Cryogenic Laser Ablation Reveals Short-Circuit Mechanism in Lithium Metal Batteries
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Formation of B 2 N molecules occurs when solid BN is utilized as feedstock for the synthesis of boron nitride nanomaterials.
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Previosuly cited in issue 17, p. 2910, Accession no. A81-39069
The NASA Glenn Research Center is constructing a 616 element scanning phased array antenna using thin film Ba(sub x)Sr(sub 1-x)TiO(sub 3) based phase shifters. A critical milestone is the production of 616 identical phase shifters at 19 GHz with [asymptotically equal to]4 dB insertion loss and at least 337.5 deg phase shift with 3 percent bandwidth. It is well known that there is a direct relationship between dielectric tuning and loss due to the Kramers-Kronig relationship and that film crystallinity and strain, affected by the substrate template, play an important role. Ba(sub 0.50)Sr(sub 0.50)TiO (sub 3) films, nominally 400 nm thick, were deposited on 48 0.25 mm thick, 5 cm diameter LaAlO(sub 3) wafers. Although previous results suggested that Mn-doped films on MgO were intrinsically superior in terms of phase shift per unit loss, for this application phase shift per unit length was more important. The composition was selected as a compromise between tuning and loss for room temperature operation (e.g. crystallinity progressively degrades for Ba concentrations in excess of 30 percent). As a prelude to fabricating the array, it was necessary to process, screen, and inventory a large number of samples. Variable angle ellipsometry was used to characterize refractive index and film thickness across each wafer. Microstructural properties of the thin films were characterized using high resolution X-ray diffractometry. Finally, prototype phase shifters and resonators were patterned on each wafer and RE probed to measure tuning as a function of dc bias voltage as well as peak (0 field) permittivity and unloaded Q. The relationship among film quality and uniformity and performance is analyzed. This work presents the first statistically relevant study of film quality and microwave performance and represents a milestone towards commercialization of thin ferroelectric films for microwave applications.
Lunar impact-melt breccias contain metal grains from the meteorites that formed the breccias. Because the breccias contain clastic material that may derive from older breccias, metal grains from earlier impacts may be present, too. The large subset of moderately mafic (8 - 12% FeO), KREEP-rich ("LKFM") melt breccias is particularly important because: (1) these are the melt breccias most likely to have been produced in basin-forming impacts, (2) it is from these breccias that many of the approx. 3.9 Gyr ages that are so common in lunar samples derive, (3) the breccias contain large proportions of FeNi metal, more than 1% in some types of Apollo 16 breccias, and (4) the metal potentially provides information about the impactors causing the apparent cataclysm at 3.9 Gyr.
Introduction: With the anticipated development of high-capacity fission power and electric propulsion for deep-space missions, it will become possible to propose experiments that demand higher power than current technologies (e.g. radioisotope power sources) provide. Jupiter Icy Moons Orbiter (JIMO), the first mission in the Project Prometheus program, will explore the icy moons of Jupiter with a suite of high-capability experiments that take advantage of the high power levels (and indirectly, the high data rates) that fission power affords. This abstract describes two high-capability active-remote-sensing experiments that will be logical candidates for subsequent Prometheus-class missions.
Scanning phased-array antennas represent a highly desirable solution for futuristic near-Earth and deep space communication scenarios requiring vibration-free, rapid beam steering and enhanced reliability. The current state-of-practice in scanning phased arrays is represented by gallium arsenide (GaAs) monolithic microwave integrated circuit (MMIC) technology or ferrite phase shifters. Cost and weight are significant impediments to space applications. Moreover, conventional manifold-fed arrays suffer from beam-forming loss that places considerable burden on MMIC amplifiers. The inefficiency can result in severe thermal management problems.
Future long-duration missions to Mars require capabilities in terms of manufacture of structures and chemical compounds essential for human habitat and exploratory activities. Currently, it is not feasible to import all the required raw and finished materials from Earth. In fact, essential items such as structural members as well as various gases for human consumption and material processing need to be largely extracted from the available planetary resources. The resources on Mars include its soil and rocks, its atmosphere and the polar caps. Mars atmosphere consists of 95% carbon dioxide and the balance contains small percentages of oxygen, nitrogen, and argon. The Mars regolith contains many metal oxides in various mineralogical forms. Presently, Martian soil samples are not available. However, a closely matched Martian soil simulant developed by the Johnson Space Center has been available for scientific research and engineering studies. The chemical makeup of this simulant is compared with the data from Viking Lander and Path Finder missions are shown..
Howardites, eucrites and diogenites (HED) form a suit of igneous achondrite meteorites that are thought to have formed on a single asteroidal body. While there have been many different models proposed for the formation of the HED parent asteroid they can be generalized into two end member models. One is the magma ocean model (e.g. [1]) in which the entire HED parent body was continuously fractionated from a planet wide magma ocean with diogenites representing the lower crust and eucrites being upper crustal rocks. The second model hypothesizes that diogenites and eucrites were formed as a series of intrusions and/or extrusions of partial melts of a primitive proto-Vesta [2]. We use in situ trace element analysis together with major and minor element analysis to try and distinguish between these different hypotheses for the evolution of the HED parent body.
Surface energy of a substrate is changed without the need for any template, mask, or additional coating medium applied to the substrate. At least one beam of energy directly ablates a substrate surface to form a predefined topographical pattern at the surface. Each beam of energy has a width of approximately 25 micrometers and an energy of approximately 1-500 microJoules. Features in the topographical pattern have a width of approximately 1-500 micrometers and a height of approximately 1.4-100 micrometers.
Absolute age determination isnecessary to check and calibratethe relative Martian chronologypresently available from meteoriticcrater counting.
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