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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

X-ray spectroscopic investigation of crystal fields in Ce 2 Rh 1 − x Ir x In 8 heavy fermions

The higher dimensionality in the crystal fields of the Ce 2 M In 8 ( M = Rh , Ir ) compounds and its interplay with hybridization and disorder are key ingredients to understand the complex phase diagrams by this family, which have been explored extensively by macroscopic techniques. Here, we present an investigation of the crystal-electric field schemes of Ce 2 Rh 1 − x Ir x In 8 using x-ray absorption spectroscopy. Our full multiplet calculations for the 4 f 1 configuration of Ce 3 + to describe the temperature-dependent linear dichroism in Ce 2 M In 8 are consistent with a Γ 7 1 = 1 − α 2 · | ∓ 3 2 〉 − | α | · | ± 5 2 〉 ground state containing a predominant | ± 3 / 2 〉 contribution that increases further with x . This enhancement is believed to favor superconductivity in Ce-based heavy fermion materials, observed in previous results in the Ce M In 5 family. Our recent observations shed light on the unexpected emergence of the ambient-pressure superconducting dome in the center of the composition phase diagram and its subsequent suppression on the Ir-rich side due to the early onset of fluctuations associated with the structurally more disordered state, inferred from previous neutron magnetic diffraction experiments. Published by the American Physical Society 2024

Christovam, D. S. (ORCID:0000000250698107)↗
DOE OSTI2022

Emergence of Spinons in Layered Trimer Iridate Ba 4 Ir 3 O 10

Spinons are well-known as the elementary excitations of one-dimensional antiferromagnetic chains, but means to realize spinons in higher dimensions is the subject of intense research. Here, we use resonant x-ray scattering to study the layered trimer iridate Ba 4 Ir 3 O 10 , which shows no magnetic order down to 0.2 K. An emergent one-dimensional spinon continuum is observed that can be well-described by XXZ spin-1/2 chains with magnetic exchange of ~55 meV and a small Ising-like anisotropy. With 2% isovalent Sr doping, magnetic order appears below TN=130 K along with sharper excitations, indicating that the spinons become more confined in (Ba 1-x Sr x ) 4 Ir 3 O 10 . We propose that the frustrated intra-trimer interactions effectively reduce the system into decoupled spin chains, the subtle balance of which can be easily tipped by perturbations such as chemical doping. Our results put Ba 4 Ir 3 O 10 between the one-dimensional chain and two-dimensional quantum spin liquid scenarios, illustrating a new way to suppress magnetic order and realize fractional spinons.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Mid-wave to near-IR optoelectronic properties and epsilon-near-zero behavior in indium-doped cadmium oxide

Indium-doped cadmium oxide (In:CdO) thin films exhibit tunable epsilon-near-zero (ENZ) modal frequencies across a wide spectral range, bridging the mid-wave and near-infrared (IR). In:CdO thin films are prepared by reactive cosputtering from metallic Cd and In targets using high-power impulse magnetron sputtering (HiPIMS) and radio frequency sputtering, respectively. Using this approach, CdO thin films with carrier concentrations ranging from 2.3 × 10 19 to 4.0 × 10 20 cm –3 and mobilities ranging from 300 to 400 cm 2 /Vs are readily achieved. UV-VIS absorption spectra are used to measure optical bandgap, revealing a Burstein-Moss shift of 0.58 eV across the doping range investigated. In this work, optical measurements demonstrate the tunability of near-perfect plasmonic ENZ absorption across the mid-wave and into the near-IR spectral ranges by controlling the carrier concentration through doping, while tuning the film thickness for impedance matching. In comparison to other dopants that can be introduced to HiPIMS-deposited CdO, In offers the largest range of carrier concentrations while maintaining high mobility, thus allowing for the widest accessibility of the IR spectrum of a single plasmonic material grown by sputtering.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Anomalous proximitized transport in metal/quantum magnet heterostructure Bi 2 Ir 2 O 7 /Yb 2 Ti 2 O 7

Fluctuations of quantum spins play a crucial role in the emergence of exotic magnetic phases and excitations. The lack of the charge degree of freedom in insulating quantum magnets, however, precludes such fluctuations from mediating electronic transport. Here, we show that the quantum fluctuations of a localized frustrated magnet induce strong proximitized charge transport of the conduction electrons in a synthetic heterostructure comprising an epitaxial Bi 2 Ir 2 O 7 ultrathin film on a single crystal of Yb 2 Ti 2 O 7 . The proximity effects are evidenced by the scaling behavior of the Bi 2 Ir 2 O 7 resistance in correspondence with the dynamic scaling of the dynamic spincorrelation function of Yb 2 Ti 2 O 7 , which is a result of quantum fluctuations near a multiphase quantum critical point. The proximitized transport in Bi 2 Ir 2 O 7 can be effectively tuned by a magnetic field through suppressing the quantum spin fluctuations (QSFs) as well as inducing transitions via magnetic anisotropy in Yb 2 Ti 2 O 7 . In this study, we establish a pathway for harnessing QSFs in magnetic insulators with electric transport, offering exciting prospects for potential applications in the realm of quantum spintronics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Measurement of 𝐷-line energies in sodiumlike Ir

We report measurements of the 𝐷 1 and 𝐷 2 transition energies in Na-like Ir (Ir 66+ ). The 𝐷 1 3⁢𝑠−3⁢𝑝 1/2 transition energy, measured in the extreme ultraviolet (EUV) region at 169.977 ± 0.005 eV with a relative uncertainty of 29 ppm, represents one of the most precise 𝐷-line energy measurements to date for high atomic numbers 𝑍 ≥ 30. The 𝐷 2 3⁢𝑠−3⁢𝑝 3/2 transition energy, measured in the x-ray region, is 621.11 ± 0.06 eV. Therefore, there is a fine-structure separation of 451.13 ± 0.06 eV for the Na-like Ir 3⁢𝑝 levels. We present theoretical calculations of these energies using quantum electrodynamic-extended relativistic many-body perturbation theory and multiple-configuration Dirac-Hartree-Fock methods, and discuss the discrepancies between experimental and theoretical values. The prospect of determining the absolute nuclear charge radii of heavy elements, including rare isotopes, from these measurements is explored.

Atomic spectra↗
NASA NTRS1973

CO2 removal by solid amine sorbents. 1: Experimental studies of amine resin IR-45 with regard to spacecraft applications. 2: Computer program for predicting the transient performance of solid amine sorbent systems

The sorbent behavior of solid amine resin IR-45 with regard to potential use in regenerative CO2-removal systems for manned spacecraft is considered. Measurements of equilibrium sorption capacity of IR-45 for water and for CO2 are reported, and the dynamic mass transfer behavior of IR-45 beds is studied under conditions representative of those expected in a manned spacecraft. A digital computer program was written for the transient performance prediction of CO2 removal systems comprised of solid amine beds. Also evaluated are systems employing inorganic molecular-sieve sorbents. Tests show that there is definitely an effect of water loading on the absorption rate.

Wright, R. M.↗
NASA NTRS1981

Structure of the St. Francois Mountains and surrounding lead belt, S. E. Missouri: Inferences from thermal IR and other data sets

Day-IR, day-visible, and night-IR image data sets were analyzed. All three images were contrast enhanced, using a linear stretch. The night-IR image was destriped using a box-car filtering approach. Apparent thermal inertia images were generated from the data. The enhanced data and the apparent thermal inertia image were also registered and overlayed onto shaded relief images depicting topography and onto a colored version of the Missouri geologic map. The combination of the apparent thermal inertial image and the shaded relief map proved to have the greatest discriminability in terms of portraying linear features. The reason seems to be that the vegetation canopy on the Ozark Plateau is different topography, tend to emphasize subtle topographic effects.

Arvidson, R. E.↗
NASA NTRS1981

Inversion technique for IR heterodyne sounding of stratospheric constituents from space platforms

The techniques which have been employed for inversion of IR heterodyne measurements for remote sounding of stratospheric trace constituents usually rely on either geometric effects based on limb-scan observations (i.e., onion peel techniques) or spectral effects by using weighting functions corresponding to different frequencies of an IR spectral line. An experimental approach and inversion technique are discussed which optimize the retrieval of concentration profiles by combining the geometric and the spectral effects in an IR heterodyne receiver. The results of inversions of some synthetic CIO spectral lines corresponding to solar occultation limb scans of the stratosphere are presented, indicating considerable improvement in the accuracy of the retrieved profiles. The effects of noise on the accuracy of retrievals are discussed for realistic situations.

Abbas, M. M.↗
NASA NTRS1982

Very large ground-based telescopes for optical and IR astronomy

Methods for improving the light grasp by an order of magnitude for earth-based observations of astrophysical objects are reviewed. Noting that the atmosphere is opaque below 0.3 micron and that techniques have been developed to make corrections for the atmospheric distortion, fully diffraction limited IR performance at 10 microns is asserted to be practicable. The use of mirror-seeing with metal mirrors with thin faceplates and air cooling is outlined as a means to achieve subarcsec resolution. Designs are considered which involve multiple sections to gain effective large aperture viewing for spectroscopy, using Si CCD detectors, and heterodyne IR interferometry, but not for direct interferometry or certain IR measurements. The Multiple Mirror Telescope is described, including designs for four 7.5 m honeycomb glass primaries co-aligned in a single mount. Further discussion is devoted to the fabrication of mirror elements and electronic image stabilization.

Angel, J. R. P.↗
NASA NTRS1983

Structure of the Saint Francois Mountains and surrounding lead belt, south east Missouri: Inferences from thermal IR and other data sets

Several digital data sets were registered to a common base map for southern Missouri. These registered data sets were examined in an attempt to improve our understanding of the crustal structure and the relationships between structure and Pb-Zn-Cu, Fe, Mn, and Ba ores in the area. Data included land station reading of gravity, geologic data, and Heat Capacity Mapping Mission (HCMM) images. The HCMM day infrared (IR) images of Missouri displayed linear features, which parallel a newly discovered NW-SE trending Bouguer gravity low. The structural pattern over the gravity low suggests vertical uplift of the low density crust via isostatic readjustment and consequent fracturing of the Paleozoic sedimentary cover. The presence of a gravity low is interesting because rifts are often sites of extensive mineralization. The HCMM thermal data were also examined in conjunction with digital topography, land use, and LANDSAT MSS data to understand the phenomena that produce linears on the HCMM day IR images. Finally, the kinds of information that can be extracted from day-night IR pairs are discussed.

Arvidson, R. E.↗
NASA NTRS1984

Design of an orbital heating simulator using IR techniques

The design of an IR rig to supply and monitor radiation fluxes in order to verify a thermal math model is discussed. The design incorporates IR lamps, Calrods and baffles to best suit the requirements of the specific zones. The required fluxes are calculated from the IR lamp/Calrod configuration software which can account for the effect of specular baffles and surface absorptivities. Radiation intensities are measured using the absorbed flux technique. Sensors, with surface properties matched to the appropriate spacecraft zone, are calibrated under conditions identical to test. The rig itself is capable of reproducing all test conditions and is versatile enough to handle other spacecrafts.

Donato, M.↗
NASA NTRS1984

An aperture synthesis map of HCN emission close to W3 IRS 4

W3 has been observed in the J = 1-0 transition of HCN with the millimeter-wave interferometer at the Hat Creek Observatory with a resolution of 11.5 by 11.1 arcsec. The HCN emission is detected in an isolated cloud with a diameter of 40 arcsec. The cloud is located to the south of IRS 4 and the compact H II region C and coincides with the western far-IR cloud mapped at 400 microns by Jaffe (1983). The total mass of the cloud is estimated to be in the range 250-2500 solar masses. No HCN emission was detected around IRS 5, the location of the other 400 micron peak. Also, no evidence for a new (heretofore undetected at other wavelengths), young main-sequence star earlier than B0 was found in the new continuum map at 3 mm.

Wright, M. C. H.↗
NASA NTRS1985

Radio and optical observations of the jets from L1555 IRS 5

New high-sensitivity radio continuum and optical observations of jets associated with the recently formed star IRS 5 are presented. The observations suggest that IRS 5 is the source of a collimated high-velocity outflow of partially ionized gas that produces the observed bipolar molecular outflow in L1551. The emission from the jets can be traced for over 10 arcsec from IRS 5; the jets are aligned with the axis of the molecular bipolar outflow observed by Snell, Loren, and Plambeck (1981). The integrated radio spectrum of the jets is flat, indicating emission by an optically thin plasma. The total mass of ionized gas is estimated to be 0.4-8 x 10 to the -6th solar mass. The absence of optical emission from the northeast jet is best explained by the presence of a dense disk of gas that lies perpendicular to the outflow axis which obscures the northeast jet and may also be responsible for collimating the outflow into two initially opposed jets.

Snell, R. L.↗
NASA NTRS1987

Evidence for extended IR emission in NGC2798 and NGC6240

Extended emission at 10 and 20 microns can be used to distinguish starbursts from monsters as the underlying energy source driving the luminous infrared emission in the central regions of galaxies. The spatial extent of the mid infrared emission in the interacting galaxy NCG 2798 and the merger NGC 6240 were investigated. The 10 and 20 micron profiles of the IR source in NGC 2798 are significantly wider than beam profiles measured on a standard star, supporting a starburst interpretation of its IR luminosity. For NGC 6240 there is marginal evidence for an extended 10 micron source, suggesting that a significant fraction of its IR luminosity could be produced by a burst of star formation.

Wright, G. S.↗
NASA NTRS1986

Extended far-infrared emission associated with mass outflows from young stars: L1551 IRS 5

Coadded IRAS survey data have been examined in the L1551 region. Extended low-surface-brightness 60 and 1200-micron emission is aligned with the molecular outflow from L1551 IRS 5. The morphology and the uniform surface brightness and color temperature of the IR emission suggest that the wind from IRS 5 is the source of this emission. It is suggested that radiative heating of grains by photons generated at the stellar wind/cloud interface is a major contributor to the extended infrared emission.

Edwards, S.↗
NASA NTRS1988

The IRAS Bright Galaxy Sample. III - 1-10 micron observations and coadded IRAS data for galaxies with L(IR) equal to or greater than 10 to the 11th solar luminosities

This paper presents the results of 1-10-micron observations and coadded IRAS data on 61 galaxies from the Bright Galaxy Sample, with IR luminosities, L(IR), equal to or greater than 10 to the 11th solar luminosities. It was found that an increase in the total L(IR) above 10 to the 11th solar luminosity is correlated with increased emission from hot dust with characteristic temperatures about 800 K. This hot dust contributes a substantial fraction of the 2.2- and 3.7-micron emission, resulting in a greatly increased dispersion in R(3.7/1.6) and R(2.2/1.6) for these high-luminosity galaxies, relative to lower-luminosity galaxies. This excess hot-dust emission appears to 'turn on' at luminosities of about 10 to the 11th solar luminosity. The spatial distribution of the 10-micron emission indicated a substantial extended component for most of the galaxies in this sample, implying that star-formation processes contribute significantly to the luminosities.

Carico, David P.↗
NASA NTRS1988

High spatial resolution infrared imaging of L1551-IRS 5 - Direct observations of its circumstellar envelope

Images of L1551-IRS 5 were obtained at 1.65, 2.2, and 3.8 microns using the University of Rochester's Infrared Array Camera. It is found that IRS 5 is spatially resolved, and that it is elongated: the observed FWHM size of IRS 5 is 4.1 x 2.8 arcsec-squared at 2.2 microns. These observations are interpreted in terms of a flattened circumstellar envelope that is viewed from about 18 deg above its equatorial plane, a configuration that has been treated theoretically by Lefevre et al. In this model the central star is not seen directly, but only light scattered toward the observer from the visible polar region, where the envelope is thinnest, is observed. It is deduced that the envelope has a diameter of 1000 AU, a molecular hydrogen density of greater than or approximately equal to 4 x 10 to the 6th/cu cm, and a mass of greater than or approximately equal to 0.02 M solar mass, which results in an extinction of Av greater than about 33 mag to the central source.

Moneti, Andrea↗
NASA NTRS1989

Test chamber for low-background IR focal plane testing

A unique and versatile vacuum chamber has been designed for JPL's IR Focal Plane Technology Group. This chamber is equipped with multiple ports for cryogen and electrical vacuum feedthroughs, pumping units, vacuum gages, sources, and detector camera heads. The design incorporates a liquid-nitrogen-cooled optical table and radiation shield for low-background IR detector testing. Focal planes can be tested at temperatures ranging from 300 K to that of liquid helium. This paper describes the design and construction of this low-background IR focal plane test chamber and discusses some of its distinctive features. An analysis of the test chamber's performance is also presented.

Staller, Craig↗