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At least 181 records · Page 10

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DOE OSTI2020

Three-Dimensional Imaging and Quantification of Gas Storativity in Nanoporous Media via X-rays Computed Tomography

This study provides the engineering science underpinnings for improved characterization and quantification of the interplay of gases with kerogen and minerals in shale. Natural nanoporous media such as shale (i.e., mudstone) often present with low permeability and dual porosity, making them difficult to characterize given the complex structural and chemical features across multiple scales. These structures give nanoporous solids a large surface area for gas to sorb. In oil and gas applications, full understanding of these media and their sorption characteristics are critical for evaluating gas reserves, flow, and storage for enhanced recovery and CO 2 sequestration potential. Other applications include CO 2 capture from industrial plants, hydrogen storage on sorbent surfaces, and heterogeneous catalysis in ammonia synthesis. Therefore, high-resolution experimental procedures are demanded to better understand the gas–solid behavior. In this study, CT imaging was applied on the sub-millimeter scale to shale samples (Eagle Ford and Wolfcamp) to improve quantitative agreement between CT-derived and pulse decay (mass balance) derived results. Improved CT imaging formulations are presented that better match mass balance results, highlighting the significance of gas sorption in complex nanoporous media. The proposed CT routine implemented on the Eagle Ford sample demonstrated a 17% error reduction (22% to 5%) when compared to the conventional CT procedure. These observations are consistent in the Wolfcamp sample, emphasizing the reliability of this technique for broader implementation of digital adsorption studies in nanoporous geomaterials.

42 ENGINEERING↗

NASA NTRS2012

Effect of Non-Equilibrium Surface Thermochemistry in Simulation of Carbon Based Ablators

This study demonstrates that coupling of a material thermal response code and a flow solver using non-equilibrium gas/surface interaction model provides time-accurate solutions for the multidimensional ablation of carbon based charring ablators. The material thermal response code used in this study is the Two-dimensional Implicit Thermal-response and AblatioN Program (TITAN), which predicts charring material thermal response and shape change on hypersonic space vehicles. Its governing equations include total energy balance, pyrolysis gas mass conservation, and a three-component decomposition model. The flow code solves the reacting Navier-Stokes equations using Data Parallel Line Relaxation (DPLR) method. Loose coupling between the material response and flow codes is performed by solving the surface mass balance in DPLR and the surface energy balance in TITAN. Thus, the material surface recession is predicted by finite-rate gas/surface interaction boundary conditions implemented in DPLR, and the surface temperature and pyrolysis gas injection rate are computed in TITAN. Two sets of nonequilibrium gas/surface interaction chemistry between air and the carbon surface developed by Park and Zhluktov, respectively, are studied. Coupled fluid-material response analyses of stagnation tests conducted in NASA Ames Research Center arc-jet facilities are considered. The ablating material used in these arc-jet tests was Phenolic Impregnated Carbon Ablator (PICA). Computational predictions of in-depth material thermal response and surface recession are compared with the experimental measurements for stagnation cold wall heat flux ranging from 107 to 1100 Watts per square centimeter.

Chen, Yih-Kanq↗

NASA NTRS1995

VRA Modeling, phase 1

The destruction of organic contaminants in waste water for closed systems, such as that of Space Station, is crucial due to the need for recycling the waste water. A co-current upflow bubble column using oxygen as the gas phase oxidant and packed with catalyst particles consisting of a noble metal on an alumina substrate is being developed for this process. The objective of this study is to develop a plug-flow model that will predict the performance of this three phase reactor system in destroying a multicomponent mixture of organic contaminants in water. Mass balances on a series of contaminants and oxygen in both the liquid and gas phases are used to develop this model. These mass balances incorporate the gas-to-liquid and liquid-to-particle mass transfer coefficients, the catalyst effectiveness factor, and intrinsic reaction rate. To validate this model, a bench scale reactor has been tested at Michigan Technological University at elevated pressures (50-83 psig,) and a temperature range of 200 to 290 F. Feeds consisting of five dilute solutions of ethanol (approx. 10 ppm), chlorobenzene (approx. 20 ppb), formaldehyde (approx. 100 ppb), dimethyl sulfoxide (DMSO approx. 300 ppb), and urea (approx. 20 ppm) in water were tested individually with an oxygen mass flow rate of 0.009 lb/h. The results from these individual tests were used to develop the kinetic parameter inputs necessary for the computer model. The computer simulated results are compared to the experimental data obtained for all 5 components run in a mixture on the differential test column for a range of reactor contact times.

Kindt, Louis M.↗

NASA NTRS2021

Estimation of Thermodynamic and Dynamic Contributions to Sea Ice Growth in the Central Arctic Using ICESat-2 and MOSAiC SIMBA Buoy Data

The fine spatial resolution of the ICESat-2 (IS2) satellite altimeter allows monitoring the evolution of sea ice thickness with detailed dynamic information (e.g. ridges and leads). In this study, we first assess the ability of IS2 to estimate thermodynamic ice growth and dynamic thickening during the ice-growing season in the central Arctic Ocean. As an indicator of the thermodynamic ice growth, we use 10 thermistor string-based sea ice mass balance array (SIMBA) buoys deployed at a scale of ~ 50 km from the Icebreaker Polarstern during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition. We collect IS2 data within 20 km buffer distance from the individual buoys, and calculate the mode, median, and mean of the IS2-derived ice thickness. The IS2 modal thickness shows the least bias (−0.169 m) with the buoy ice thickness, representing level ice thickness. In addition, the increasing rate of the IS2 modal thickness is close to the thermodynamic ice growth with a small bias of −0.054 cm/day. However, the increasing rates of the IS2 median and mean thickness are greater than the thermodynamic ice growth by about 0.114 cm/day and 0.198 cm/day, respectively, because they also include ice growth caused by thickness redistribution during dynamic deformation. The dynamic contributions may account for 26.1 ± 10.3% and 34.4 ± 10.1% of the total increase of the IS2 median and mean thickness, respectively. Within a ~ 50 km radius area from the MOSAiC Central Observatory, IS2 measurements exhibit that the ridge fraction increased from <2% in November to ~ 4% in March (~0.029%/day of average increasing rate) and ridge height increased about 0.047 cm/day during the same period. However, lead formation does not show significant contributions to the dynamic ice thickening because leads are temporary features lasting only 2–3 days. Although there are considerable uncertainties in IS2 ice thickness estimation and IS2-buoy thickness comparison, this study emphasizes the importance of combining measurements by IS2 and SIMBA buoys to explain the regional sea ice mass balance with separating the thermodynamic and dynamic contributions.

satellite altimeter↗

NASA NTRS2016

Resource Tracking Model Updates and Trade Studies

The Resource tracking model has been updated to capture system manager and project manager inputs. Both the Trick/GUNNS RTM simulator and the RTM mass balance spreadsheet have been revised to address inputs from system managers and to refine the way mass balance is illustrated. The revisions to the RTM included addition of a Plasma Pyrolysis Assembly (PPA) to recover hydrogen from Sabatier reactor methane which was vented in the prior version of the RTM. The effect of the PPA on the overall balance of resources in an exploration vehicle is illustrated in the increased recycle of vehicle oxygen. Additionally simulation of EVAs conducted from the exploration module was added. Since the focus of the exploration module is to provide a habitat during deep space operations the EVA simulation approach to EVA is based on ISS EVA protocol and processes. Case studies have been run to show the relative effect of performance changes on vehicle resources.

Chambliss, Joe↗

NASA NTRS2016

Resource Tracking Model Updates and Trade Studies

The Resource Tracking Model has been updated to capture system manager and project manager inputs. Both the Trick/General Use Nodal Network Solver Resource Tracking Model (RTM) simulator and the RTM mass balance spreadsheet have been revised to address inputs from system managers and to refine the way mass balance is illustrated. The revisions to the RTM included the addition of a Plasma Pyrolysis Assembly (PPA) to recover hydrogen from Sabatier Reactor methane, which was vented in the prior version of the RTM. The effect of the PPA on the overall balance of resources in an exploration vehicle is illustrated in the increased recycle of vehicle oxygen. Case studies have been run to show the relative effect of performance changes on vehicle resources.

Chambliss, Joe↗

NASA NTRS1999

Glacier and Ice Shelves Studies Using Satellite SAR Interferometry

Satellite radar interferometry is a powerful technique to measure the surface velocity and topography of glacier ice. On ice shelves, a quadruple difference technique separates tidal motion from the steady creep flow deformation of ice. The results provide a wealth of information about glacier grounding lines , mass fluxes, stability, elastic properties of ice, and tidal regime. The grounding line, which is where the glacier detaches from its bed and becomes afloat, is detected with a precision of a few tens of meters. Combining this information with satellite radar altimetry makes it possible to measure glacier discharge into the ocean and state of mass balance with greater precision than ever before, and in turn provide a significant revision of past estimates of mass balance of the Greenland and Antarctic Ice Sheets. Analysis of creep rates on floating ice permits an estimation of basal melting at the ice shelf underside. The results reveal that the action of ocean water in sub-ice-shelf cavities has been largely underestimated by oceanographic models and is the dominant mode of mass release to the ocean from an ice shelf. Precise mapping of grounding line positions also permits the detection of grounding line migration, which is a fine indicator of glacier change, independent of our knowledge of snow accumulation and ice melting. This technique has been successfully used to detect the rapid retreat of Pine Island Glacier, the largest ice stream in West Antarctica. Finally, tidal motion of ice shelves measured interferometrically provides a modern, synoptic view of the physical processes which govern the formation of tabular icebergs in the Antarctic.

Rignot, Eric↗

DOE OSTI2021

Integrated atomic force microscopy and x-ray irradiation for in situ characterization of radiation-induced processes

Understanding radiation-induced chemical and physical transformations at material interfaces is important across diverse fields, but experimental approaches are often limited to either ex situ observations or in situ electron microscopy or synchrotron-based methods in which cases the radiation type and dose are inextricably tied to the imaging basis itself. In this work we overcome this limitation by demonstrating integration of an X-ray source with an atomic force microscope to directly monitor radiolytically-driven interfacial chemistry at the nanoscale. We illustrate the value of in situ observations by examining effects of radiolysis on material adhesion forces in aqueous solution, as well as examining the production of alkali nitrates at the interface between an alkali halide crystal surface and air. For the examined salt-air interface, direct visualization under flexible experimental conditions greatly extends prior observations by enabling the transformation process to be followed comprehensively from source-to-sink with mass balance quantitation. Overall, our novel rad-AFM opens doors into understanding the dynamics of radiolytically-driven mass transfer and surface alteration at the nanoscale in real-time.

47 OTHER INSTRUMENTATION↗

NASA NTRS1997

Global Geodetic Signatures of the Antarctic Ice Sheet

Four scenarios of present day Antarctic ice sheet mass change are developed from comprehensive reviews of the available glaciological and oceanographic evidence. The gridded scenarios predict widely varying contributions to secular sea level change xi ranging from -1.1 to 0.45 mm/yr, and predict polar motion m and time-varying low-degree gravitational coefficients J(sub l) that differ significantly from earlier estimates. A reasonably linear relationship between the rate of sea level change from Antarctica xi(sub A) and the predicted Antarctic J(sub l) is found for the four scenarios. This linearity permits a series of forward models to be constructed that incorporate the effects of ice mass changes in Antarctica, Greenland, and distributed smaller glaciers, as well as postglacial rebound (assuming the ICE-3G deglaciation history), with the goal of obtaining optimum reconciliation between observed constraints on J(sub l) and sea level rise xi. Numerous viable combinations of lower mantle viscosity and hydrologic sources are found that safely "observed" in the range of 1 to 2-2.5 mm/yr and observed J(sub l) for degrees 2, 3, and 4. In contrast, rates of global sea level rise above 2.5 mm/yr are inconsistent with available J(sub l) observations. The successful composite models feature a pair of lower mantle viscosity solutions arising from the sensitivity of J(sub l) to glacial rebound. The paired values are well separated at xi = 1 mm/yr, but move closer together as xi is increased, and, in fact, merge around xi = 2 - 2.5 mm/yr, revealing an intimate relation between xi and preferred lower mantle viscosity. This general pattern is quite robust and persists for different J(sub l) solutions, for variations in source assumptions, and for different styles of lower mantle viscosity stratification. Tighter J(sub l) constraints for l greater than 2 may allow some viscosity stratification schemes and source assumptions to be excluded in the future. For a given total observed xi the sea level rise from Antarctica xi(sub A) is tightly constrained and ranges from 0 to + 1 mr/yr (corresponding to an ablating ice sheet) as estimates of xi are raised from 1 to 2.5 mm/yr. However, when the degree 3 zonal harmonic constraint is removed, the solutions show little sensitivity to Antarctic mass balance, emphasizing the need for a well determined odd-degree secular zonal harmonic for determining polar ice mass balance.

James, Thomas S.↗

NASA NTRS1942

Flutter calculations in three degrees of freedom

The present paper is a continuation of the general study of flutter published in NACA reports nos. 496 and 685. The paper is mainly devoted to flutter in three degrees of freedom (bending, torsion, and aileron) for which a number of selected cases have been calculated and presented in graphical form. The results are analyzed and discussed with regard to the effects of structural damping, of fractional-span ailerons, and of mass-balancing. The analysis shows that more emphasis should be put on the effect of structural damping and less on mass-balancing. The conclusion is drawn that a definite minimum amount of structural damping, which is usually found to be present, is essential in the calculations for an adequate description of the flutter case. Theoretical flutter predictions are thus brought into closer agreement with the facts of experience. A brief discussion is included of a particular biplane that had experienced flutter at about 200 miles per hour. Some simplifications have been achieved in the method of calculation. (author)

Theodorsen, Theodore↗

NASA NTRS1999

A Preliminary Model for Spacecraft Propulsion Performance Analysis Based on Nuclear Gain and Subsystem Mass-Power Balances

Rapid transportation of human crews to destinations throughout the solar system will require propulsion systems having not only very high exhaust velocities (i.e., I(sub sp) >= 10(exp 4) to 10(exp 5) sec) but also extremely low mass-power ratios (i.e., alpha <= 10(exp -2) kg/kW). These criteria are difficult to meet with electric propulsion and other power-limited systems, but may be achievable with propulsion concepts that use onboard power to produce a net gain in energy via fusion or some other nuclear process. This paper compares the fundamental performance of these gain-limited systems with that of power-limited systems, and determines from a generic power balance the gains required for ambitious planetary missions ranging up to 100 AU. Results show that energy gain reduces the required effective mass-power ratio of the system, thus enabling shorter trip times than those of power-limited concepts.

Chakrabarti, S.↗

DOE OSTI2023

Modeling starch dynamics from seasonal variations of photosynthesis, growth and respiration

Abstract Nonstructural carbohydrates (NSCs) buffer differences in plant carbon supply (photosynthesis) and demand (respiration, growth, etc.), but the regulation of their dynamics remains unresolved. Seasonal variations in NSCs are well-documented, but differences in the time-average, amplitude, phase and other characteristics across ecosystems and functional types lack explanation; furthermore, observed dynamics do not always match expectations. The failure to match observed and expected dynamics has stimulated debate on whether carbon supply or demand drives NSC dynamics. To gain insight into how carbon supply and demand drive seasonal NSC dynamics, we derive a simple model of NSC dynamics based on carbon mass balance and linearizing the NSC demand to determine how supply-driven and demand-driven seasonal NSC dynamics differ. We find that supply-driven and demand-driven dynamics yield distinct timings of seasonal extrema, and supply overrides demand when carbon supply is low in winter (e.g., at high latitudes). Our results also suggest that NSC dynamics often lag changes carbon mass balance. We also predict differences in NSC dynamics across mass, suggesting that saplings are more dynamic and respond more quickly to the environment than mature trees. Our findings suggest that substrate-dependent regulation with environmental variation is sufficient to generate complex NSC dynamics.

Forestry↗

NASA NTRS1989

Time-dependent viscous incompressible Navier-Stokes equations - The finite difference Galerkin formulation and streamfunction algorithms

Numerical techniques are developed to solve the Navier-Stokes equations for unsteady incompressible flow. The extension of the finite-difference Galerkin (FDG) method of Stephens et al. (1984) to the continuous-time case in two or three space dimensions is explained, and the numerical implementation of the method is discussed with particular attention to the staggered-MAC-grid primitive-variable discretization, the application of discrete mass balance to avoid problems inherent in FDG schemes, the direct interpretation of the FDG expansion variables as a discrete streamfunction, and a mass-balance approach to two-dimensional problems with throughflow or obstacles. Numerical results are presented graphically for the evolution of asymptotic steady flow in a driven cavity at Reynolds number 400, 1000, or 3200; good agreement with published experimental data is demonstrated, with accurate predictions of secondary-vortex formation from wall bubble recirculations at Reynolds number 1000.

Goodrich, John W.↗

DOE OSTI2023

Ultrasonic degradation of GenX (HFPO-DA) – Performance comparison to PFOA and PFOS at high frequencies

Sonolytic degradation kinetics of hexafluoropropylene oxide-dimer acid (HFPO-DA or GenX) were studied for the first time at four high ultrasonic frequencies (375, 580, 860 and 1,140kHz) and three power densities (200, 300 and 400W/L), and compared to the degradation of previously studied perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). The frequency of 580kHz displayed the highest degradation of all three PFAS tested. Within each frequency, the degradation performance increased consistently with increasing power density. Degradation rates were highest for GenX over PFOA to PFOS (k GenX = 0.0501 min -1 , k PFOA = 0.0444 min -1 , k PFOS 0.0153 min -1 ), which is in direct agreement with their reported thermal stability (PFOS > PFOA > GenX). No known by-product formation as expected from the literature on truncation mechanism was detected in the samples (i.e. shorter chain carboxylic acid PFAS). Further, fluorine mass balance experiments at 580kHz and 400W/ L confirmed that GenX defluorinated fastest among the three tested PFAS and had lowest loss of fluorine in the mass balance. Degradation experiments with a mixture of all three PFAS displayed lower degradation rates than the individual experiments, where PFOA exhibited the largest reduction in degradation rate (by 31%), followed by GenX (by 19%), and finally by PFOS (by 17%). Overall, our study demonstrates that ultrasound can provide effective destruction of different PFAS (70-90% fluorine from mitigated PFAS was detected as inorganic fluoride) with a similar energy demand to alternative PFAS treatment methods reported in literature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

MODELING AND TESTING OF A NOVEL ULTRA-LOW TEMPERATURE SCO2 OPPOSING PISTON EXPANDER

The Flameless Pressurized Oxy-Combustion (FPO) cycle, a novel flexible fuel technology, is being developed into a large pilot. This effort seeks to complete the preliminary engineering and planning of a 25 MWth Pilot Plant that will demonstrate the technology for scale-up to a commercial unit. The technology, pioneered by ITEA at the 5 MWth scale, must be brought to a higher technology readiness level (TRL) to be viable at the commercial scale. The 25 MWth pilot cycle was optimized for cost and technology development and demonstration. Preliminary drawings, layouts, and plans were defined. Process flow diagrams were used to describe the pilot configuration in greater detail. A heat and mass balance with stream data was created. A master equipment list specified the operating conditions for major pieces of equipment within the pilot using this heat and mass balance. The 25 MWth FPO pilot is assessed for environmental performance. A test campaign is developed to assess the type of test and number of hours required for pilot demonstration. The environmental performance is compared against projected performance at the commercial scale. This project builds upon extensive evaluation of the techno-economic performance of the FPO technology already performed by ITEA. This includes system improvements, such as the addition of a turbo-expander to the flue gas stream. Some of the performance-enhancing components are not as well defined as others. The primary goal of this effort was to bring all of the core cycle components to the same level of design maturity. A techno-economic assessment (TEA) evaluated the FPO technology at the commercial scale in comparison to the NETL baseline cases. The reference plants were used in combination with proprietary equipment estimates to build a plant capital cost and cost of electricity evaluation. FPO performed better than the sub-bituminous post-combustion capture cases. Further preliminary estimates of improvements to the FPO cycle show even further gains when compared to conventional carbon capture methods.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2021

DEVELOPMENT OF A 25 MWTH FLAMELESS PRESSURIZED OXY-COMBUSTION PILOT

20 FOSSIL-FUELED POWER PLANTS↗

NASA NTRS1977

Test of a model for trace element partition during closed-system solidification of a silicate liquid

Trace-element concentrations in separated minerals and rock fragments from a coarsely crushed and sieved sample of medium-grained lunar basalt are determined by high-precision instrumental neutron activation analysis for three main purposes. These are: (1) to test a previously proposed model for describing trace-element behavior during solidification of a silicate liquid under conditions of a closed system; (2) to compare trace-element concentrations among different size fractions of a comminuted basalt; and (3) to investigate small-scale heterogeneity within a single medium-grained basalt. It is found that an excellent mass balance for the whole rock is attained in terms of the trace-element concentrations of the component minerals and mesostasis, that the mixing model describing this mass balance yields a superior modal analysis for the whole rock, and that different size fractions of the coarsely crushed basalt vary in mineral composition. The closed-system model is shown to account properly for the average behavior of the trace elements during solidification of the basalt, and values of distribution coefficients are obtained for incompatible elements in that rock.

Haskin, L. A.↗

NASA NTRS1972

Survey of the seasonal snow cover of Alaska

The author has identified the following significant results. The delineation of the transient snow cover can generally be made directly from any of the RBV of MSS images. On many glaciers, however, there seems to be a relatively small difference between the reflectivities of snow and ice in the visible portion of the spectrum (corresponding to MSS bands 4 and 5). On the other hand, the reflectivity is distinctly lower for ice than for snow in the near infrared (MSS bands 6 and 7). By applying the sensors of the latter spectral bands the position of the transient snowline, indicative of the mass balance, can in many cases be determined with what appears to be a satisfactory accuracy. This circumstance should prove especially useful in studies of regional variations of glacier mass balances. It had been found that the effect of winds early in the fall seasons can be seen on the arctic slope when a light dusting of snow is present. Winds channeled by topography redistribute the snow and actually remove it from regions. After freeze up has occurred and a continuous snow cover exists it is possible to identify open water reaches on streams flowing through the region. Such cases are identifiable on the ERTS images especially on the MSS 7 images.

Weller, G. E.↗