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Circumstellar matter in Algols and Serpentids

A systematic search is reported for phenomena associated with circumstellar matter in interacting binary systems of the Algol and W Serpentis type. Ultraviolet emission lines have been detected by the author in 10 Algols and 6 Serpentids. No conspicuous difference exists between systems with disk accretion and those with direct stream impact. Evidence is indicated that the lines are formed predominantly by scattering in an induced stellar wind. Relative intensity of Fe II and Fe III emissions appears to be correlated with the spectral type of the gainer. It is suggested that in the Serpentids we see a thick disk nearly edge-on, but that the emission lines indicate the nature of the gainer inside.

Plavec, Mirek J.↗

LASE Measurements of Water Vapor, Aerosol, and Cloud Distributions in Saharan Air Layers and Tropical Disturbances

LASE (Lidar Atmospheric Sensing Experiment) on-board the NASA DC-8 measured high resolution profiles of water vapor and aerosols, and cloud distributions in 14 flights over the eastern North Atlantic during the NAMMA (NASA African Monsoon Multidisciplinary Analyses) field experiment. These measurements were used to study African easterly waves (AEWs), tropical cyclones (TCs), and the Saharan Air Layer(s) (SAL). Interactions between the SAL and tropical air were observed during the early stages of the TC development. These LASE measurements represent the first simultaneous water vapor and aerosol lidar measurements to study the SAL and its impact on AEWs and TCs. Examples of profile measurements of aerosol scattering ratios, aerosol extinction coefficients, aerosol optical thickness, water vapor mixing ratios, RH, and temperature are presented to illustrate their characteristics in SAL, convection, and clear air regions. LASE data suggest that the SAL suppresses low-altitude convection at the convection-SAL interface region. Mid-level convection associated with the AEW and transport are likely responsible for high water vapor content observed in the southern regions of the SAL on August 20, 2008. This interaction is responsible for the transfer of about 7 x 10(exp 15) J latent heat energy within a day to the SAL. Measurements of lidar extinction-to-backscatter ratios in the range 36+/-5 to 45+/-5 are within the range of measurements from other lidar measurements of dust. LASE aerosol extinction and water vapor profiles are validated by comparison with onboard in situ aerosol measurements and GPS dropsonde water vapor soundings, respectively.

Ismail, Syed↗

Initial PVO evidence of electron depletion signatures downstream of Venus

This first analysis of Pioneer Venus Orbiter (PVO) plasma analyzer electron measurements obtained in early 1992 during teh PVO entry phase of the mission indicates the presence downstream from the terminator of a depletion or 'bite out' of energetic ionosheath electrons similar to that observed on Mariner 10. There is more than one possible explanation for this energetic electron depletion. If it is due to atmospheric scattering, the electrons traveling along draped magnetic flux tubes that thread through the Venus neutral atmosphere would lose energy from impact ionization with oxygen. The cross-section for such electron impact ionization of oxygen has a peak near 100 eV, and it remains high above this energy, so atmospheric loss could provde a natural process for electrons at these energies to be selectively removed. In this case, our results are consistent with the Kar et al. (1994) study of PVO atmospheric entry ion mass spectrometer data, which indicates that electron impact plays a significant role in maintaining the nightside ionosphere. Although it is appealing to interpret the energetic electron depletion in terms of direct atmospheric scattering, alternatively it could result from strong draping which connects the depletion region magnetically to the weak downstream bow shock and thereby reduces the electron source strength.

Intriligator, D. S.↗

Initial PVO Evidence of Electron Depletion Signatures Downstream of Venus

This first analysis of Pioneer Venus Orbiter (PVO) plasma analyzer electron measurements obtained in early 1992 during the PVO entry phase of the mission indicates the presence downstream from the terminator of a depletion or "bite out" of energetic ionosheath electrons similar to that observed on Mariner 10. There is more than one possible explanation for this energetic electron depletion. If it is due to atmospheric scattering, the electrons traveling along draped magnetic flux tubes that thread through the Venus neutral atmosphere would lose energy from impact ionization with oxygen. The cross-section for such electron impact ionization of oxygen has a peak near 100 eV, and it remains high above this energy, so atmospheric loss could provide a natural process for electrons at these energies to be selectively removed. In this case, our results are consistent with the Kar et al. (1994) study of PVO atmospheric entry ion mass spectrometer data which indicates that electron impact plays a significant role in maintaining the nightside ionosphere. Although it is appealing to interpret the energetic electron depletion in terms of direct atmospheric scattering, alternatively it could result from strong draping which connects the depletion region magnetically to the weak downstream bow shock and thereby reduces the electron source strength.

Intriligator, D. S.↗

Radiative Heating Rate Profiles over the Southeast Atlantic Ocean during the 2016 and 2017 Biomass Burning Seasons

Marine boundary layer clouds, including the transition from stratocumulus to cumulus, are poorly represented in numerical weather prediction and general circulation models. Further uncertainties in the cloud structure arise in the presence of biomass burning carbonaceous aerosol, as is the case over the southeast Atlantic Ocean where biomass burning aerosol is transported from the African continent. As the aerosol plume progresses across the southeast Atlantic Ocean, radiative heating within the aerosol layer has the potential to alter the thermodynamic environment and therefore the cloud structure; however, limited work has been done to quantify this along the trajectory of the aerosol plume in the region. The deployment of the First Atmospheric Radiation Measurement Mobile Facility in support of the Layered Atlantic Smoke Interactions with Clouds field campaign provided a unique opportunity to collect observations of cloud and aerosol properties during two consecutive biomass burning seasons during July through October of 2016 and 2017 over Ascension Island (7.96 °S, 14.35 °W). Using observed profiles of temperature, humidity, and clouds from the field campaign, alongside aerosol optical properties from MERRA-2 as input for the Rapid Radiation Transfer Model, profiles of the radiative heating rate due to aerosols and clouds were computed. Radiative heating is also assessed across the southeast Atlantic Ocean using an ensemble of back trajectories from the Hybrid Single Particle Lagrangian Integrated Trajectory Model. Idealized experiments using the Rapid Radiation Transfer Model with and without aerosols and a range of values for the single scattering albedo demonstrate that shortwave heating within the aerosol layer above Ascension Island can locally range between 2 and 8 K per day depending on the aerosol optical properties, though impacts of the aerosol can be felt elsewhere in the atmospheric column. When considered under clear conditions, the aerosol has a cooling effect at the TOA and based on the observed cloud properties at Ascension Island, the cloud albedo is not large enough to overcome this. Shortwave radiative heating due to biomass burning aerosol is not balanced by additional longwave cooling, and the net radiative impact results in a stabilization of the lower troposphere. However, these results are extremely sensitive to the single scattering albedo assumptions in models.

Allison B. Marquardt Collow↗

The tektite problem

Small glassy pebbles, called tektites, are found in widely scattered locations around the world. These tektites appear much like volcanic glass obsidian, but their chemical composition is different from that of any terrestrial lava and they contain far less water and none of obsidian's characteristic microcrystals. No one has ever found the mother lode of a field of tektites. They cannot, therefore, be the product of terrestrial volcanism. Recently acquired knowledge about the moon's surface confirms earlier indications that tektites cannot be bits of lunar soil propelled to the earth by the impact of meteorites on the moon. According to one of two remaining possibilities tektites are bits of terrestrial sedimentary rock excavated by meteorites striking the earth's surface, melted by the heat of impact, and congealed into glass as they travel above the atmosphere to the scattered sites where they are found. The other possibility is that tektites are the remains of gobs of lava fired at the earth by volcanic activity on the moon.

Okeefe, J. A.↗

[MODIS Investigation]

Our first activity is based on delivery of code to Bob Evans (University of Miami) for integration and eventual delivery to the MODIS Science Data Support Team. As we noted in our previous semi-annual report, coding required the development and analysis of an end-to-end model of fluorescence line height (FLH) errors and sensitivity. This model is described in a paper in press in Remote Sensing of the Environment. Once the code was delivered to Miami, we continue to use this error analysis to evaluate proposed changes in MODIS sensor specifications and performance. Simply evaluating such changes on a band by band basis may obscure the true impacts of changes in sensor performance that are manifested in the complete algorithm. This is especially true with FLH that is sensitive to band placement and width. The error model will be used by Howard Gordon (Miami) to evaluate the effects of absorbing aerosols on the FLH algorithm performance. Presently, FLH relies only on simple corrections for atmospheric effects (viewing geometry, Rayleigh scattering) without correcting for aerosols. Our analysis suggests that aerosols should have a small impact relative to changes in the quantum yield of fluorescence in phytoplankton. However, the effect of absorbing aerosol is a new process and will be evaluated by Gordon.

Abbott, Mark R.↗

Lunar origin: role of giant impacts

The explanation that lunar origin involved giant impacts remains attractive. Large planetesimals are consistent with current accretion models, and may have been widely scattered in the early solar system; their existence is a reasonable, assumption in Moon origin models. Isotopic data require the Moon's formation primarily from local material resembling Earth's upper mantle, not material from elsewhere in the solar system. Giant impacts are stochastic, class predictable events that would provide the required type of ejected Earth mantle material without requiring large moons to form near other planets (a problem with less stochastic processes). Such material may have mixed with incoming meteorites during lunar formation, affecting lunar chemistry.

Hartmann, W. K.↗

Lunar Origin: Role of Giant Impacts

The explanation that lunar origin involved giant impacts remains attractive. Large planetesimals are consistent with current accretion models, and may have been widely scattered in the early solar systems; their existence is a reasonably, assumption in Moon origin models. Isotopic data require the Moon's formation primarily from local material resembling Earth's upper mantle, not material from elsewhere in the solar system. Giant impacts are stochastic, class predictable events that would provide the required type of ejected Earth mantle material without requiring large moons to form near other planets (a problem with less stochastic processes). Such material may have mixed with incoming meteorites during lunar formation, affecting lunar chemistry.

Hartmann, W. K.↗

Modeling Atmosphere-Ocean Radiative Transfer: A PACE Mission Perspective

The research frontiers of radiative transfer (RT) in coupled atmosphere-ocean systems are explored to enable new science and specifically to support the upcoming Plankton, Aerosol, Cloud ocean Ecosystem (PACE) satellite mission. Given (i) the multitude of atmospheric and oceanic constituents at any given moment that each exhibits a large variety of physical and chemical properties and (ii) the diversity of light-matter interactions (scattering, absorption, and emission), tackling all outstanding RT aspects related to interpreting and/or simulating light reflected by atmosphere-ocean systems becomes impossible. Instead, we focus on both theoretical and experimental studies of RT topics important to the science threshold and goal questions of the PACE mission and the measurement capabilities of its instruments. We differentiate between (a) forward (FWD) RT studies that focus mainly on sensitivity to influencing variables and/or simulating data sets, and (b) inverse (INV) RT studies that also involve the retrieval of atmosphere and ocean parameters. Our topics cover (1) the ocean (i.e., water body): absorption and elastic/inelastic scattering by pure water (FWD RT) and models for scattering and absorption by particulates (FWD RT and INV RT); (2) the air-water interface: variations in ocean surface refractive index (INV RT) and in whitecap reflectance (INV RT); (3) the atmosphere: polarimetric and/or hyperspectral remote sensing of aerosols (INV RT) and of gases (FWD RT); and (4) atmosphere-ocean systems: benchmark comparisons, impact of the Earth's sphericity and adjacency effects on space-borne observations, and scattering in the ultraviolet regime (FWD RT). We provide for each topic a summary of past relevant (heritage) work, followed by a discussion (for unresolved questions) and RT updates.

Chowdhary, Jacek↗

Principles and procedures for determining absolute differential electron-molecule (atom) scattering cross sections

Procedures and calibration techniques for measuring the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples. The elastic DCS for the molecule under study is first determined by calibration against helium using the relative flow technique. The second step involves the production of energy-loss spectra for the instrument response function, the unfolding of overlapping inelastic structures and the normalization of inelastic intensities to the elastic cross sections. It is concluded that this method of determining absolute differential electron-molecule (atom) scattering cross sections is generally applicable and provides reliable results.

Nickel, J. C.↗

Tunable lasers and their application in analytical chemistry

The impact that laser techniques might have in chemical analysis is examined. Absorption, scattering, and heterodyne detection is considered. Particular emphasis is placed on the advantages of using frequency-tunable sources, and dye solution lasers are regarded as the outstanding example of this type of laser. Types of spectroscopy that can be carried out with lasers are discussed along with the ultimate sensitivity or minimum detectable concentration of molecules that can be achieved with each method. Analytical applications include laser microprobe analysis, remote sensing and instrumental methods such as laser-Raman spectroscopy, atomic absorption/fluorescence spectrometry, fluorescence assay techniques, optoacoustic spectroscopy, and polarization measurements. The application of lasers to spectroscopic methods of analysis would seem to be a rewarding field both for research in analytical chemistry and for investments in instrument manufacturing.

Steinfeld, J. I.↗

Electron impact spectroscopy of high temperature species

The application of the methods of electron impact spectroscopy to the study of high temperature species is discussed. Electron scattering by metal vapors (Ba, Bi, Cu, Mn, Tl, Zn), alkali halide molecules, and KOH are described as demonstrative examples.

Trajmar, S.↗

Experiments on the formation, properties and processing of cosmic dust

The results from various experiments on the formation, properties, and processing of potential silicate components of cosmic dust are reviewed. Consideration is given to the role of evaporation and condensation in grain formation, nucleation experiments using volatile compounds and refractory species, and efforts to produce particles that might represent cosmic grains. Other studies include particle scattering experiments, studies on the growth of clusters, the sputtering process, the impact of temperature on sputtering yield and optical properties, and experimental and theoretical studies of the structure of particulate aggregates.

Donn, B. D.↗

A Survey of Electron Impact Cross-Sections for Halogens and Halogen Compounds of Interest to Plasma Processing

Published electron impact cross section data on halogens Cl2, F2, and halogen containing compounds such as Cx Fy, HCl, Cx Cly Fz are reviewed and critically evaluated based on the information provided by various researchers. The present work reports data on electron impact excitation, ionization, dissociation, electron attachment, electron detachment, and photo detachment. Elastic scattering cross sections and data on bulk properties such as diffusion coefficients in various background gases are also evaluated. Since some of the cross sectional data is derived from indirect measurements such as drift velocity, care has been taken to reconcile the differences among the reported data with due attention to the measurement technique. In conclusion, the processes with no or very limited amount of data and questionable set of data are identified and recommendation for further research direction is made.

Sharma, S. P.↗

Lunar Simple Crater Impact Melt Volumes

Impact melt is observed in simple lunar craters having diameters as small as less than 200 m. The presence of ponds of impact melt on the floor of such small craters is interpreted to indicate vertical impacts. Data from the LRO LROC and LOLA experiments allow quantitative estimates of the volume of impact melt in simple crater. Such estimates allow for validation of theoretical models of impact melt generation and examination of target effects. Preliminary data have considerable scatter but are broadly consistent with the models.

Plescia, Jeffrey B.↗

Measurements of the absorption coefficient of stratospheric aerosols

The absorption coefficients of stratospheric aerosols are measured using a variation on the integrating plate method. The technique is based on the decrease in the transparency of a substrate when an absorbing aerosol is deposited on it. A Lambert scatterer is placed behind the substrate to integrate forward scattered light and minimize the effect of scattering on the measurement. The low pressure in the stratosphere is used for the direct impaction of particles onto a narrow strip of opal glass. The eight samples collected had a median value of 4 x 10 to the -9th m with an uncertainty of + or - 5 x 10 to the -9th m. If this absorption is due to graphitic carbon, then its concentration is estimated at about 0.4 ng/cu m, or about 0.25% of the total aerosol mass concentration. Estimates of the aerosol scattering coefficients based on satellite extinction inversions result in an aerosol single-scattering albedo in the range of 0.96-1.0.

Ogren, J. A.↗