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At least 181 records · Page 10

Safety Considerations for Advanced Material Irradiation at the Advanced Test Reactor

The Advanced Test Reactor (ATR) is a light water reactor with aluminum-clad driver fuel. A primary mission of the ATR is to support the next generation of nuclear reactors. This support necessarily requires irradiation of advanced materials such as sodium, fuel salts, and metal eutectics. Irradiation of advanced materials in the ATR environment presents a challenge when completing accident analyses and demonstrating compliance to the Safety Analysis Report (SAR). Many advanced materials have the possibility to react with the ATR protective barriers such as the cladding or primary coolant system (PCS) boundary during postulated accident scenarios. Further, molten fuel experiments fall outside of the standard regulatory framework for dose consequence analyses. ATR is currently developing new safety analysis methods to support irradiation of advanced materials. The primary considerations for this development are 1) experiment containment design requirements, 2) primary coolant system response to an experiment containment failure, and 3) dose analyses for molten fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

AFC Metal Fuel Workshop Presentations

Compilation of PowerPoint slide decks from presentations given at the 3rd Annual AFC Metal Fuels Workshop. The purpose of this workshop is to bring the national metallic fuel stakeholders together to discuss status and needs of metallic fuel and review the DOE AFC Metal Fuel R&D. Desired Outcomes - Advance Metallic Fuel Technology: 1. Stakeholder Community Building 2. National Program R&D Accountability, Planning Support, and Increased Stakeholder Advocation.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Thermal Cycling and High Temperature Reverse Bias Testing of Control and Irradiated Gallium Nitride Power Transistors

The power systems for use in NASA space missions must work reliably under harsh conditions including radiation, thermal cycling, and exposure to extreme temperatures. Gallium nitride semiconductors show great promise, but information pertaining to their performance is scarce. Gallium nitride N-channel enhancement-mode field effect transistors made by EPC Corporation in a 2nd generation of manufacturing were exposed to radiation followed by long-term thermal cycling and testing under high temperature reverse bias conditions in order to address their reliability for use in space missions. Result of the experimental work are presented and discussed.

thermal cycling tests↗

Post-irradiation Examination of Eurofer-97 Steel Irradiated to 20 dpa at 200–400°C in HFIR under the EUROfusion (ORNL-KIT) Collaboration Program

The Oak Ridge National Laboratory/Karlsruhe Institute of Technology (ORNL/KIT) collaboration focuses on research involving irradiation experiments and post-irradiation examinations (PIE) of isotopically modified Eurofer-97 steels for fusion reactor applications. This collaboration capitalizes on ORNL’s expertise in radiation effects on materials and its capabilities in irradiation and PIE. The research aims to qualify Fe-9Cr-based Eurofer-97 steel under simulated fusion conditions, which include high doses and high transmutation rates. A unique isotopic modification technique is utilized in the research, wherein high-transmutation isotopes such as Fe-54 and Ni-58 are alloyed into the Eurofer steel to align with the expected helium production rates in fusion reactor conditions. This report presents the results of post-irradiation mechanical testing activities for the EUROFER-97/2 specimens after irradiation to ~20 dpa at various irradiation temperatures. The irradiation doses and temperatures for the ES capsules ranged from 18.4–20.4 dpa and 202–256°C, respectively. The mechanical property datasets, obtained through baseline testing and PIE of the tensile and fracture specimens, include microhardness data from 93 irradiated and non-irradiated tensile specimens and 28 irradiated bend bar specimens, uniaxial tensile property data from 45 irradiated and non-irradiated tensile specimens, and fracture toughness data from the bend bar specimens. Further data analyses provide statistical information on the microhardness values and tensile properties, as well as the reference ductile-brittle transition temperature (T 0 ) data.

36 MATERIALS SCIENCE↗

Laboratory Testing of the Temperature Sensor Qualification Device

The Temperature sensor Qualification Device (TQD) has been developed and tested under laboratory conditions to evaluate its thermal performance and the reliability of its retractable sensor system. The TQD is designed to provide an isothermal environment for temperature sensors in both test and reference zones during irradiation experiments. Initial testing revealed minimal radial and azimuthal temperature variations but identified a significant axial gradient. To address this, design modifications were implemented, including enhanced insulation and the addition of a small heater at the device's top. These changes are expected to produce a more uniform axial temperature profile, though further testing is recommended prior to irradiation. The retractable sensor mechanism was rigorously tested, achieving 1,350 cycles at room temperature and 332 cycles at 400°C before failure. The primary failure mechanism was the thermocouple becoming stuck in the wire guide or capillary tube. Based on these results, design improvements were proposed, such as incorporating a load cell for force monitoring and a stepper motor for precise sensor positioning.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Assessment of Buffer-IPyC Thermomechanical Debonding Behavior Using New Experiment Strength Data in BISON

TRIstructural ISOtropic (TRISO) single sub-millimeter-diameter nuclear fuel particle consists of a spherical fuel kernel surrounded by four coating layers. During reactor operation, the TRISO coating layers are subjected to irradiation-induced dimensional changes and the associated thermomechanical behavior of each layer. One of the observed behaviors is gap formation between the buffer and IPyC layer due to the porous buffer’s irradiation-induced shrinkage exceeding that of the IPyC layer. To predict TRISO thermomechanical performance, multi-physics models have been built that are continually updated and refined. The BISON code is a finite element-based nuclear fuel performance code that may be used for TRISO particle simulations. One of the recent additions to the BISON code is the ability to model the process of layer debonding. This paper will focus on the simulation results of the improved BISON debonding model that will utilize updated strengths measured from irradiated TRISO fuel particles. The new experimental strength data from micromechanical tests of irradiated TRISO fuel samples were exercised in the BISON simulations and compared to baseline strength data to assess their applicability in the models. This also includes updated buffer-IPyC bond strengths to simulate layer delamination. Based on current experimental observations it is noted that the buffer-IPyC separation occurs not exactly at the junction of these two layers, but more on the side of the buffer layer. This improved modeling approach using experimental strength data to characterize buffer-IPyC debonding and its potential subsequent cracking will be presented in the paper along with comparisons to available experimental observations.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Out-of-Pile Testing and Instrumentation Transient Water Irradiation System

Current initiatives to increase the burnup of conventional nuclear fuels past the approximate 62 GWd/t limit have been spurred on by direct savings to refueling and waste storage. The technical justification for a new license limit requires extensive qualification through experimental testing. Unlike beginning-of-life fuels, high-burnup fuels are more susceptible to fuel fragmentation, relocation, and dispersal (FFRD), therefore more data is needed to characterize fuels under key accident scenarios. The Transient Reactor Test Facility (TREAT) located at the Idaho National Laboratory has developed a testing apparatus architecture to test fuels and claddings at prototypic conditions. The Transient Water Irradiation System (TWIST) is the latest iteration of a testing device capable of conducting loss of coolant accidents (LOCAs) in TREAT. The Out-of-Pile Testing and Instrumentation TWIST (OPTI-TWIST) is an electrically heated device that is analogous to TWIST. OPTI-TWIST allows for detailed instrumentation and thermal-hydraulic characterization. TWIST ultimately aims to conduct the most advanced in-situ diagnostics to evaluate FFRD in a prototypic LOCA. Moreover, it will explore the phenomenological bifurcation of a decay-energy heat up driven LOCA and a stored-energy heat up driven LOCA. The instrumentation suite includes conventional thermocouples and pressure transducers in addition to an electro impedance sensor, an acoustic emission sensor, an optical pressure sensor, and an optical pyrometer. Characterizing these instruments in OPTI-TWIST eliminates complications of irradiation effects while preserving extreme thermal-hydraulic conditions. Finally, benchmarking both devices to a thermal-hydraulic code like the Reactor Excursion and Leak Analysis Program (RELAP)5-3D provides a unique opportunity for iteration. Pre-test predictions and post-test interpretations inform the physical designs, operational procedures, test conditions, and instrumentation types and positions.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

CCTE Irradiation Plan - PBNC 2024

This paper outlines the irradiation plan for the CCTE-ANEEL-1A experiment in the ATR including irradiation locations, test train geometry, and a summary of the experiment design analysis. ATR irradiation is expected to begin in Spring 2024, with burnup targets of 20, 40, and 60 GWd/MTU.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Assessment of buffer-IPyC thermomechanical debonding behavior using new experimental strength data in BISON

TRIstructural ISOtropic (TRISO) fuel is a nuclear fuel commonly used in High Temperature Gas-cooled Reactors (HTGRs). A single sub-millimeter-diameter TRISO fuel particle consists of a spherical fuel kernel surrounded by four coating layers: a low-density pyrocarbon buffer layer, an inner pyrolytic carbon (IPyC) layer, a silicon carbide (SiC) layer, and an outer pyrolytic carbon (OPyC) layer. The kernel is commonly made of UO2 or a mixture of uranium carbide and uranium oxide (UCO). During reactor operation, the TRISO coating layers are subjected to irradiation-induced dimensional changes and the associated thermomechanical behavior of each layer. One of the observed behaviors is gap formation between the buffer and IPyC layer due to the porous buffer’s irradiation-induced shrinkage exceeding that of the IPyC layer. Not all irradiated particles will experience buffer-IPyC gap formation. The debonding may be partial, or it may be nearly total. However, from post-irradiation examination of UCO TRISO fuels irradiated as part of the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program, it was concluded that partial buffer-IPyC debonding was the most common type of buffer-IPyC interaction. To predict TRISO thermomechanical performance, multi-physics models have been built that are being continually updated and refined. The BISON code is a finite element-based nuclear fuel performance code that may be used for 1D, 2D, and 3D TRISO particle simulations. This code is used to calculate fuel temperature, kernel swelling, buffer densification, thermal and irradiation creep, fracture, and fission gas production and release. One of the recent additions to the BISON code is the ability to model the process of layer debonding. This paper will focus on the simulation results of the improved BISON debonding model that will utilize updated strengths measured from irradiated AGR TRISO fuel particles. The new experimental strength data from micromechanical tests of irradiated TRISO fuel samples were exercised in the BISON simulations and compared to baseline strength data to assess their applicability in the models. This also includes updated buffer-IPyC bond strengths to simulate layer delamination. Based on current experimental observations it is noted that the buffer-IPyC separation occurs not exactly at the junction of these two layers, but more on the side of the buffer layer. That observation is also implemented in the TRISO interface debonding model. This improved modeling approach using experimental strength data to characterize buffer-IPyC debonding and its potential subsequent cracking will be presented in the paper along with comparisons to available experimental observations.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Photon radiation effects on CdS/CuInSe2 thin film solar cells

The unknown tolerance of CuInSe2 cells to proton irradiation, was tested. It was shown that CdS/CuInSe2 solar cells have an inherent tolerance to irradiation by 1 MeV electrons up to at least 2 x 10 to the 16th power electrons/sq cm. Eleven, unencapsulated, 1 sq cm cells deposited on alumina substrates were irradiated with 1 MeV protons at normal incidence. The cells were exposed to six fluences ranging from 2.5 x 10 to the 10th power protons/sq cm to 5.0 x 10 to the 13th power protons/sq cm. After each interval of exposure, the cells were removed from the radiation chamber to undergo current/voltage characterization. It is shown that none of the cells electrical characteristics exhibited any degradation up to and including a fluence of 1 x 10 to the 11th power protons/sq cm. At fluences greater than this, the damage to the CuInSe2 cells V sub oc and fill factor (FF) was more severe than that exhibited by the Isc. The CuInSe2 cells proved to be approximately a factor of 50 more resistant to 1 MeV proton irradiation than silicon or gallium arsenide cells. Annealing of a CuInSe2 cell at 225 deg C for 6 minutes restored it to within 95% of its initial efficiency.

Dursch, H.↗

Effect of X-Rays on the Mechanical Properties of Aluminized FEP Teflon(R)

Pieces of the multilayer insulation (MLI) that is integral to the thermal control of the Hubble Space Telescope (HST) have been returned by two servicing missions after 3.6 and 6.8 years in orbit. They reveal that the outer layer, which is made from 5 mil (0.13 mm)thick aluminized fluorinated ethylene propylene(FEP) Teflon(R), has become severely embrittled. Although possible agents of this embrittlement include electromagnetic radiation across the entire solar spectrum, trapped particle radiation, atomic oxygen, and thermal cycling, intensive investigations have not yielded unambiguous causes. Previous studies utilizing monoenergetic photons in the 69-1900 eV range did not cause significant embrittlement, even at much higher doses than were experienced by the HST MLI. Neither did x-rays in the 3 to 10 keV range generated in a modified electron beam evaporator. An antidotal aluminized FEP sample that was exposed to an intensive dose from unfiltered Mo x-ray radiation from a rotating anode generator, however, did show the requisite embrittlement. Thus, a study was undertaken to determine the effects of x-ray exposure on the embrittlement of aluminized FEP in hopes that it might elucidate the HST MLI degradation mechanism. Tensile specimens of aluminized 5 mil thick FEP were exposed to a constant fluence of unfiltered x-ray radiation from a Mo target whose maximum energy ranged from 20-60 kV. Other samples were annealed, thermally cycled (100x) between 77-333 K, or cycled and irradiated. Tensile tests and density measurements were then performed on the samples. Only the samples which had been irradiated had the drastically reduced elongation-to-break, characteristic of the HST samples. Thermal cycling may accelerate the embrittlement, but the effect was near the scatter in the measurements. Annealing and thermal cycling had no apparent effect. Only the samples which had been irradiated and annealed showed significant density increases, likely implicating polymer chain scission and annealing.

Gaier, James R.↗

Effect of X-Rays on the Mechanical Properties of Aluminized FEP Teflon(trademark)

Pieces of the multilayer insulation (MLI) that is integral to the thermal control of the Hubble Space Telescope (HST) have been returned by two servicing missions after 3.6 and 6.8 years in orbit. They reveal that the outer layer, which is made from 5 mil (0.13 mm) thick aluminized fluorinated ethylenepropylene (FEP) Teflon. has become severely embrittled. Although possible agents of this embrittlement include electromagnetic radiation across the entire solar spectrum, trapped particle radiation, atomic oxygen, and thermal cycling, intensive investigations have not yielded unambiguous causes. Previous studies utilizing monoenergetic photons in the 69-1900 eV range did not cause significant embrittlement, even at much higher doses than were experienced by the HST MLI. Neither did x-rays in the 3 to 10 keV range generated in a modified electron bean evaporator. An antidotal aluminized FEP sample that was exposed to an intensive dose from unfiltered Mo x-ray radiation from a rotating anode generator, however, did show the requisite embrittlement. Thus, a study was undertaken to determine the effects of x-ray exposure on the embrittlement of aluminized FEP in hopes that it might elucidate the HST MLI degradation mechanism. Tensile specimens of aluminized 5 mil thick FEP were exposed to a constant fluence of unfiltered x-ray radiation from a Mo target whose maximum energy ranged from 20-60 kV. Other samples were annealed, thermally cycled (100x) between 77-333 K, or cycled and irradiated. Tensile tests and density measurements were then performed on the samples. Only the samples which had been irradiated had the drastically reduced elongation-to-break, characteristic of the HST samples. Thermal cycling may accelerate the embrittlement, but the effect was near the scatter in the measurements. Annealing and thermal cycling had no apparent effect. Only the samples which had been irradiated and annealed showed significant density increases, likely implicating polymer chain scission and annealing.

Gaier, James R.↗