y000802, and two from Morocco (NWA998 and NWA817. Radiometric ages (Sm-Nd, Rb-Sr, U-Pb, and Ar-Ar) for the first three nakhlites, along with Chassigny, fall in the range of 1.19-1.37 Gyr and may suggest a common formation age. These meteorites also show very similar cosmic-ray (space) exposure ages, suggesting a single ejection event from Mars. The ages for nakhlites are different from those of Martian shergottites, whose radiometric ages vary by nearly a factor of three (approx. 165-475 Myr) and whose space exposure ages vary over a factor of approx. 20. Shergottite ages suggest that multiple locations on the Martian surface have been sampled, whereas nakhlite data imply sampling of only one Mars surface location. Because older Martian surfaces are expected to be more abundant, it seems surprising that all nakhlites would represent only one Martian impact event. To address this issue, we are measuring the (39)Ar-(40)Ar ages of Y-000593, NWA-998, Nakhla, and MIL-03346, and the space (CRE) exposure age of NWA998. Additional information is included in the original extended abstract.

Garrison, D. H.↗

EARLY IMPACT MELTING AND SPACE EXPOSURE HISTORY OF THE PAT91501 LCHONDRITE

Collisions probably occurred frequently in the early history of the asteroid belt. Their effects, which should be recorded in meteorites, must have included heating and melting along with shock alteration of mineral textures. Some non-chondritic meteorite types e.g., eucrites and IIE and IAB irons - do indeed give evidence of extensive impact heating more than 3.4 Gyr ago. The ordinary chondrites, in contrast, show little evidence of early impact heating. The Ar-Ar and Rb-Sr ages of ordinary chondrites that experienced intense shock are for the most part relatively young, many less than 1.5 Gyr. The numerous L-chondrites with Ar- Ar ages clustering near 0.5 Gy are a well-known example. One of them, the 105-kg Chico Lchondrite, shows the effects of unusually intense heating. It is approximately 60% impact melt and likely formed as a dyke beneath a large crater when the L-chondrite parent body underwent a very large impact approximately 0.5 Gyr ago. In rare instances, older shock dates are indicated for ordinary chondrites. Dixon et al show early impact resetting of Ar-Ar ages of a few LL-chondrites including MIL 99301 at 4.23 0.03 Gyr, but in none of these stones did shock lead to extensive melting. As of 2003, searches for chondritic melts attributable to early shock had turned up only the Shaw L-chondrite, which has an Ar-Ar age of approximately 4.42 Gyr. PAT91501 is an 8.55-kg L-chondrite containing vesicles and metal-troilite nodules. It is a unique, near-total impact melt, unshocked, depleted in siderophile and chalcophile elements, and contains only approximately 10% relic chondritic material. The authors conclude that PAT91501 crystallized rapidly and from a much more homogeneous melt than did Shaw. They suggest that PAT resembles Chico and likely formed as an impact melt vein within an impact crater. To define the history of PAT, we have determined its Ar-39-Ar-40 age and measured several radioactive and stable nuclides produced during its space exposure to cosmic rays.

Bogard, Donald D.↗