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At least 181 records · Page 10

The Triple-Dip La Niña of 2020–22: Updates to the Correlation of ENSO With the Termination of Solar Cycles

The Sun provides the energy required to sustain life on Earth and drive our planet’s atmosphere. However, establishing a solid physical connection between solar and tropospheric variability has posed a considerable challenge across the spectrum of Earth-system science. Over the past few years a new picture to describe solar variability has developed, based on observing, understanding and tracing the progression, interaction and intrinsic variability of the magnetized activity bands that belong to the Sun’s 22-year magnetic activity cycle. A solar cycle’s fiducial clock does not run from the canonical min or max, instead resetting when all old cycle polarity magnetic flux is cancelled at the equator, an event dubbed the “termination” of that solar cycle, or terminator. In a recent paper, we demonstrated with high statistical significance, a correlation between the occurrence of termination of the last five solar cycles and the transition from El Niño to La Niña in the Pacific Ocean, and predicted that there would be a transition to La Niña in mid 2020. La Niña did indeed begin in mid-2020, and endured into 2023 as a rare “triple dip” event, but some of the solar predictions made did not occur until late 2021. This work examines what went right, what went wrong, the correlations between El Niño, La Niña and geomagnetic activity indices, and what might be expected for the general trends of large-scale global climate in the next decade.

Robert J Leamon↗

Materials Data on La(AlGe)2 by Materials Project

LaAl2Ge2 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. La is bonded to six equivalent Ge atoms to form distorted LaGe6 octahedra that share corners with twelve equivalent AlGe4 tetrahedra, edges with six equivalent LaGe6 octahedra, and edges with six equivalent AlGe4 tetrahedra. All La–Ge bond lengths are 3.14 Å. Al is bonded to four equivalent Ge atoms to form distorted AlGe4 tetrahedra that share corners with six equivalent LaGe6 octahedra, corners with six equivalent AlGe4 tetrahedra, edges with three equivalent LaGe6 octahedra, and edges with three equivalent AlGe4 tetrahedra. The corner-sharing octahedra tilt angles range from 23–53°. All Al–Ge bond lengths are 2.58 Å. Ge is bonded to three equivalent La and four equivalent Al atoms to form a mixture of distorted corner and edge-sharing GeLa3Al4 pentagonal bipyramids.

36 MATERIALS SCIENCE↗

Materials Data on La(MnGe)2 by Materials Project

LaMn2Ge2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. La is bonded in a 8-coordinate geometry to eight equivalent Ge atoms. All La–Ge bond lengths are 3.20 Å. Mn is bonded to four equivalent Ge atoms to form a mixture of edge and corner-sharing MnGe4 tetrahedra. All Mn–Ge bond lengths are 2.45 Å. Ge is bonded in a 9-coordinate geometry to four equivalent La, four equivalent Mn, and one Ge atom. The Ge–Ge bond length is 2.82 Å.

36 MATERIALS SCIENCE↗

Materials Data on La(AlBr4)3 by Materials Project

La(AlBr4)3 crystallizes in the trigonal P3_121 space group. The structure is one-dimensional and consists of one La(AlBr4)3 ribbon oriented in the (0, 0, 1) direction. La3+ is bonded in a 8-coordinate geometry to eight Br1- atoms. There are a spread of La–Br bond distances ranging from 3.02–3.20 Å. There are two inequivalent Al3+ sites. In the first Al3+ site, Al3+ is bonded in a tetrahedral geometry to four Br1- atoms. There are a spread of Al–Br bond distances ranging from 2.27–2.41 Å. In the second Al3+ site, Al3+ is bonded in a tetrahedral geometry to four Br1- atoms. There are two shorter (2.33 Å) and two longer (2.34 Å) Al–Br bond lengths. There are six inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Al3+ atom. In the second Br1- site, Br1- is bonded in a distorted L-shaped geometry to one La3+ and one Al3+ atom. In the third Br1- site, Br1- is bonded in an L-shaped geometry to one La3+ and one Al3+ atom. In the fourth Br1- site, Br1- is bonded in a single-bond geometry to one Al3+ atom. In the fifth Br1- site, Br1- is bonded in a distorted L-shaped geometry to one La3+ and one Al3+ atom. In the sixth Br1- site, Br1- is bonded in a distorted L-shaped geometry to one La3+ and one Al3+ atom.

36 MATERIALS SCIENCE↗

Materials Data on La(ReSi)2 by Materials Project

La(ReSi)2 crystallizes in the orthorhombic Imma space group. The structure is two-dimensional and consists of two La(ReSi)2 sheets oriented in the (0, 0, 1) direction. La2+ is bonded in a distorted q4 geometry to ten Si4- atoms. There are four shorter (3.22 Å) and six longer (3.23 Å) La–Si bond lengths. There are two inequivalent Re3+ sites. In the first Re3+ site, Re3+ is bonded in a bent 120 degrees geometry to two equivalent Si4- atoms. Both Re–Si bond lengths are 2.53 Å. In the second Re3+ site, Re3+ is bonded in a water-like geometry to two equivalent Si4- atoms. Both Re–Si bond lengths are 2.53 Å. There are two inequivalent Si4- sites. In the first Si4- site, Si4- is bonded in a 9-coordinate geometry to six equivalent La2+ and three Si4- atoms. There are two shorter (2.41 Å) and one longer (2.49 Å) Si–Si bond lengths. In the second Si4- site, Si4- is bonded in a 9-coordinate geometry to four equivalent La2+, four Re3+, and one Si4- atom.

36 MATERIALS SCIENCE↗

Materials Data on La(HO)3 by Materials Project

La(OH)3 crystallizes in the monoclinic Pm space group. The structure is three-dimensional. there are two inequivalent La3+ sites. In the first La3+ site, La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.57–2.64 Å. In the second La3+ site, La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.56–2.68 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom.

36 MATERIALS SCIENCE↗

Materials Data on La(HO)3 by Materials Project

La(OH)3 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are two inequivalent La3+ sites. In the first La3+ site, La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.56–2.64 Å. In the second La3+ site, La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.54–2.65 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom.

36 MATERIALS SCIENCE↗

Materials Data on La(BiO2)2 by Materials Project

La(BiO2)2 crystallizes in the trigonal R-3m space group. The structure is two-dimensional and consists of three La(BiO2)2 sheets oriented in the (0, 0, 1) direction. La3+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are six shorter (2.51 Å) and two longer (2.67 Å) La–O bond lengths. Bi+2.50+ is bonded to four O2- atoms to form corner-sharing BiO4 trigonal pyramids. There are one shorter (2.15 Å) and three longer (2.36 Å) Bi–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to three equivalent La3+ and one Bi+2.50+ atom to form OLa3Bi tetrahedra that share corners with nine equivalent OLa3Bi tetrahedra, corners with three equivalent OLaBi3 trigonal pyramids, edges with three equivalent OLa3Bi tetrahedra, and edges with three equivalent OLaBi3 trigonal pyramids. In the second O2- site, O2- is bonded to one La3+ and three equivalent Bi+2.50+ atoms to form distorted OLaBi3 trigonal pyramids that share corners with three equivalent OLa3Bi tetrahedra, corners with seven equivalent OLaBi3 trigonal pyramids, and edges with three equivalent OLa3Bi tetrahedra.

36 MATERIALS SCIENCE↗

Materials Data on La(HO)3 by Materials Project

La(OH)3 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one La(OH)3 sheet oriented in the (1, 0, 0) direction. La3+ is bonded to six O2- atoms to form distorted edge-sharing LaO6 octahedra. There are a spread of La–O bond distances ranging from 2.42–2.49 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent La3+ and one H1+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent La3+ and one H1+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent La3+ and one H1+ atom.

36 MATERIALS SCIENCE↗

Materials Data on La(Ge3Pt)4 by Materials Project

LaPt4Ge12 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. La is bonded to twelve equivalent Ge atoms to form LaGe12 cuboctahedra that share faces with eight equivalent PtGe6 octahedra. All La–Ge bond lengths are 3.38 Å. Pt is bonded to six equivalent Ge atoms to form PtGe6 octahedra that share corners with six equivalent PtGe6 octahedra and faces with two equivalent LaGe12 cuboctahedra. The corner-sharing octahedral tilt angles are 60°. All Pt–Ge bond lengths are 2.53 Å. Ge is bonded in a 2-coordinate geometry to one La, two equivalent Pt, and two equivalent Ge atoms. There are one shorter (2.54 Å) and one longer (2.66 Å) Ge–Ge bond lengths.

36 MATERIALS SCIENCE↗

Materials Data on La(IO3)3 by Materials Project

La(IO3)3 crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of one La(IO3)3 sheet oriented in the (0, 0, 1) direction. La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.53–3.03 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to one La3+, one O2-, and two I5+ atoms. The O–O bond length is 1.37 Å. There are one shorter (2.54 Å) and one longer (2.77 Å) O–I bond lengths. In the second O2- site, O2- is bonded in a 3-coordinate geometry to one La3+ and two equivalent I5+ atoms. Both O–I bond lengths are 2.21 Å. In the third O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to one La3+ and two equivalent I5+ atoms. Both O–I bond lengths are 2.15 Å. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to one La3+ and one I5+ atom. The O–I bond length is 1.87 Å. There are two inequivalent I5+ sites. In the first I5+ site, I5+ is bonded in a 5-coordinate geometry to five O2- atoms. In the second I5+ site, I5+ is bonded in a distorted water-like geometry to six O2- atoms.

36 MATERIALS SCIENCE↗

Materials Data on La(Cu2P)2 by Materials Project

La(Cu2P)2 crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. there are two inequivalent La2+ sites. In the first La2+ site, La2+ is bonded to six P3- atoms to form LaP6 octahedra that share corners with eight equivalent LaP6 pentagonal pyramids, corners with six equivalent CuP4 tetrahedra, edges with two equivalent LaP6 octahedra, edges with two equivalent LaP6 pentagonal pyramids, and edges with four equivalent CuP4 tetrahedra. There are two shorter (2.97 Å) and four longer (2.98 Å) La–P bond lengths. In the second La2+ site, La2+ is bonded to six P3- atoms to form distorted LaP6 pentagonal pyramids that share corners with four equivalent LaP6 octahedra, corners with four CuP4 tetrahedra, an edgeedge with one LaP6 octahedra, edges with six CuP4 tetrahedra, and faces with two equivalent LaP6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 34–40°. There are a spread of La–P bond distances ranging from 2.95–3.07 Å. There are six inequivalent Cu1+ sites. In the first Cu1+ site, Cu1+ is bonded in a water-like geometry to two P3- atoms. Both Cu–P bond lengths are 2.41 Å. In the second Cu1+ site, Cu1+ is bonded in a trigonal non-coplanar geometry to three P3- atoms. There are two shorter (2.40 Å) and one longer (2.47 Å) Cu–P bond lengths. In the third Cu1+ site, Cu1+ is bonded in a 2-coordinate geometry to two equivalent P3- atoms. Both Cu–P bond lengths are 2.47 Å. In the fourth Cu1+ site, Cu1+ is bonded to four P3- atoms to form CuP4 tetrahedra that share corners with two equivalent LaP6 pentagonal pyramids, corners with three CuP4 tetrahedra, edges with two equivalent LaP6 octahedra, edges with three equivalent LaP6 pentagonal pyramids, and edges with two equivalent CuP4 tetrahedra. There are a spread of Cu–P bond distances ranging from 2.44–2.50 Å. In the fifth Cu1+ site, Cu1+ is bonded to four P3- atoms to form distorted CuP4 tetrahedra that share corners with three equivalent LaP6 octahedra, corners with two equivalent LaP6 pentagonal pyramids, corners with three CuP4 tetrahedra, edges with three equivalent LaP6 pentagonal pyramids, and edges with two equivalent CuP4 tetrahedra. The corner-sharing octahedra tilt angles range from 43–61°. There are a spread of Cu–P bond distances ranging from 2.33–2.61 Å. In the sixth Cu1+ site, Cu1+ is bonded in a trigonal non-coplanar geometry to three P3- atoms. There are one shorter (2.30 Å) and two longer (2.40 Å) Cu–P bond lengths. There are three inequivalent P3- sites. In the first P3- site, P3- is bonded in a 9-coordinate geometry to three La2+ and six Cu1+ atoms. In the second P3- site, P3- is bonded in a 9-coordinate geometry to two equivalent La2+ and seven Cu1+ atoms. In the third P3- site, P3- is bonded in a 9-coordinate geometry to four La2+ and five Cu1+ atoms.

36 MATERIALS SCIENCE↗

Chemistry imaging and distribution analysis of rare earth elements in coal using LIBS and LA-ICP-MS instruments

Currently, demand for rare earth elements (REEs) increased significantly. Coal is actively evaluated as potential economic sources for extraction of REEs. Here, in this work, laser-induced breakdown spectroscopy (LIBS) was evaluated for rapid estimation of REEs content and their distribution in the natural coal samples. The results were compared with similar laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) measurements. Thirteen coal samples (nine standard samples and five natural samples) were used in this study. Powder samples were pressed into pellets while coal chunks were directly ablated for data recording. Pellets of the powder standard samples were used to optimize the data acquisition system and then data recorded with this optimized system was used to identify the proper data acquisition and analysis models. After establishing the proper data acquisition system and analysis model using the standard samples, natural coal samples in powder form and their chunks were utilized to record LIBS and LA-ICP-MS spectra. Multivariate calibration models were developed using four of the natural samples, which were evaluated by predicting the REE content in the fifth sample. Principal component analysis was performed on the LIBS data obtained from the natural samples and it classified all the samples with high accuracy. Two-dimensional (2D) elemental mapping on coal chunk samples was also performed using both LIBS and LA-ICP-MS to study the distribution of REEs in the samples. The resulting elemental images and their correlations can be used to infer mineral distributions.

01 COAL, LIGNITE, AND PEAT↗

Bulk cloud microphysical properties as seen from numerical simulation and remote sensing products: case study of a hailstorm event over the La Plata Basin

Hailstorms develop over the La Plata Basin, in south-eastern South America, more often during later winter and early austral spring, between September and October. These systems have significant socioeconomic impacts over the region. Thus, a better understanding of how atmospheric drivers modulate the formation of hailstorms is important to improve the forecast of such phenomena. In this study, we selected a hailstorm event observed over the eastern La Plata Basin during 14–15 July 2016 to evaluate the performance of the Brazilian developments on the Regional Atmospheric Modelling System (BRAMS) model. The ability of the model in simulating cloud microphysical properties was evaluated by comparing simulations driven by different global forcings against in situ and remote sensing observations. The model results showed good skill in capturing the basic characteristics of the thunderstorm, particularly in terms of the spatial distribution of hydrometeors. The simulated spatial distribution of hail covers locations where hail fall was reported. The BRAMS simulations suggest that, despite relatively low values of the convective available potential energy (CAPE) (700–1000 J kg -1 ), environments with strong 0–8-km bulk shear (60–70 kt, ~30.9–36.0 m s –1 ) can promote the formation of ice clouds and hail fall over the eastern La Plata Basin. To be more conclusive, however, further research is needed to understand how different combinations of CAPE and shear affect hail formation over the region.

54 ENVIRONMENTAL SCIENCES↗

Exploration of a Combined LIBS and LA-ICP-MS Approach for Apatite Characterisation

A combined laser‐induced breakdown spectroscopy (LIBS) and laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) method is demonstrated for comprehensive apatite analysis. These measurements provide elemental imaging that can be used as a screening technique for chemical selection of grains for subsequent analysis (e.g., U‐Pb geochronology) or can be used to understand elemental distributions within a single grain that would have direct textural‐chemical implications (e.g., zoning patterns). Adding LIBS as a simultaneous measurement, to LA‐ICP‐MS U‐Pb geochronology, allowed for the direct determination of F (H and O show promise for future applications) in addition to major and trace elements of interest. Here, the quantitative measurements were validated against a series of apatites with known values and used to characterise a wide range of samples. Fluorine detection limits were determined to be as low as 70 μg g ‐1 F (broadband CMOS detector) and 4.2 μg g ‐1 F (ICCD detector). U‐Pb age dating was simultaneously collected by LA‐ICP‐MS with the quantitative elemental data from LIBS, providing a comprehensive method for geochronology.

Apatite↗

La 0.6 Sr 0.4 CoO 3−δ Films Under Deoxygenation: Magnetic And Electronic Transitions Are Apart from The Structural Phase Transition

Abstract Topotactic phase transitions induced by changes in the oxygen vacancy concentration can largely alter the physical properties of complex oxides, including electronic and magnetic phases, while maintaining the structural integrity of the crystal lattice. An oxygen‐vacancy‐induced topotactic phase transition from perovskite (PV) to brownmillerite (BM) is achieved in epitaxial La 0.6 Sr 0.4 CoO 3−δ (LSCO) thin films. Two novel intermediate states with different oxygen content are identified by X‐ray diffraction, which involves a single‐phase reduced PV state and a mixed state of co‐existing PV and BM. The combination of depth‐sensitive polarized neutron reflectometry (PNR) and Rutherford backscattering (RBS) allows a quantitative determination of magnetization and the mean oxygen content in all states, revealing a continuous transition from La 0.6 Sr 0.4 CoO 2.97 to La 0.6 Sr 0.4 CoO 2.5 . BM formation is observed for an LSCO layer with an oxygen content of 2.67, while the magnetic and electronic transition already occurs for a layer with a higher oxygen content of 2.77 (and above) and in the absence of a BM signature. These results demonstrate that the physics of electronic metal‐to‐insulator transition (MIT), magnetic ferromagnet‐to‐non‐ferromagnet transition (FM‐to‐non‐FM), and structural PV‐to‐BM phase transition should be considered within the framework of separate but interrelated processes.

36 MATERIALS SCIENCE↗

Construction of the Bioconjugate Py‐Macrodipa‐PSMA and Its In Vivo Investigations with Large 132/135 La 3+ and Small 47 Sc 3+ Radiometal Ions

To harness radiometals in clinical settings, a chelator forming a stable complex with the metal of interest and targets the desired pathological site is needed. Toward this goal, we previously reported a unique set of chelators that can stably bind to both large and small metal ions, via a conformational switch. Within this chelator class, py-macrodipa is particularly promising based on its ability to stably bind several medicinally valuable radiometals including large 132/135 La 3+ , 213 Bi 3+ , and small 44 Sc 3+ . Here, in this study, we report a 10-step organic synthesis of its bifunctional analogue py-macrodipa-NCS, which contains an amine-reactive −NCS group that is amenable for bioconjugation reactions to targeting vectors. The hydrolytic stability of py-macordipa-NCS was assessed, revealing a half-life of 6.0 d in pH 9.0 aqueous buffer. This bifunctional chelator was then conjugated to a prostate-specific membrane antigen (PSMA)-binding moiety, yielding the bioconjugate py-macrodipa-PSMA, which was subsequently radiolabeled with large 132/135 La 3+ and small 47 Sc 3+ , revealing efficient and quantitative complex formation. The resulting radiocomplexes were injected into mice bearing both PSMA-expressing and PSMA-non-expressing tumor xenografts to determine their biodistribution patterns, revealing delivery of both 132/135 La 3+ and 47 Sc 3+ to PSMA+ tumor sites. However, partial radiometal dissociation was observed, suggesting that py-macrodipa-PSMA needs further structural optimization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Synthesis, Crystal and Electronic Structure of La 2 SiP 4

La 2 SiP 4 (mP-28, Z=4, Wyckoff sequence e 7 , space group P2 1 /c (No. 14), a=10.8230(6) Å, b=7.5208(4) Å, c=7.9189(4) Å, and β=105.389(2)°) which crystallizes in the La 2 CuS 4 structure type is reported here. Instead of isolated CuS 3 triangles bridged by disulfide anions, in the crystal structure of La 2 SiP 4 , one-dimensional zig-zag chains composed of SiP 4 tetrahedra connected by P–P bonds are present. Lanthanum cations fill the voids between the chains and are coordinated by either 9P or 8P+Si atoms. La2SiP4 is a narrow bandgap semiconductor with calculated and measured optical bandgaps of 0.35 eV and 0.85(1) eV, respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗