Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Photon absorption”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10

Theoretical emergent Lyman alpha intensities from Mars.

The behavior of the Lyman alpha 1216-A intensity on Mars is presented for a range of atomic hydrogen density distributions below 200 km. Two sets of radiative transfer calculations have been performed. The first is based on spherical geometry and includes the effect of pure absorption of the resonance photons by CO2. The second set is based on the simpler plane parallel geometry and includes the effects of both pure absorption and a varying Doppler width associated with the planetary Lyman alpha line. From the plane parallel solutions, we are able to estimate and account for the effect of a varying Doppler width on our spherical model results. When pure absorption and a varying Doppler width are incorporated in the theory, the maximum change in the Lyman alpha disc intensity is a factor of about 2 over the range of hydrogen density models considered.

Strickland, D. J.↗

Two-photon lidar technique for remote sensing of atomic oxygen

A technique is proposed for remote sensing of atomic oxygen by laser excitation of a two-photon transition. Excitation at 2256 A and subsequent fluorescence at 8447 A allow probing of the mesosphere and lower thermosphere without interference by absorption. The two-photon excitation rate is calculated, and its dependence on laser power, duration, and linewidth is discussed. Values are given for remote sensing from a spacecraft at 200 km ranging down to 80 km with 1-km range resolution. Accuracies of better than 10% are expected with a 1 J, a 20-psec excitation pulse and a 1-sq-m collecting telescope.

Mcllrath, T. J.↗

Enhanced indirect optical absorption in AlAs and GaP.

Measurement and analysis of indirect interband optical absorption in GaP. Deviations from a simple indirect absorption law are shown to be consistent with those given by a model which takes into account both the variation of the energy denominators with photon energy and indirect absorption to higher-energy conduction-band valleys. The analysis of the GaP data indicates that such an analysis on data of limited absorption-constant range can provide reasonably accurate values of the direct band gap. The value of the direct band gap best fitting this model for AlAs at 6 K is 3.13 eV. In GaP and AlAs there is evidence of a higher set of extrema giving rise to an additional indirect absorption component 0.34 and 0.20 eV, respectively, above that due to the lowest-energy conduction-band minima. The strength of the absorption due to these higher-energy valleys indicates that they contain states of X sub 3 symmetry.

Dumke, W. P.↗

Method of forming silicon structures with selectable optical characteristics

Silicon and metal are coevaporated onto a silicon substrate in a molecular beam epitaxy system with a larger than stoichiometric amount of silicon so as to epitaxially grow particles of metal silicide embedded in a matrix of single crystal epitaxially grown silicon. The particles interact with incident photons by resonant optical absorption at the surface plasmon resonance frequency. Controlling the substrate temperature and deposition rate and time allows the aspect ratio of the particles to be tailored to desired wavelength photons and polarizations. The plasmon energy may decay as excited charge carriers or phonons, either of which can be monitored to indicate the amount of incident radiation at the selected frequency and polarization.

Fathauer, Robert W.↗

Optical detector having a plurality of matrix layers with cobalt disilicide particles embedded therein

Silicon and metal are coevaporated onto a silicon substrate in a molecular beam epitaxy system with a larger than stoichiometric amount of silicon so as to epitaxially grow particles of metal silicide embedded in a matrix of single crystal epitaxially grown silicon. The particles interact with incident photons by resonant optical absorption at the surface plasmon resonance frequency. Controlling the substrate temperature and deposition rate and time allows the aspect ratio of the particles to be tailored to desired wavelength photons and polarizations. The plasmon energy may decay as excited charge carriers of phonons, either of which can be monitored to indicate the amount of incident radiation at the selected frequency and polarization.

Fathauer, Robert W.↗

Unveiling the High Energy Obscured Universe: Hunting Collapsed Objects Physics

A large part of energy from space is coming from collapsing stars (SN, Hypernovae) and collapsed stars (black holes, neutron stars and white dwarfs). The peak of their energy release is in the hard-X and gamma-ray wavelengths where photons are insensitive to absorption and can travel from the edge the Universe or the central core of the Galaxy without loosing the primordial information of energy, time signature and polarization. The most efficient process to produce energetic photons is gravitational accretion of matter from a "normal" star onto a collapsed companion (L~GxMcollxdMacc/dtx( 1Rdisc)-dMacc/dt x c2), exceeding by far the nuclear reaction capability to generate high energy quanta. Thus our natural laboratory for "in situ" investigations are collapsed objects in which matter and radiation co-exist in extreme conditions of temperature and density due to gravitationally bent geometry and magnetic fields. This is a unique opportunity to study the physics of accretion flows in stellar mass and super-massive Black Holes (SMBHs), plasmoids generated in relativistic jets in galactic microQSOs and AGNs, ionised plasma interacting at the touching point of weakly magnetized NS surface, GRB/Supernovae connection, and the mysterious origins of "dark" GRB and X-ray flash.

Ubertini, P.↗

Two-photon or higher-order absorbing optical materials for generation of reactive species

Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

Cumpston, Brian↗

Two-photon or higher-order absorbing optical materials for generation of reactive species

Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

Cumpston, Brian↗

Two-Photon or Higher-Order Absorbing Optical Materials for Generation of Reactive Species

Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

Cumpston, Brian↗

Current and potential productivity of wheat for a controlled environment life support system

Several determinants of crop growth are analyzed to determine theoretical and potentially achievable productivity. These include: incident photosynthetic photon flux (PPF); percent absorption of the incident PPF by photo synthetic tissue; photosynthetic efficiency; respiratory carbon use efficiency; and harvest index. The effects of optimal environmental and cultural factors on each of these determinants are also investigated. Results indicate that an increase in the percentage of absorbed photons is responsible for most of the improvement in wheat yields in an optimal controlled environment. An integrated PPF of 150 mol/sq m per d has produced 60 g/sq m per d of grain. There is almost a linear increase in wheat yields with increasing PPF. At intermediate and equal integrated daily PPF levels, photoperiod had little effect on yield per day or energy efficiency. Decreasing temperature from 23 to 17 deg increased yield per day by 20 percent but increased the life cycle from 62 to 89 days.

Bugbee, B. G.↗

FT-IR spectroscopic studies of polycyclic aromatic hydrocarbons

Proper assessment of the hypothesis which correlates polycyclic aromatic hydrocarbons (PAHs) with the unidentified infrared emission bands requires additional experimental laboratory data. In order to address this need, thermal infrared emission studies were performed on a subset of PAHs suggested to be of astrophysical importance. It was proposed that infrared emission from interstellar PAHs occurs following absorption of an ultraviolet photon. Since energy transfer to the ground electronic state can be rapid for a species in which intersystem crossing is negligible, the emission spectrum may be viewed as resulting from an equilibrium vibrational temperature (Leger and d'Hendecourt, 1987). This has been the basis for using infrared absorption spectra to calculate the corresponding emission spectra at various temperatures. These calculations were made using room temperature infrared absorption coefficients instead of those at the temperature of interest because of the latter's unavailability. The present studies are designed to address the differences between the calculated and experimental thermal emission spectra and to provide information which will be useful in future ultraviolet induced infrared fluorescence studies. The emission spectra have been obtained for temperatures up to 825K using an emission cell designed to mount against an external port of an FT-IR spectrometer. These spectra provide information concerning relative band intensities and peak positions which is unavailable from previous calculations.

Salisbury, D. W.↗

Non-Geiger-Mode Single-Photon Avalanche Detector with Low Excess Noise

This design constitutes a self-resetting (gain quenching), room-temperature operational semiconductor single-photon-sensitive detector that is sensitive to telecommunications optical wavelengths and is scalable to large areas (millimeter diameter) with high bandwidth and efficiencies. The device can detect single photons at a 1,550-nm wavelength at a gain of 1 x 10(exp 6). Unlike conventional single photon avalanche detectors (SPADs), where gain is an extremely sensitive function to the bias voltage, the multiplication gain of this device is stable at 1 x 10(exp 6) over a wide range of bias from 30.2 to 30.9 V. Here, the multiplication gain is defined as the total number of charge carriers contained in one output pulse that is triggered by the absorption of a single photon. The statistics of magnitude of output signals also shows that the device has a very narrow pulse height distribution, which demonstrates a greatly suppressed gain fluctuation. From the histograms of both pulse height and pulse charge, the equivalent gain variance (excess noise) is between 1.001 and 1.007 at a gain of 1 x 10(exp 6). With these advantages, the device holds promise to function as a PMT-like photon counter at a 1,550- nm wavelength. The epitaxial layer structure of the device allows photons to be absorbed in the InGaAs layer, generating electron/hole (e-h) pairs. Driven by an electrical field in InGaAs, electrons are collected at the anode while holes reach the multiplication region (InAlAs p-i-n structure) and trigger the avalanche process. As a result, a large number of e-h pairs are created, and the holes move toward the cathode. Holes created by the avalanche process gain large kinetic energy through the electric field, and are considered hot. These hot holes are cooled as they travel across a p -InAlAs low field region, and are eventually blocked by energy barriers formed by the InGaAsP/ InAlAs heterojunctions. The composition of the InGaAsP alloy was chosen to have an 80 meV valance band offset with InAlAs, which is high enough to hinder the transport of the already cooled holes. Being stopped by the energy barrier, holes are accumulated at the junctions to shield the electric field, resulting in a decrease of the electric field in the multiplication region. Because the impact ionization rate is extremely sensitive to the magnitude of the electric field, the field-screening effect drastically reduces the impact ionization rate and quenches the output signals. After the avalanche pulse signal is self-quenched, the accumulated holes at the InGaAsP/ InAlAs interface escape the energy barrier through thermal excitation and tunneling and finally leave the device. The device is thus reset and ready for subsequent photon detection. This recovery time is controlled by the height of the energy barrier and the hole-cooling rate.

Zhao, Kai↗

Advances toward high spectral resolution quantum X-ray calorimetry

Thermal detectors for X-ray spectroscopy combining high spectral resolution and quantum efficiency have been developed. These microcalorimeters measure the energy released in the absorption of a single photon by sensing the rise in temperature of a small absorbing structure. The ultimate energy resolution of such a device is limited by the thermodynamic power fluctuations in the thermal link between the calorimeter and isothermal bath and can in principle be made as low as 1 eV. The performance of a real device is degraded due to noise contributions such as excess 1/f noise in the thermistor and incomplete conversion of energy into phonons. The authors report some recent advances in thermometry, X-ray absorption and thermalization, fabrication techniques, and detector optimization in the presence of noise. These improvements have resulted in a device with a spectral resolution of 17 eV FWHM, measured at 6 keV.

Moseley, S. H.↗

Airborne Demonstration of Atmospheric Oxygen Optical Depth Measurements with an Integrated Path Differential Absorption Lidar

We report on an airborne demonstration of atmospheric oxygen (O2) optical depth measurements with an Integrated Path Differential Absorption (IPDA) lidar using a fiber-based laser transmitter and photon counting detectors. Accurate atmospheric temperature and pressure measurements are needed for NASA's Active Sensing of CO2 Emissions over Nights, Days and Seasons (ASCENDS) mission. Since O2 is uniformly mixed in the atmosphere, its spectrum can be used to estimate the dry mixing ratio of CO2. In its airborne configuration, the IPDA lidar uses an Erbium Doped Fiber amplifier, a frequency doubler and single photon counting detectors to measure O2 absorption at multiple wavelengths near 765 nm. This instrument was deployed in 2013 and 2014 aboard NASA's DC-8 airborne laboratory as part of two campaigns to measure CO2 mixing ratios over a wide range of topography and weather conditions from altitudes ranging between 3 km and 13 km. In this paper we will review a summary of the results from our flights, discuss the errors that limit the precision and accuracy of the measurement and identify possible areas of improvement.

Methane↗

Two-dimensional imaging of molecular hydrogen in H2-air diffusion flames using two-photon laser-induced fluorescence

The use of a tunable ArF laser at 193.26 nm to record simultaneous single-laser-shot, planar images of molecular hydrogen and hot oxygen in a turbulent H2-air diffusion flame. Excitation spectra of fuel and oxidant-rich flame zones confirm a partial overlap of the two-photon H2 and single-photon O2 Schumann-Runge absorption bands. UV Rayleigh scattering images of flame structure and estimated detection limits for the H2 two-photon imaging are also presented.

Lempert, W.↗

Mariner 6 and 7 ultraviolet spectrometer experiment - Implications of CO2/+/, CO, and O airglow.

The Mariner 6 and 7 UV spectrometer experiments observed intense emissions from CO, O, and CO2(+) in the Martian airglow. Analysis shows that they are excited predominantly by the absorption of solar EUV photons by CO2 and constitute a major energy-loss mechanism for the thermosphere. Models of the thermospheric temperature profile and the airglow layer that demonstrate the effects of neutral chemistry and ionospheric composition are developed. With their aid, the observed CO Cameron-band emission scale height of 19 (plus or minus 4.5) km is shown to suggest an exospheric temperature of 315 (plus or minus 75) K. Consideration of other data suggests a 'best' value of about 350 K. Within the uncertainties in the excitation efficiencies and in the thermospheric cooling mechanisms, the observations are consistent with the measured electron density. There is no indication in the data that the ionosphere is modified by the solar wind below 200 km.

Stewart, A. I.↗

On the theory of H2 rotational excitation

A number of mechanisms for exciting higher-J states in the ground vibrational level are considered. Attention is given to collisions with H atoms and electrons. Other mechanisms involve a cascading down from upper vibrational levels, following absorption and reemission of photons in the Lyman and Werner bands, or a cascading down from upper vibrational levels, following formation of hydrogen molecules in excited vibrational and rotational levels. Theoretical population densities of rotational levels are shown in a graph.

Spitzer, L., Jr.↗