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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Effects of radiation on charge-coupled devices

The effects of 1 MeV electron irradiation upon the performance of two phase, polysilicon aluminum gate CCDs are reported. Both n- and p-surface channel and n-buried channel devices are investigated using 64- and 128-stage line arrays. Characteristics measured as a function of radiation dose include: Transfer inefficiency, threshold voltage, field effect mobility, interface state density, full well signal level and dark current. Surface channel devices are found to degrade considerably at less than 10 to the 5th power rads (Si) due to the large increase in fast interface state density caused by radiation. Buried channel devices maintain efficient operation to the highest dose levels used.

Carnes, J. E.↗

Radiation Effects in Used Next Generation Nuclear Fuel Reprocessing Strategies

Given global commitments to significantly increase nuclear energy capacity, it is now more important than ever to develop efficient used nuclear fuel (UNF) management strategies to encourage widespread adoption of closed fuel cycles. To achieve this ambitious goal, a comprehensive understanding of radiation effects is essential for these next generation technologies, as radiolysis often limits longevity and performance. Here, we present new findings on: (i) the radiation robustness and performance of advanced sulfur chloride-based chlorination processes in the presence of nuclear materials (Fig. 1A); and (ii) the impacts of voloxidized uranium and rhenium complexation on monoamide-based UNF direct dissolution strategies (Fig 1B). These studies employed a combination of time-resolved electron pulse and dose accumulation gamma and electron beam irradiation techniques.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗

Simulations of coherent scattering experiments at storage ring synchrotron radiation sources in the hard x-ray range

Detailed simulations of experiments carried out at modern light sources are directly related to the most efficient and productive use of these facilities for research in multiple branches of science and technology. The “Synchrotron Radiation Workshop” computer code with its Python interface, and Sirepo web-browser-based graphical user interface, currently supports physical optics simulations of coherent X-ray scattering and imaging experiments on user-defined virtual samples. We present examples of simulations of coherent scattering experiments that are typically performed at the Coherent Hard X-ray beamline at Brookhaven National Laboratory’s (BNL) National Synchrotron Light Source II. We also present several comparisons of the simulations with the results of actual coherent X-ray scattering experiments with nano-fabricated test samples produced at BNL’s Center for Functional Nanomaterials.

36 MATERIALS SCIENCE↗

Efficient stream distributions in radiative transfer theory

This paper discusses a new, computationally-efficient method for approximating the integro-differential equation of radiative transfer with a finite set of coupled differential equations for discrete streams. The method uses recommended spatial distributions of streams that are quite different from those typically used in that they are based on the symmetry of several regular Platonic solids. To facilitate the use of such distributions, an explicit, one-parameter relationship between the physical radiance and the abstract stream is formulated. The parameter is used to determine the minimum number of streams required in the radiative transfer model. Accuracy and computational efficiency are shown to be served best by choosing a stream distribution that is invariant to a large number of three space rotations. For various values of the above-mentioned parameter, the resulting recommended stream distribution is shown to be more computationally efficient than more conventional stream distributions. Finally, the incorporation of polarization in the stream definition is described.

Whitney, C.↗

Radiation Data Portal: Connection of Radiation Measurements on Airplane Flights with Observations of Solar-Terrestrial Environment

The impact of solar radiation dramatically increases at high altitudes in the Earth’s atmosphere and in space. Therefore, continuous monitoring of the radiation environment is critical for the safety of aircraft and spacecraft crews and passengers. Addressing the problem requires a complex approach of integration of different data sources and enhancement of the visualization and search capabilities. The Radiation Portal Database represents an interactive web-based application for convenient search and visualization of in-flight radiation measurements and exploration of various properties related to the radiation environment. The primary element of the Radiation Portal back-end is a MySQL relational database that currently contains the radiation measurements obtained from the Automated Radiation Measurements for Aerospace Safety (ARMAS)device, and soft X-ray and proton fluxes from Geostationary Orbiting Environmental Satellite (GOES). The developed Application Programming Interface (API) and related Python routines allow a user to retrieve the database records directly and efficiently, without interaction with the web interface. As a use case of the Radiation Portal, we examine the properties of the ARMAS flights taken during the enhanced Solar Proton (SP) fluxes and compare them to the flights of similar time and location taken during SP-quiet periods.

SMD↗

A Study of the Ultraviolet Radiation of Hybrid X-Pinches

The results of an experimental study of hybrid X-pinches (HXPs) as sources of vacuum ultraviolet (VUV) radiation within the wavelength range of λ < 2000 Å are presented here. A KING compact low-voltage generator (45 kV, 200 kA, 190 ns) was used to feed the X-pinches. The dynamics of forming the radiating plasma of HXPs of different materials were studied using pinhole cameras with radiation receivers based on microchannel plates with a time resolution of 5 ns and a spatial resolution of 150 µm. The time structure and energy characteristics of the radiation were studied using diamond photoconducting detectors (PCDs). The spectral composition of UV radiation was investigated using a spectrograph based on the transmission grating. It has been shown that the efficiency of conversion of the capacitor-stored energy to the VUV radiation may reach 5%, whereas the fraction of soft X-rays (SXR) with quanta energies above 800 eV is no more than 3%. In this case, the source brightness reaches 2 × 10 9 W/(sr cm 2 ).

plasma UV-spectroscopy↗

Aerosol Remote Sensing in Polar Regions

Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness tau(lambda) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent alpha were calculated. Analyzing these data, the monthly mean values of tau(0.50 micrometers) and alpha and the relative frequency histograms of the daily mean values of both parameters were determined for winter-spring and summer-autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of alpha versus tau(0.50 micrometers) showed: (i) a considerable increase in tau(0.50 micrometers) for the Arctic aerosol from summer to winter-spring, without marked changes in alpha; and (ii) a marked increase in tau(0.50 micrometer) passing from the Antarctic Plateau to coastal sites, whereas alpha decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of tau(lambda) and alpha at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterize vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of tau(lambda) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface-atmosphere system over polar regions.

Sun-photometer measurements↗

Effect of Gamma Radiation on TaOₓ ECRAM

Electrochemical random access memory (ECRAM) is an emerging three-terminal nonvolatile memory (NVM) with highly controllable channel conductance which is promising for use as an analog memory (or synapse) in analog in-memory computing (IMC) systems. Energy-efficient analog IMC computing is particularly desirable for power-constrained, high-radiation environments such as satellites. However, little is known about the suitability of ECRAM for use in a total ionizing dose (TID) environment. Here, this work investigates the effect of Co-60 gamma radiation on the channel conductance and noise—two properties critical for analog IMC systems—of a TaO x -based ECRAM up to 17.3 Mrad(SiO 2 ) for both low- and high-channel-conductance state devices. A transient increase in conductance is observed in response to radiation which consists of two elements: an immediate increase in conductivity due to photocurrent and a secondary increase in conductivity, which has a slower rise and saturation and can persist for hours after exposure. This secondary, persistent photoconductivity is attributed to charging caused by hole trapping. These transient effects would not likely occur in a space environment due to the low dose rate compared with this experiment. No permanent change is found in the low conductance state (LCS) following exposure and the minor shift in the high conductance change would be less significant than the regular retention decay in this state. A permanent increase in the random telegraph noise is observed, possibly due to increased traps created in the channel. This work demonstrates that TaO x -based ECRAM is suitable for use in spaceborne analog IMC systems that are subject to significant TID.

ECRAM↗

Impacts of Dual-Use Solar (Agrivoltaics) on Crop Productivity and the Agricultural Economy in Massachusetts and Beyond

This project contributes applied research to better understand the impacts of agrivoltaics on farm microclimates, crop productivity, and economics at the farm and sector level. The site trial research is divided into two sets of site trials integrated into commercial farm and agrivoltaic operations – one set on annual vegetable and hay crops and one on perennial cranberry bog operations. The economic research developed methods for recording and evaluating changes in farm operations and costs, and on the public perception of and willingness-to-accept agrivoltaics.

14 SOLAR ENERGY↗

The limits of crop productivity

The component processes that govern yield limits in food crops are reviewed and how each process can be individually measured is described. The processes considered include absorption of photosynthetic radiation by green tissue, carbon-fixation efficiency in photosynthesis, carbon use efficiency in respiration, biomass allocation to edible products, and efficiency of photosynthesis and respiration. The factors limiting yields in optimal environments are considered.

Bugbee, Bruce↗

Passively Cooled Superconductors in Space

The objective of this project was to determine to what extent (as a function of distance from the Sun) our “Solar White” coatings could passively chill a high temperature superconductor (HTS) and maintain it in a superconducting state. The end goal is to enable the use of superconductors in space for active radiation shielding and highly efficient energy storage and retrieval. The best we were able to demonstrate during this testing was a coating with a solar absorptivity of 2.6%, which is sufficient to keep the superconductor we chose cold enough for these purposes at distances of 1.25 astronomical units (AU) from the Sun. Computations and modeling show that we would need samples with solar absorptivities of less than 1.5% for 1 AU and beyond operation. Our best tile to date was measured as having 1% absorption, which is still an order of magnitude higher than our theoretical limit. This should be achievable once manufacturing consistency is achieved. We are in the process of commercializing production of Solar White, and are hopeful that more consistent and improved results will be achieved within the coming year.

Mark Nurge↗

Unraveling radiation damage and healing mechanisms in halide perovskites using energy-tuned dual irradiation dosing

Perovskite photovoltaics have been shown to recover, or heal, after radiation damage. Here, we deconvolve the effects of radiation based on different energy loss mechanisms from incident protons which induce defects or can promote efficiency recovery. We design a dual dose experiment first exposing devices to low-energy protons efficient in creating atomic displacements. Devices are then irradiated with high-energy protons that interact differently. Correlated with modeling, high-energy protons (with increased ionizing energy loss component) effectively anneal the initial radiation damage, and recover the device efficiency, thus directly detailing the different interactions of irradiation. We relate these differences to the energy loss (ionization or non-ionization) using simulation. Dual dose experiments provide insight into understanding the radiation response of perovskite solar cells and highlight that radiation-matter interactions in soft lattice materials are distinct from conventional semiconductors. These results present electronic ionization as a unique handle to remedying defects and trap states in perovskites.

14 SOLAR ENERGY↗

Technique for Configuring an Actively Cooled Thermal Shield in a Flight System

Broad area cooling shields are a mass-efficient alternative to conductively cooled thermal radiation shielding. The shield would actively intercept a large portion of incident thermal radiation and transport the heat away using cryogenic helium gas. The design concept consists of a conductive and conformable surface that maximizes heat transfer and formability. Broad Area Cooled (BAC) shields could potentially provide considerable mass savings for spaceflight applications by eliminating the need for a rigid thermal radiation shield for cryogen tanks. The BAC consists of a network of capillary tubes that are thermally connected to a conductive shield material. Chilled helium gas is circulated through the network and transports unwanted heat away from the cryogen tanks. The cryogenic helium gas is pumped and chilled simultaneously using a specialized pulse-tube cryocooler, which further improves the mass efficiency of the system. By reducing the thermal environment temperature from 300 to 100 K, the radiative heat load on a cryogen tank could be reduced by an order of magnitude. For a cryogenic liquid propellant scenario of oxygen and hydrogen, the boiloff of hydrogen would be significantly reduced and completely eliminated for oxygen. A major challenge in implementing this technology on large tanks is that the BAC system must be easily scalable from lab demonstrations to full-scale missions. Also, the BAC shield must be conformable to complex shapes like spheres without losing the ability to maintain constant temperature throughout. The initial design maximizes thermal conductivity between the capillary tube and the conductive radiation shielding by using thin, corrugated aluminum foil with the tube running transverse to the folds. This configuration has the added benefit of enabling the foil to stretch and contract longitudinally. This allows the BAC to conform to the complex curvature of a cryogen tank, which is key to its success. To demonstrate a BAC shield system with minimal impact to current cryogen tank designs, the shielding must be applied after the final assembly of the tank and supporting structure. One method is to pre-fabricate the shield in long strips. A spool of corrugated aluminum foil with a thermally sunk aluminum capillary running through the center could then be simply wound around the cryogen tanks and encapsulated within the multi-layer insulation (MLI) blanket. Then, on orbit, the BAC would intercept thermal radiation coming in through the MLI and transport it away from the cryogen tanks. An optimization of the design could be done to take into account mass savings from thinner MLI blankets, eliminating solid thermal shields, and ultimately, a reduction in the required cryogen tank size.

Barkfknecht, Peter↗

Comparative study of crystallization kinetics and phase segregation of triple cation and methylammonium lead iodide perovskites on moisture probing using synchrotron X-ray based radiation

3D mixed perovskites have achieved substantial success in boosting solar cell efficiency, but the complicated perovskite crystal formation pathway remains mysterious. Here we present detailed crystallization kinetics of mixed perovskites FA 0.83 MA 0.17 Pb(I 0.83 Br 0.17 ) 3 , where FA is formamidinium and MA is methylammonium, with the addition of Cs + to form a triple cation perovskite (3-CAT), in a comparison with the perovskite building block MAPbI 3 (MAPI) via static grazing-incidence wide-angle X-ray scattering (GIWAXS) and micro-diffraction measurements. Spin-coated films produced α-perovskite peaks with no PbI 2 or δ-intermediate phases, which was a promising result for the 3-CAT perovskite from micro-diffraction measurements. However, the 3-CAT did not remain stable on probing with varied relative humidity (RH) conditions as segregation back to the δ-intermediate and PbI 2 phase after 10 s of exposure to an RH value of 11% was found to occur from the GIWAXS results. When RH levels were elevated to over 100%, segregation peaks of PbI 2 and δ-intermediate (2H, 4H and 6H) became conspicuous as the α-phase intensity diminished, unlike for MAPI that remains relatively stable. The possible cause of this is hydrophilic bonds that form between the 3-CAT crystals and the small annealing window of the best composition perovskite (5% Cs + ) film.

Shatsala, Miller (ORCID:0009000927230192)↗

Study of radiatively sustained cesium plasmas for solar energy conversion

The results of a study aimed at developing a high temperature solar electric converter are reported. The converter concept is based on the use of an alkali plasma to serve as both an efficient high temperature collector of solar radiation as well as the working fluid for a high temperature working cycle. The working cycle is a simple magnetohydrodynamic (MHD) Rankine cycle employing a solid electrode Faraday MHD channel. Research milestones include the construction of a theoretical model for coupling sunlight in a cesium plasma and the experimental demonstration of cesium plasma heating with a solar simulator in excellent agreement with the theory. Analysis of a solar MHD working cycle in which excimer laser power rather than electric power is extracted is also presented. The analysis predicts a positive gain coefficient on the cesium-xenon excimer laser transition.

Palmer, A. J.↗

An Exponential Luminous Efficiency Model for Hypervelocity Impact into Regolith

The flash of thermal radiation produced as part of the impact-crater forming process can be used to determine the energy of the impact if the luminous efficiency is known. From this energy the mass and, ultimately, the mass flux of similar impactors can be deduced. The luminous efficiency, Eta is a unique function of velocity with an extremely large variation in the laboratory range of under 8 km/s but a necessarily small variation with velocity in the meteoric range of 20 to 70 km/s. Impacts into granular or powdery regolith, such as that on the moon, differ from impacts into solid materials in that the energy is deposited via a serial impact process which affects the rate of deposition of internal (thermal) energy. An exponential model of the process is developed which differs from the usual polynomial models of crater formation. The model is valid for the early time portion of the process and focuses on the deposition of internal energy into the regolith. The model is successfully compared with experimental luminous efficiency data from laboratory impacts and from astronomical determinations and scaling factors are estimated. Further work is proposed to clarify the effects of mass and density upon the luminous efficiency scaling factors

Swift, Wesley R.↗

An Exponential Luminous Efficiency Model for Hypervelocity Impact into Regolith

The flash of thermal radiation produced as part of the impact-crater forming process can be used to determine the energy of the impact if the luminous efficiency is known. From this energy the mass and, ultimately, the mass flux of similar impactors can be deduced. The luminous efficiency, eta, is a unique function of velocity with an extremely large variation in the laboratory range of under 6 km/s but a necessarily small variation with velocity in the meteoric range of 20 to 70 km/s. Impacts into granular or powdery regolith, such as that on the moon, differ from impacts into solid materials in that the energy is deposited via a serial impact process which affects the rate of deposition of internal (thermal) energy. An exponential model of the process is developed which differs from the usual polynomial models of crater formation. The model is valid for the early time portion of the process and focuses on the deposition of internal energy into the regolith. The model is successfully compared with experimental luminous efficiency data from both laboratory impacts and from lunar impact observations. Further work is proposed to clarify the effects of mass and density upon the luminous efficiency scaling factors. Keywords hypervelocity impact impact flash luminous efficiency lunar impact meteoroid 1

Swift, W. R.↗

Progress toward thin-film GaAs solar cells using a single-crystal Si substrate with a Ge interlayer

Development of a technology for fabricating light-weight, high-efficiency, radiation-resistant solar cells for space applications is reported. The approaches currently adopted are to fabricate shallow homojunction n(+)/p as well as p/n AlGaAs-heteroface GaAs solar cells by organometallic chemical vapor deposition (OM-CVD) on single-crystal Si substrates using in each case, a thin Ge epi-interlayer first grown by CVD. This approach maintains the advantages of the low specific gravity of Si as well as the high efficiency and radiation-resistant properties of the GaAs solar cell which can lead to greatly improved specific power for a solar array. The growth of single-crystal GaAs epilayers on Ge epi-interlayers on Si substrates is investigated. Related solar cell fabrication is reviewed.

Yeh, Y. C. M.↗