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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Acceleration of Near-IR Emission through Efficient Surface Passivation in Cd 3 P 2 Quantum Dots

Fast near-IR (NIR) emitters are highly valuable in telecommunications and biological imaging. The most established NIR emitters are epitaxially grown In x Ga 1-x As quantum dots (QDs), but epitaxial growth has several disadvantages. Colloidal synthesis is a viable alternative that produces a few NIR-emitting materials, but they suffer from long photoluminescence (PL) times. These long PL times are intrinsic in some NIR materials (PbS, PbSe) but are attributed to emission from bright trapped carrier states in others. We show that Cd 3 P 2 QDs possess substantial trap emission with radiative times >10 1 ns. Surface passivation through shell growth or coordination of Lewis acids is shown to accelerate the NIR emission from Cd 3 P 2 QDs by decreasing the amount of trap emission. This finding brings us one step closer to the application of colloidally synthesized QDs as quantum emitters.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Single Crystal Growth of Synthetic Sulfide- and Phosphide-Based Minerals for Physical Measurements

In this work, we review recent advances in the use of high-temperature solution growth that allow for the growth of single crystalline samples of synthetic minerals. We outline how low-melting binary or ternary solutions are attractive solvents for solution growth and provide examples of the growth of bismuthinite (Bi 2 S 3 ), galena (PbS) and parkerite (Ni 3 Bi 2 S 2 ). We then focus on the Rh-S, Pd-S and Ni-P phase spaces to discuss how the low-melting regions near transition metal-main group eutectic compositions make excellent solvents for crystal growth of several binary and ternary minerals containing both high melting and volatile elements as well as for the discovery of new materials. We end by discussing the growth of synthetic canfieldite (Ag 8 SnS 6 ) and argyrodite (Ag 8 GeS 6 ) from Ag 2 S–Sn-S-based solutions.

58 GEOSCIENCES↗
DOE OSTI2023

Particle inertial effects on radar Doppler spectra simulation

Abstract. Radar Doppler spectra observations provide a wealth of information about cloud and precipitation microphysics and dynamics. The interpretation of these measurements depends on our ability to simulate these observations accurately using a forward model. The effect of small-scale turbulence on the radar Doppler spectra shape has been traditionally treated by implementing the convolution process on the hydrometeor reflectivity spectrum and environmental turbulence. This approach assumes that all the particles in the radar sampling volume respond the same to turbulent-scale velocity fluctuations and neglects the particle inertial effect. Here, we investigate the inertial effects of liquid-phase particles on the forward modeled radar Doppler spectra. A physics-based simulation (PBS) is developed to demonstrate that big droplets, with large inertia, are unable to follow the rapid change of the velocity field in a turbulent environment. These findings are incorporated into a new radar Doppler spectra simulator. Comparison between the traditional and newly formulated radar Doppler spectra simulators indicates that the conventional simulator leads to an unrealistic broadening of the spectrum, especially in a strong turbulent environment. This study provides clear evidence to illustrate the droplet inertial effect on radar Doppler spectrum and develops a physics-based simulator framework to accurately emulate the Doppler spectrum for a given droplet size distribution (DSD) in a turbulence field. The proposed simulator has various potential applications for the cloud and precipitation studies, and it provides a valuable tool to decode the cloud microphysical and dynamical properties from Doppler radar observation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Development of an infrared polarimeter

AEROPOL infrared polarimeter was built for measurements microns between 1.1 and 3.5 microns, with a 1.5 degree field of view, using a wire grid polarization analyzer. A PbS detector is cooled by condensed Freon-13. The instrument operates under minicomputer control, giving a polarization least squares solution each 2.5 seconds. AEROPOL was flown on the NASA CV-990 aircraft, in a remote-sensing study of terrestrial cloud particle sizes and shapes.

Coffeen, D. L.↗
NASA NTRS1974

An autoranging scanning system and compatible methods of noise reduction

The autoranging scanning system discussed combines in a unique way four different methods for removing noise. The system employs a narrow-band amplifier. Other noise reduction methods make use of digital summation, convolution numbers, and the coaddition of scans. The system was designed to digitize the output of an infrared spectrometer and to record it on magnetic tape. Light passes through a mechanical light chopper and the spectrometer optics, and falls on the PbS cell to produce a signal which is amplified by the first preamplifier.

Saufley, D. C.↗
NASA NTRS1975

Airborne infrared polarimeter

An infrared polarimeter was built to measure the degree of linear polarization and the direction of vibration of radiation scattered upwards by clouds, between 1.1 and 3.5 microns, with a 1.5-deg field of view, using a rotating wire-grid polarization analyzer. A PbS detector is cooled to 192 K by condensing freon-13. This AEROPOL instrument operates under minicomputer control, giving a polarization least-squares solution every 2.5 s. The polarimeter was flown on the NASA CV-990 aircraft, in a remote-sensing study of terrestrial cloud particle sizes and shapes.

Coffeen, D. L.↗
NASA NTRS1981

Infrared absorption spectra of metal carbides, nitrides and sulfides

The infrared absorption spectra of 12 kinds of metal carbides, 11 kinds of nitrides, and 7 kinds of sulfides, a total of 30 materials, were measured and the application of the infrared spectra of these materials to analytical chemistry was discussed. The measurements were done in the frequency (wave length) range of (1400 to 400/cm (7 to 25 mu). The carbides Al4C3, B4C, the nitrides AlN, BN, Si3N4, WB, and the sulfides Al2S3, FeS2, MnS, NiS and PbS were noted to have specific absorptions in the measured region. The sensitivity of Boron nitride was especially good and could be detected at 2 to 3 micrograms in 300 mg of potassium bromide.

Kammori, O.↗
NASA NTRS1980

Near-infrared spectral imaging Michelson interferometer for astronomical applications

The design and operation of an imaging Michelson interferometer-spectrometer used for near-infrared (0.8 micron to 2.5 microns) spectral imaging are reported. The system employs a rapid scan interferometer modified for stable low resolution (250/cm) performance and a 42 element PbS linear detector array. A microcomputer system is described which provides data acquisition, coadding, and Fourier transformation for near real-time presentation of the spectra of all 42 scene elements. The electronic and mechanical designs are discussed and telescope performance data presented.

Wells, C. W.↗
NASA NTRS1982

A next-generation mapping spectrometer

Operational and design characteristics for a remote sensing instrument for aircraft and orbital use are defined. The ideal instrument would be based around two-dimensional detector arrays, silicon for the visible and very-near infrared (0.4 to 1.0 microns) and InSb or PbS for the rest of the near-infrared (out to about 2.6 microns). Spectral information would be dispersed along one axis. Thus one exposure or frame would simultaneously record a full spectrum for each pixel in a row perpendicular to the ground track. The instrument should be smart and versatile, with extensive pre-processing capability programmable from the ground. Spatial and spectral resolution, signal to noise radio, data precision, and calibration and atmospheric corrections are also discussed.

Singer, R. B.↗
NASA NTRS1983

Lead sulfide - Silicon MOSFET infrared focal plane development

A process for directly integrating photoconductive lead sulfide (PbS) infrared detector material with silicon MOS integrated circuits has been developed primarily for application in long (greater than 10,000 detector elements) linear arrays for pushbroom scanning applications. The processing technology is based on the conventional PMOS and CMOS technologies with a variation in the metallization. Results and measurements on a fully integrated eight-element multiplexer are shown.

Barrett, J. R.↗
NASA NTRS1983

Tunable diode lasers for 3-30 micron infrared operation

The tunable diode laser is now widely used in high resolution infrared spectroscopy studies, taking into account laboratory and industrial applications. The present investigation is concerned with advances related to laser performance and reliability. The advances are the result of improvements in materials and device technologies. Reliability data for broad-area Pb(1-x)Sn(x)Se lasers are considered along with performance improvements in stripe-geometry lasers, laser performance at wavelengths above 25 microns, and laser performance at wavelengths below 4 microns. Attention is given to tunable Pb-salt infrared diode lasers, mesa-stripe geometry lasers of Pb(1-x)Sn(x)Se and PbS(1-x)Se(x), and long wavelength diode laser emission observed in both Pb(1-x)Sn(x)Te and Pb(1-x)Sn(x)Se.

Linden, K. J.↗
NASA NTRS1984

Extreme incompatibility of Pb during the crystallization of magmatic iron meteorites

The partitioning behavior of Pb in the three-phase system metal-troilite-sulfide liquid was investigated. Microscopic examination and electron microprobe analysis of a polished section showed three phases--Fe metal, troilite and an Fe-S-Pb-O metallic liquid. The Pb concentration of the metallic liquid was 1.4 wt.%; the Pb contents of both the troilite and the Fe metal were below the detection limit of the electron probe. To better define the Pb concentrations of the solid phases, the same sample was analyzed for Pb and Fe using the M.I.T., Harvard and Brown ion microprobe. Even at this level of precision, some conclusions and speculations are possible: (1) The D(Pb) (troilite/metallic liquid) is low (.01 to .001) and, contrary to expectation, troilite, like metal, excludes Pb very effectively during the crystallization of metallic liquids; (2) Pb in iron meteorites is conceivably concentrated in trace phases which are less susceptible to contamination than metal and troilite; and (3) taken at face value D(Pb)(metal/troilite) is 0.1, but given the Pb and Fe ion yields from simple endmember phases (Fe, FeS, Pb, PbS), this D is more likely to be 0.05 to 0.03.

Jones, J. H.↗
NASA NTRS1986

Small-scale coronal structure, part 3

Recent observations and models pertaining specifically to solar coronal bright points (BPs) and generally to small-scale coronal structure are reviewed. Two questions were addressed: What is the degree of correspondence among various alleged signatures of BPs at different levels of atmosphere and what can PBs tell about the emerging flux spectrum of the sun?

Webb, David F.↗
NASA NTRS1988

Uniform Etching For Polycrystalline Photoconductor Films

Prewetting surface overcomes problem of nonuniformity of etching often occuring in polycrystalline films at PbS and PbSe. Believed prewetting causes etchant to attack film uniformly. Because process involves wet chemistry, inexpensive and easy to use.

Barrett, John↗
NASA NTRS1991

Life on ice, Antarctica and Mars

The study of the origin of life and the prospects for human exploration of Mars are two themes developed in a new 57-minute film, Life on Ice, Antarctica, and Mars, produced by the InnerSpace Foundation and WHRO Television for broadcast by the Public Broadcasting System (PBS). A brief explanation of the film and how it relates to the future human exploration of space is presented.

Anderson, D. T.↗
NASA NTRS1997

STS-86 Day 06 Highlights

On this sixth day of the STS-86 mission, the flight crew, Cmdr. James D. Wetherbee, Jr., Pilot Michael J. Bloomfield, Mission Specialists Scott E. Parazynski, Jean-Loup Chretien, Vladimir G. Titov, Wendy B. Lawrence and Mike Foale are seen discussing their mission objectives in an interview with CNN, PBS and the Russian media.

Source record↗
NASA NTRS2000

Infrastructure for Training and Partnershipes: California Water and Coastal Ocean Resources

The purpose of this project was to advance the existing ICESS/Bren School computing infrastructure to allow scientists, students, and research trainees the opportunity to interact with environmental data and simulations in near-real time. Improvements made with the funding from this project have helped to strengthen the research efforts within both units, fostered graduate research training, and helped fortify partnerships with government and industry. With this funding, we were able to expand our computational environment in which computer resources, software, and data sets are shared by ICESS/Bren School faculty researchers in all areas of Earth system science. All of the graduate and undergraduate students associated with the Donald Bren School of Environmental Science and Management and the Institute for Computational Earth System Science have benefited from the infrastructure upgrades accomplished by this project. Additionally, the upgrades fostered a significant number of research projects (attached is a list of the projects that benefited from the upgrades). As originally proposed, funding for this project provided the following infrastructure upgrades: 1) a modem file management system capable of interoperating UNIX and NT file systems that can scale to 6.7 TB, 2) a Qualstar 40-slot tape library with two AIT tape drives and Legato Networker backup/archive software, 3) previously unavailable import/export capability for data sets on Zip, Jaz, DAT, 8mm, CD, and DLT media in addition to a 622Mb/s Internet 2 connection, 4) network switches capable of 100 Mbps to 128 desktop workstations, 5) Portable Batch System (PBS) computational task scheduler, and vi) two Compaq/Digital Alpha XP1000 compute servers each with 1.5 GB of RAM along with an SGI Origin 2000 (purchased partially using funds from this project along with funding from various other sources) to be used for very large computations, as required for simulation of mesoscale meteorology or climate.

Siegel, David A.↗