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At least 181 records · Page 10

All sources NASA NTRS DOE OSTI

NASA NTRS1973

Nonlinear analysis of a shock-loaded membrane.

Results from a computer method for analyzing the unsteady interaction of a fluid stream and a flat circular elastic membrane are presented. The loading on the membrane is assumed to be caused by the firing of a shock tube. The fluid pressures and velocities are determined from a scheme based on the numerical method of characteristics, and the membrane is analyzed using exact relations for membrane strain. The interactive solution is found to give peak stresses 40% lower than a solution which assumes a pressure invariant in space and time.

Madden, R.↗

NASA NTRS1974

Development of an improved membrane for a vapor diffusion water recovery process

Recovery of potable water from urine on manned space missions of extended duration was the objective of work aimed at the improvement of membrane performance for the vapor diffusion process (VDR). Kynar, Teflon, PVC, and polysulfone candidate membranes were evaluated from chemical, thermal, mechanical, and fabricating standpoints to determine their suitability for operation in the VDR pervaporation module. Pervaporation rates and other performance characteristics were determined in a breadboard pervaporator test rig. Kynar and Teflon membranes were demonstrated to be chemically stable at pervaporation temperatures in urine pretreated with chromic acid bactericide. The separation of the pervaporator and condenser modules, the use of a recirculating sweep gas to conduct pervaporate to the condenser, and the selection of a hollow fiber membrane configuration for pervaporator module design is recommended as a result of the investigation.

Rich, T. R.↗

NASA NTRS1975

Anion selective membrane

Experimental anion permselective membranes were prepared and tested for their suitability as cell separators in a chemical redox power storage system being developed at NASA-Lewis Research Center. The goals of long-term (1000 hr) oxidative and thermal stability at 80 C in FeCl3 and CrCl3 electrolytes were met by most of the weak base and strong base amino exchange groups considered in the program. Good stability is exhibited by several of the membrane substrate resins. These are 'styrene' divinylbenzene copolymer and PVC film. At least four membrane systems produce strong flexible films with electrochemical properties (resistivity, cation transfer) superior to those of the 103QZL, the most promising commercial membrane. The physical and chemical properties of the resins are listed.

Alexander, S. S.↗

NASA NTRS1980

Advances in membrane technology for the NASA redox energy storage system

Anion exchange membranes used in the system serve as a charge transferring medium as well as a reactant separator and are the key enabling component in this storage technology. Each membrane formulation undergoes a series of screening tests for area-resistivity, static (non-flow) diffusion rate determination, and performance in Redox systems. The CDIL series of membranes has, by virtue of its chemical stability and high ion exchange capacity, demonstrated superior properties in the redox environment. Additional resistivity results at several acid and iron solution concentrations, iron diffusion rates, and time dependent iron fouling of the various membrane formulations are presented in comparison to past standard formulations.

Ling, J. S.↗

NASA NTRS1983

Self-Cleaning Tubular-Membrane Module

Tubular membranes made self-cleaning with aid of flow reversing valve. Sponge balls scrub membrane surfaces as they travel inside membrane tubes. A four-way flow-reversal valve automatically reverses flow in tubes at preset intervals so sponge balls reciprocate along tubes. Baskets at ends of tubes prevent sponges from escaping. Automatic cleaning feature added to existing membrane processing equipment with minimal modifications.

Sarbolouki, M. N.↗

NASA NTRS1983

Preparation, characterization, physical testing and performance of flurocarbon membranes and separators

The direct fluorination method of converting carefully selected hydrocarbon substrates to fluorinated membranes was successfully applied to produce promising, novel membranes for electrochemical devices. A family of polymer blends was identified which permits wide latitude in the concentration of both crosslinks and carboxyl groups in hydrocarbon membranes. The membranes of paragraph two were successfully fluorinated.

Lagow, R. J.↗

NASA NTRS1982

Basic investigation into the electrical performance of solid electrolyte membranes

The electrical performance of solid electrolyte membranes was investigated analytically and the results were compared with experimental data. It is concluded that in devices that are used for pumping oxygen the major power losses have to be attributed to the thin film electrodes. Relations were developed by which the effectiveness of tubular solid electrolyte membranes can be determined and the optimum length evaluated. The observed failure of solid electrolyte tube membranes in very localized areas is explained by the highly non-uniform current distribution in the membranes. The analysis points to a possible contact resistance between the electrodes and the solid electrolyte material. This possible contact resistance remains to be investigated experimentally. It is concluded that film electrodes are not appropriate for devices which operate with current flow, i.e., pumps though they can be employed without reservation in devices that measure oxygen pressures if a limited increase in the response time can be tolerated.

Richter, R.↗

NASA NTRS1982

Finite element analysis of wrinkling membranes

The finite element analysis of wrinkling membranes was investigated. The determination of stresses and deformations within large partly wrinkled membrane surfaces is a problem of significant technical interest in such areas as conceptual design and analysis of ultra lightweight spacecraft structures. A closed-form solution to an axisymmetric problem involving partial wrinkling of an inflated shallow membrane was obtained. In particular, a membrane in the shape of a sperical annulus was considered. The outer edge of the annulus was assumed to be fixed so that no displacements occur along the outer perimeter. The inner edge is assumed to be clamped to a rigid movable plug. Solutions for the complete stress, strain, and displacement fields under the assumption of inextensional material behavior are presented for the case of pure torsional loads applied to the plug, and for the case of pure axial loads applied to the plug.

Miller, R. K.↗

NASA NTRS1983

Polymer thick-film conductors and dielectrics for membrane switches and flexible circuitry

The fabrication and operation of membrane switches are discussed. The membrane switch functions as a normally open, momentary contact, low-voltage pressure-sensitive device. Its design is a three-layer sandwich usually constructed of polyester film. Conductive patterns are deposited onto the inner side of top and bottom sheets by silk screening. The center spacer is then placed between the two circuit layers to form a sandwich, generally held together by an adhesive. When pressure is applied to the top layer, it flexes through the punched openings of the spacer to establish electrical contact between conductive pads of the upper and lower sheets, momentarily closing the circuit. Upon release of force the top sheet springs back to its normal open position. The membrane touch switch is being used in a rapidly expanding range of applications, including instrumentation, appliances, electronic games and keyboards. Its board acceptance results from its low cost, durability, ease of manufacture, cosmetic appeal and design flexibility. The principal electronic components in the membrane switch are the conductor and dielectric.

Nazarenko, N.↗

NASA NTRS1984

Method for the preparation of thin-skinned asymmetric reverse osmosis membranes and products thereof

A method for preparing water insoluble asymmetric membranes from water soluble polymers is discussed. The process involves casting a film of the polymer, partially drying it, and then contacting it with a concentrated solution of a transition metal salt. The transition metal ions render the polymer insoluable and are believed to form a complex with it. Optionally, the polymer is crosslinked with heat or radiation. The most preferred polymer is poly(vinyl alcohol). The most preferred complexing salt is copper sulfate. The process and the metal ion linked membranes are discussed. The membranes are reverse osmosis membranes.

Wydeven, T. J.↗

NASA NTRS1983

Static shape forming for an electrostatically controlled membrane mirror

A design concept is described permitting the static construction of a flexible membrane reflector for use in a radiometer spacecraft. The scheme utilizes electrostatic forces to actively shape the membrane toward a specified reflector surface with a required degree of precision. The formulations of the required electrostatic attractive forces, and stress and strain distributed in the membrane are presented in this paper in terms of curvilinear coordinates. An example is given to illustrate a variety of spherical membrane characteristics associated with different boundary conditions.

Juang, J. N.↗

NASA NTRS1989

Hydrogen-oxygen proton-exchange membrane fuel cells and electrolyzers

Hydrogen-oxygen SPE fuel cells and SPE electrolyzers (products of Hamilton Standard) both use a Proton-Exchange Membrane (PEM) as the sole electrolyte. The SPE cells have demonstrated a ten year life capability under load conditions. Ultimate life of PEM fuel cells and electrolyzers is primarily related to the chemical stability of the membrane. For perfluorocarbon proton-exchange membranes an accurate measure of the membrane stability is the fluoride loss rate. Millions of cell hours have contributed to establishing a relationship between fluroride loss rates and average expected ultimate cell life. Several features were introduced into SPE fuel cells and SPE electrolyzers such that applications requiring greater than or equal to 100,000 hours of life can be considered. Equally important as the ultimate life is the voltage stability of hydrogen-oxygen fuel cells and electrolyzers. Here again the features of SPE fuel cells and SPE electrolyzers have shown a cell voltage stability in the order of 1 microvolt per hour. That level of stability were demonstrated for tens of thousands of hours in SPE fuel cells at up to 500 amps per square foot (ASF) current density. The SPE electrolyzers have demonstrated the same at 1000 ASF. Many future extraterrestrial applications for fuel cells require that they be self recharged. To translate the proven SPE cell life and stability into a highly reliable extraterrestrial electrical energy storage system, a simplification of supporting equipment is required. Static phase separation, static fluid transport and static thermal control will be most useful in producting required system reliability. Although some 200,000 SPE fuel cell hours were recorded in earth orbit with static fluid phase separation, no SPE electrolyzer has, as yet, operated in space.

Baldwin, R.↗

NASA NTRS1988

Dehumidification via membrane separation for space-based applications

The paper describes the development of a membrane-based dehumidification process for space-based applications, such as spacecraft cabins and EVA space suits. Results presented are from: (1) screening tests conducted to determine the efficacy of various membranes to separate water vapor from air, and (2) parametric and long-term tests of membranes operated at conditions that simulate the range of environmental conditions (e.g., temperature and relative humidity) expected in the planned Space Station. Also included in this paper is a discussion of preliminary designs of membrane-based dehumidification processes for the Space Station and EVA space suits. These designs result in compact and energy-efficient systems that offer significant advantages over conventional dehumidification processes.

Gienger, Jane Kucera↗

NASA NTRS1989

Hydrogen-oxygen proton-exchange membrane fuel cells and electrolyzers

Hydrogen-oxygen solid polymer electrolyte (SPE) fuel cells and SPE electrolyzers (products of Hamilton Standard) both use a Proton-Exchange Membrane (PEM) as the sole electrolyte. These solid electrolyte devices have been under continuous development for over 30 years. This experience has resulted in a demonstrated ten-year SPE cell life capability under load conditions. Ultimate life of PEM fuel cells and electrolyzers is primarily related to the chemical stability of the membrane. For perfluorocarbon proton exchange membranes an accurate measure of the membrane stability is the fluoride loss rate. Millions of cell hours have contributed to establishing a relationship between fluoride loss rates and average expected ultimate cell life. This relationship is shown. Several features have been introduced into SPE fuel cells and SPE electrolyzers such that applications requiring greater than or equal to 100,000 hours of life can be considered. Equally important as the ultimate life is the voltage stability of hydrogen-oxygen fuel cells and electrolyzers. Here again the features of SPE fuel cells and SPE electrolyzers have shown a cell voltage stability in the order of 1 microvolt per hour. That level of stability has been demonstrated for tens of thousands of hours in SPE fuel cells at up to 500 amps per square foot (ASF) current density.

Baldwin, R.↗

NASA NTRS1989

Investigation of humidity control via membrane separation for advanced Extravehicular Mobility Unit (EMU) application

This paper describes the development of a membrane-based process for dehumidifying the Extravehicular Mobility Unit (EMU). The membrane process promises to be smaller, lighter, and more energy efficient than the other technologies for dehumidification. The dehydration membranes were tested for 90 days at conditions expected to be present in the EMU. The results of these tests indicate that membrane-based technology can effectively control humidity in the EMU.

Newbold, D. D.↗

NASA NTRS1990

Absence of first-order unbinding transitions of fluid and polymerized membranes

Unbinding transitions of fluid and polymerized membranes are studied by renormalization-group (RG) methods. Two different RG schemes are used and found to give rather consistent results. The fixed-point structure of both RG's exhibits a complex behavior as a function of the decay exponent tau for the fluctuation-induced interaction of the membranes. For tau greater than tau(S2) interacting membranes can undergo first-order transitions even in the strong-fluctuation regime. These estimates for tau(S2) imply, however, that both fluid and polymerized membranes unbind in a continuous way in the absence of lateral tension.

Grotehans, Stefan↗

NASA NTRS1989

The modeling of gas phase permeation through iron and nickel membranes

The gas phase permeation of hydrogen through metal membranes encompasses many kinetic processes. This paper reviews a permeation model which incorporates second order gas-surface reaction kinetics with simple bulk diffusion. The model is used to investigate the effect of this particular surface reaction of steady-state permeation. The dependence of the steady-state permeation flux on temperature, pressure, and thickness of the membrane has been calculated. The model predicts that the bulk controlled steady-state flux will change to a surface limited steady-state flux as either the temperature or thickness of the membrane is reduced. Finally, using independently derived parameters, the model is compared with permeation measurements on iron and nickel membranes.

Kuhn, David K.↗

NASA NTRS1991

Deflection And Stress In Preloaded Square Membrane

Theoretical analysis yields equations for transverse deflection of, and stresses in, square membrane subject to both uniform transverse load and tension preloads applied uniformly along the edges. Follows energy/virtual-displacement approach. Basic equation expresses strain energy in membrane as double integral, over x and y coordinates of square, of function of longitudinal strains, shear strain, thickness of membrane, and Young's modulus and Poissons's ratio of membrane material.

Hermida, Alfonso↗