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Granular Materials Research at NASA-Glenn

This paper presents viewgraphs of granular materials research at NASA-Glenn. The topics include: 1) Impulse dispersion of a tapered granular chain; 2) High Speed Digital Images of Tapered Chain Dynamics; 3) Impulse Dispersion; 4) Three Dimensional Granular Bed Experimental Setup; 5) Magnetic Resonance Imaging of Fluid Flow in Porous Media; and 6) Net Charge on Granular Materials (NCharG).

Agui, Juan H.

The features of self-assembling organic bilayers important to the formation of anisotropic inorganic materials in microgravity conditions

Materials with directional properties are opening new horizons in a variety of applications including chemistry, electronics, and optics. Structural, optical, and electrical properties can be greatly augmented by the fabrication of composite materials with anisotropic microstructures or with anisotropic particles uniformly dispersed in an isotropic matrix. Examples include structural composites, magnetic and optical recording media, photographic film, certain metal and ceramic alloys, and display technologies including flat panel displays. The new applications and the need for model particles in scientific investigations are rapidly out-distancing the ability to synthesize anisotropic particles with specific chemistries and narrowly distributed physical characteristics (e.g. size distribution, shape, and aspect ratio).

Talham, Daniel R.

The structure, energy balance, and winds of cool stars

Solar magnetic field phenomena which occur in cool stars are summarized. Factors which can produce magnetic fields in stars are listed. Information on cool star atmospheres, provided by high dispersion spectra, is discussed. These spectra show that in Beta Dra (G2 Ib) the transition lines are red shifted (an antiwind), perhaps indicating downflows in closed magnetic flux tubes, as seen in the solar flux tubes above sunspots. The G and K giants and supergiants are classed as active, quiet, or hybrid, depending on whether their atmospheres are dominated by closed magnetic flux tubes, open field geometries, or a predominantly open geometry with a few closed flux tubes embedded.

Linsky, J. L.

Van Allen Probes Observations of Magnetic Field Dipolarization and Its Associated O+ Flux Variations in the Inner Magnetosphere at L 6.6

We investigate the magnetic field dipolarization in the inner magnetosphere and its associated ion flux variations, using the magnetic field and energetic ion flux data acquired by the Van Allen Probes. From a study of 74 events that appeared at L= 4.5-6.6 between 1 October 2012 and 31 October 2013, we reveal the following characteristics of the dipolarization in the inner magnetosphere: (1) its time scale is approximately 5 min; (2) it is accompanied by strong magnetic fluctuations that have a dominant frequency close to the O+ gyrofrequency; (3) ion fluxes at 20-50 keV are simultaneously enhanced with larger magnitudes for O+ than for H+; (4) after a few minutes of the dipolarization, the flux enhancement at 0.1-5 keV appears with a clear energy-dispersion signature only for O+; and (5) the energy-dispersed O+ flux enhancement appears in directions parallel or antiparallel to the magnetic field. From these characteristics, we discuss possible mechanisms that can provide selective acceleration to O+ ions at > 20 keV. We conclude that O+ ions at L= 5.4-6.6 undergo nonadiabatic local acceleration caused by oscillating electric field associated with the magnetic fluctuations and/or adiabatic convective transport from the plasma sheet to the inner magnetosphere by the impulsive electric field. At L= 4.5-5.4, however, only the former acceleration is plausible. We also conclude that the field-aligned energy-dispersed O+ ions at 0.1-5 keV originate from the ionosphere and are extracted nearly simultaneously to the onset of the dipolarization.

Magnetosphere

Prediction of structures and magnetic orientations in solid alpha and beta-O2

A quasi-harmonic-lattice-dynamics method coupled with a pattern-recognition optimization scheme is used to determine the minimum energy structures and magnetic orientations of solid oxygen. It is shown that the magnetic interaction is responsible for the stability of alpha-O2 with respect to beta-O2 at zero temperature and pressure. The calculated alpha-O2 lattice parameters, magnetic orientations, and sublimation energy are in good agreement with experiment. Phonon dispersion curves are calculated at vector k not equal to zero and the acoustic sound velocities are determined. The rms translational and orientational fluctuations from equilibrium are also calculated. The beta-O2 phase is described by constraining the magnetic moments so that the magnetic Hamiltonian preserves the hexagonal symmetry of the crystal. The calculated lattice parameters are in good agreement with the experiments, and a three-sublattice, quasi-helical magnetic orientation is predicted from structural and energetic considerations.

Etters, R. D.

Absence of Long-Range Magnetic Ordering in a Trirutile High-Entropy Oxide (Mn 0.2 Fe 0.2 Co 0.2 Ni 0.2 Cu 0.2 )Ta 1.92 O 6–δ

Functionalities of solid-state materials are usually considered to be dependent on their crystal structures. The limited structural types observed in the emerging high-entropy oxides put constraints on the exploration of their physical properties and potential applications. Herein, we synthesized the first high-entropy oxide in a trirutile structure, (Mn 0.2 Fe 0.2 Co 0.2 Ni 0.2 Cu 0.2 )Ta 1.92 O 6–δ , and investigated its magnetism. The phase purity and high-entropy nature were confirmed by powder Xray diffraction and energy-dispersive spectroscopy, respectively. X-ray photoelectron spectroscopy indicated divalent Mn, Co, Ni, and Cu along with trivalent Fe. Magnetic property measurements showed antiferromagnetic coupling and potential short-range magnetic ordering below ~4 K. The temperature-dependent heat capacity data measured under zero and high magnetic fields confirmed the lack of long-range magnetic ordering and a possible low-temperature phonon excitation. The discovery of the first trirutile high-entropy oxide opens a new pathway for studying the relationship between the highly disordered atomic arrangement and magnetic interaction. Furthermore, it provides a new direction for exploring the functionalities of highentropy oxides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Electroconductive PET/SWNT Films by Solution Casting

The market for electrically conductive polymers is rapidly growing, and an emerging pathway for attaining these materials is via polymer-carbon nanotube (CNT) nanocomposites, because of the superior properties of CNTs. Due to their excellent electrical properties and anisotropic magnetic susceptibility, we expect CNTs could be easily aligned to maximize their effectiveness in imparting electrical conductivity to the polymer matrix. Single-walled carbon nanotubes (SWNT) were dispersed in a polyethylene terephthalate (PET) matrix by solution blending then cast onto a glass substrate to create thin, flexible films. Various SWNT loading concentrations were implemented (0.5, 1.0, and 3.0 wt.%) to study the effect of additive density. The processing method was repeated to produce films in the presence of magnetic fields (3 and 9.4 Tesla). The SWNTs showed a high susceptibility to the magnetic field and were effectively aligned in the PET matrix. The alignment was characterized with Raman spectroscopy. Impedance spectroscopy was utilized to study the electrical behavior of the films. Concentration and dispersion seemed to play very important roles in improving electrical conductivity, while alignment played a secondary and less significant role. The most interesting result proved to be the effect of a magnetic field during processing. It appears that a magnetic field may improve dispersion of unmodified SWNTs, which seems to be more important than alignment. It was concluded that SWNTs offer a good option as conductive, nucleating filler for electroconductive polymer applications, and the utilization of a magnetic field may prove to be a novel method for CNT dispersion that could lead to improved nanocomposite materials.

Steinert, Brian W.

Generalized Langmuir Waves in Magnetized Kinetic Plasmas

The properties of unmagnetized Langmuir waves and cold plasma magnetoionic waves (x, o, z and whistler) are well known. However, the connections between these modes in a magnetized kinetic plasma have not been explored in detail. Here, wave properties are investigated by numerically solving the dispersion equation derived from the Vlasov equations both with and without a beam instability present. For omega(sub p)>Omega(sub e), it is shown that the generalized Langmuir mode at oblique propagation angles has magnetic z-mode characteristics at low wave numbers and thermal Langmuir mode characteristics at high wave numbers. For omega(sub p)<Omega(sub e), it is shown that the (oblique) Langmuir mode instead connects to the whistler mode at low wave numbers. The transition from the Langmuir/z mode to the Langmuir/whistler mode near omega(sub p) = Omega(sub e) is rapid. In addition, the effects on wave dispersion and polarization after adding a beam are investigated. Applications of this theory to magnetized Langmuir waves in Earth's foreshock and the solar wind, to waves observed near the plasma frequency in the auroral regions, and to solar type III bursts are discussed.

Willes, A. J.

Ordinary electromagnetic mode instability

The instability of the ordinary electromagnetic mode propagating perpendicular to an external magnetic field is analyzed for a single-species plasma with ring velocity distribution. The marginal instability boundaries for both the purely growing mode and the propagating growing modes are calculated from the instability criteria. The dispersion characteristics are derived for a cold plasma and a very strong static magnetic field. The point is determined at which the real parts of the complex frequency band are centered. The typical growth rates are found to be of the order of the cyclotron frequency and can be enhanced by increasing the ratio of parallel kinetic pressure to magnetic pressure.

Cheng, C.-Z.

The mirror and ion cyclotron anisotropy instabilities

The linear dispersion equation for fully electromagnetic waves and instabilities at arbitrary directions of propagation relative to a background magnetic field B(0) in a homogeneous Vlasov plasma is solved numerically for bi-Maxwellian particle distributions. For isotropic plasmas the dispersion and damping of the three modes below the proton cyclotron frequency are studied as functions of Beta(i) and T(e)/T(i). The transport ratios of helicity, cross-helicity, Alfven ratio, compressibility, and parallel compressibility are defined. Under the condition that the proton temperature perpendicular to B(0) is greater than the parallel temperature, the growth rates and transport ratios of the mirror instability and the ion cyclotron anisotropy instability are examined and compared. Both the proton parallel compressibility and the proton Alfven ratio are significantly different for the two growing modes.

Gary, S. P.

Wide range magnetic electron spectrograph

An electron spectrogrpah is described that covers electron energies from 400 eV to 200 keV with an energy resolution of 10 percent. This overlaps the range of electrostatic deflection devices at low energy and solid state detectors at high energy. The spectrograph uses magnetic deflection of the electrons to achieve energy separation and images the full range of energies on a single plane. The magnetic circuit uses the fringing field of two axially located magnets to attain the large energy range. Six separate electron beams can be dispersed in the field, each entering the circuit from a different angle. This is a particular advantage when measuring plasma electron three-dimensional velocity distributions. The angular response of the instrument is particularly favorable and the stray magnetic field is sufficiently low to meet spacecraft requirements.

Coplan, M. A.

Electromagnetic instabilities driven by cool heavy ion beams

The effects of the mass and density of cool, heavy ion beams on the linear and nonlinear characteristics of right-hand resonant and nonresonant electromagnetic ion beam instabilities are analyzed. The magnetic helicity and Alfven speed for a computer simulated complete linear dispersion equation for electromagnetic instabilities are examined. The data reveal that the maximum growth rate of the resonant mode and the threshold velocity of the nonresonant mode decrease with beam mass; however, the maximum growth rate of the nonresonant mode and the threshold velocity of the resonant mode are independent of the beam mass. The role reversal of the instabilities which occur when a heavy ion beam is the more dense component is studied. The nonlinear behavior of the instabilities is described; variations in the magnetic field fluctuation levels and the beam mass dependence are investigated. It is observed that at low beam density the magnetic field fluctuation level increases with beam mass and at higher beam density the fluctuation level correlates with the core mass. The instability data are applied to observations of Venus and the Comet Giacobini-Zinner.

Winske, D.

MAVEN Case Studies of Plasma Dynamics in Low‐Altitude Crustal Magnetic Field at Mars 1: Dayside Ion Spikes Associated With Radial Crustal Magnetic Fields

We report for the first time, simultaneous ion, electron, magnetic field vector and electric field wave measurements made possible by Mars Atmosphere and Volatile EvolutioN, during ion energy flux spikes in low‐altitude radial crustal magnetic fields on the Mars dayside. Observations show energetic electrons and ions (E > 25 eV) precipitating on magnetic field lines assumed as closed. Ions (E < 1.4 keV) display broad velocity distributions toward Mars, showing ions flowing from higher altitude possibly after magnetic reconnection or loss cone filling from pitch angle scattering effects. Precipitating ions (E < 1.4 keV) show nonadiabatic features depending on ion mass and energy and returning ions (E < 1.4 keV) show evidence of conserving the first adiabatic invariant in a mirror field. We observe magnetic field perturbations up to 60 nT, electric field wave amplitudes up to 38 mV/m, and brief periods of peaked electron spectra. At ∼175 km and at times Mars Atmosphere and Volatile EvolutioN is below the mirroring altitude of electrons, we observe mirroring and transverse heating of H+ ions alongside increased electric field wave amplitude fluctuations. It suggests field aligned potential drops result from different mirror altitudes of ions and electrons. Ions E > 1.4 keV (O+) occur as injected accelerated ion beams and ions heated after energization or deceleration. Energy dispersed kilo‐electron‐volt ions suggest a selection effect in radial magnetic fields for lower‐energy Marsward ions, compared to reflection of higher‐energy anti‐Sunward ions. Precipitating kilo‐electron‐volt ions show energy deposition rates of 3.6 ×10(exp -6) W/sq m and sputtering escape rates from precipitating O+ ions of 1.5 ×10(exp 5)/(sq cm.s) and 2.1 ×10(exp 6)/(sq cm.s) are calculated.

Plasma Dynamics

Current Closure in the Auroral Ionosphere: Results from the Auroral Current and Electrodynamics Structure Rocket Mission

The Auroral Current and Electrodynamics Structure (ACES) mission consisted of two sounding rockets launched nearly simultaneously from Poker Flat Research Range, AK on January 29, 2009 into a dynamic multiple-arc aurora. The ACES rocket mission was designed to observe electrodynamic and plasma parameters above and within the current closure region of the auroral ionosphere. Two well instrumented payloads were flown along very similar magnetic field footprints, at different altitudes, with small temporal separation between both payloads. The higher altitude payload (apogee 360 km), obtained in-situ measurements of electrodynamic and plasma parameters above the current closure region to determine the input signature. The low altitude payload (apogee 130 km), made similar observations within the current closure region. Results are presented comparing observations of the electric fields, magnetic components, and the differential electron energy flux at magnetic footpoints common to both payloads. In situ data is compared to the ground based all-sky imager data, which presents the evolution of the auroral event as the payloads traversed through magnetically similar regions. Current measurements derived from the magnetometers on the high altitude payload observed upward and downward field-aligned currents. The effect of collisions with the neutral atmosphere is investigated to determine it is a significant mechanism to explain discrepancies in the low energy electron flux. The high altitude payload also observed time-dispersed arrivals in the electron flux and perturbations in the electric and magnetic field components, which are indicative of Alfven waves.

Kaeppler, S. R.

Current Closure in the Auroral Ionosphere: Results from the Auroral Current and Electrodynamics Structure Rocket Mission

The Auroral Current and Electrodynamics Structure (ACES) mission consisted of two sounding rockets launched nearly simultaneously from Poker Flat Research Range, AK on January 29, 2009 into a dynamic multiple-arc aurora. The ACES rocket mission was designed to observe electrodynamic and plasma parameters above and within the current closure region of the auroral ionosphere. Two well instrumented payloads were flown along very similar magnetic field footprints, at different altitudes, with small temporal separation between both payloads. The higher altitude payload (apogee 360 km), obtained in-situ measurements of electrodynamic and plasma parameters above the current closure region to determine the input signature. The low altitude payload (apogee 130 km), made similar observations within the current closure region. Results are presented comparing observations of the electric fields, magnetic components, and the differential electron energy flux at magnetic footpoints common to both payloads. In situ data is compared to the ground based all-sky imager data, which presents the evolution of the auroral event as the payloads traversed through magnetically similar regions. Current measurements derived from the magnetometers on the high altitude payload observed upward and downward field-aligned currents. The effect of collisions with the neutral atmosphere is investigated to determine if it is a significant mechanism to explain discrepancies in the low energy electron flux. The high altitude payload also observed time-dispersed arrivals in the electron flux and perturbations in the electric and magnetic field components, which are indicative of Alfven waves.

Kaeppler, S. R.

Kinetic theory for electrostatic waves due to transverse velocity shears

A kinetic theory in the form of an integral equation is provided to study the electrostatic oscillations in a collisionless plasma immersed in a uniform magnetic field and a nonuniform transverse electric field. In the low temperature limit the dispersion differential equation is recovered for the transverse Kelvin-Helmholtz modes for arbitrary values of K parallel, where K parallel is the component of the wave vector in the direction of the external magnetic field assumed in the z direction. For higher temperatures the ion-cyclotron-like modes described earlier in the literature by Ganguli, Lee and Plamadesso are recovered. In this article, the integral equation is reduced to a second-order differential equation and a study is made of the kinetic Kelvin-Helmholtz and ion-cyclotron-like modes that constitute the two branches of oscillation in a magnetized plasma including a transverse inhomogeneous dc electric field.

Ganguli, G.

Atomically Resolved Acoustic Dynamics Coupled with Magnetic Order in a Van der Waals Antiferromagnet

Magnetoelastic coupling in van der Waals (vdW) magnetic materials enables a unique interplay between the spin and lattice degrees of freedom. Characterizing the elastic responses with atomic and femtosecond resolution across the magnetic transition is essential for guiding the design of magnetically tunable actuators and strain-mediated spintronic devices. Here, ultrafast X-ray diffraction employed at a free-electron laser reveals that the atomic displacements, wave vectors, and dispersion relations of acoustic phonon modes in a vdW antiferromagnet FePS3 are coupled with the magnetic order, by tracking both in-plane and out-of-plane Bragg peaks upon optical excitation across the Néel temperature (TN). One transverse mode shows that a quasi-out-of-plane atomic displacement undergoes a significant directional change across TN. Its quasi-in-plane wave vector is derived by comparing the measured sound velocity and the first-principles calculations. The other transverse mode is an interlayer shear acoustic mode whose amplitude is strongly enhanced in the antiferromagnetic phase, exhibiting eight times stronger amplitude than the longitudinal acoustic mode below TN. The atomically resolved characterization of acoustic phonon dynamics that couple with magnetic ordering opens opportunities for harnessing unique magnetoelastic coupling in vdW magnets on ultrafast timescales.

coherent acoustic phonons

High-temperature quantum coherence of spinons in a rare-earth spin chain

Conventional wisdom dictates that quantum effects become unimportant at high temperatures. In magnets, when the thermal energy exceeds interactions between atomic magnetic moments, the moments are usually uncorrelated, and classical paramagnetic behavior is observed. This thermal decoherence of quantum spin behaviors is a major hindrance to quantum information applications of spin systems. Remarkably, our neutron scattering experiments on Yb chains in an insulating perovskite crystal defy these conventional expectations. We find a sharply defined spectrum of spinons, fractional quantum excitations of spin-1/2 chains, to persist to temperatures much higher than the scale of the interactions between Yb magnetic moments. The observed sharpness of the spinon continuum’s dispersive upper boundary indicates a spinon mean free path exceeding ≈ 35 inter-atomic spacings at temperatures more than an order of magnitude above the interaction energy scale. We thus discover an important and highly unique quantum behavior, which expands the realm of quantumness to high temperatures where entropy-governed classical behaviors were previously believed to dominate. Our results have profound implications for spin systems in quantum information applications operating at finite temperatures and motivate new developments in quantum metrology.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND