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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Phonons of Fe-based superconductor Ca 10 Pt 4 As 8 (Fe 1- x Pt x As) 10

In this paper, we report the results of inelastic neutron scattering measurements on particular phonons of a superconducting (SC) Ca10Pt 4 As 8 (Fe 1-x Pt x As) 10 with the onset transition temperature T c ~ 33 K to investigate mainly what roles orbital fluctuation plays in Cooper pairing, where we observed a slight softening of the in-plane transverse acoustic mode corresponding to the elastic constant C 66 . This softening starts at temperature T well above the superconducting T c , as T decreases. An anomalously strong change of the scattering intensity of in-plane optical modes was observed at the M point of the pseudo tetragonal reciprocal space in the range of 35 < ω < 40 meV with decreasing T from far above T c . Finally, because this ω region mainly corresponds to the motion of Fe and As atoms in the FeAs planes, the finding presents information on the coupling between the orbital fluctuation of Fe 3d electrons and the lattice system, useful for studying the possible roles of orbital fluctuation in the pairing mechanism and/or the appearance of the so-called nematic phase.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

The electrochemical reactions of solid oxide fuel cells occur in the region where gas-phase species, electrode, and electrolyte coincide. When the electrode is an ionic insulator and the electrolyte is an electronic insulator, this triple phase boundary is assumed to have atomic dimensions. For this study, we use photoemission electron microscopy to show that the reduced surface of the electrolyte yttria-stabilized zirconia (YSZ) has a sharp electronic metal-insulator boundary near Pt negative electrodes. The electronic conductivity of the reduced YSZ allows for oxygen reduction, allowing the reduced YSZ to behave as an extended triple phase boundary. This extended triple phase boundary can be many microns in size, depending on oxygen pressure, temperature, applied voltage, and time.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2011

Atomic-scale modeling of particle size effects for the oxygen reduction reaction on Pt.

We estimate the activity of the oxygen reduction reaction on platinum nanoparticles of sizes of practical importance. The proposed model explicitly accounts for surface irregularities and their effect on the activity of neighboring sites. The model reproduces the experimentally observed trends in both the specific and mass activities for particle sizes in the range between 2 and 30 nm. The mass activity is calculated to be maximized for particles of a diameter between 2 and 4 nm. Our study demonstrates how an atomic-scale description of the surface microstructure is a key component in understanding particle size effects on the activity of catalytic nanoparticles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗