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At least 181 records · Page 10
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ARRISTOTLE Simulation Demo

NASA’s Katherine Johnson Independent Verification and Validation (NASA IV&V) Jon McBride Software Testing and Research (JSTAR) laboratory has developed the Advanced Risk Reduction Integrated Software Test and Operations Tri-program Lightweight Environment (ARRISTOTLE). ARRISTOTLE is a digital twin of NASA’s Artemis mission. ARRISTOLE executes the true SLS and Orion flight binaries integrated on a single laptop computer. This demo will showcase the execution of the full Artemis liftoff. Once airborne, an inflight anomaly will be injected, resulting in Orion detaching from the booster. The Launch Abort System (LAS) will safely bring Orion back to earth. The Unity game engine is used to visualize the flyout as flight software executes.

emulation↗
DOE OSTI2020

Building [U IV 70 (OH) 36 (O) 64 ] 4– oxocluster frameworks with sulfate, transition metals, and U V

Uranium (IV) oxide clusters, colloids, and materials are designed and studied for 1) nuclear materials applications, 2) understanding environmental fate and transport of actinides, and 3) exploring the complex bonding behavior of open-shell f-elements. U IV -oxyhydroxsulfate clusters are particularly relevant in industrial processes and in nature. Recent studies have shown that counter-cations to these polynuclear anions differentiate rich structural topologies in the solid-state. Here we present nine different structures with wheel-shaped [U 70 (OH) 36 (O) 64 (SO 4 ) 60 ] 4- (U 70 ) linked into 1-dimensional and 2-dimensional frameworks with sulfate, divalent transition metals (Cr II , Fe II , Co II , Ni II ) and U V . Here, the small-angle X-ray scattering of these phases dissolved in butylamine reveals differing supramolecular assembly of U 70 clusters, controlled primarily by sulfates. However, observed trends in transition metal linking guide future design of U 70 -materials with different topologies. Finally, U 70 linking via U IV -O-U V -O-U IV bridges presents a rare example of mixed oxidation state uranium oxides without disorder.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1995

Photospheric, circumstellar, and interstellar features of HE, C, N. O, and Si in the HST spectra of four hot white dwarf stars

This paper reports on the observations of four hot white dwarf stars with the spectrographs on the Hubble Space Telescope (HST). The higher resolving power and higher signal/noise, in comparison with IUE, reveals a very rich phenomomenology, including photospheric features from heavy elements, circumstellar features, and the first direct detection of accretion onto the white dwarf component of a binary system. Specific results include the following: Our observations of the ultrahot degenerate H1504+65 confirm that it has a photosphere which is depleted in both H and He, and reveals features of C IV and O VI. The spectrum fits previously published models extremely well. The intermediate-temperature DO star PG 1034+001 has an ultraviolet spectrum showing complex profiles of the well-known resonance doublets of C IV, N v, and Si IV. The O V 1371 line shows a clear separation into a photospheric and a circumstellar component, and it is likely that the same two components can explain the other lines as well. The cooler DA star GD 394 has an extensive system of heavy-element features, but their radial velocity is such that it is highly unlikely that they are formed in the stellar photosphere. Time-resolved spectra of the accreting white dwarf in the V 471 Tau binary system are briefly presented here; they do show the presence of C IV, Si IV, and He II. However, the C IV and He II lines are in emission, rather than in aborption as had been expected.

Shipman, Harry L.↗
DOE OSTI2023

Reversible Electrochemical Lithium Cycling in a Vanadium(IV)- and Niobium(V)-Based Wadsley–Roth Phase

Fast charging remains one of the greatest safety challenges in Li-ion batteries due to Li-dendrite growth occurring on graphite anodes if they are lithiated too quickly. The search for high-rate anodes has highlighted materials in the Wadsley–Roth (WR) shear phase family. The relative abundance of V compared with traditional WR compositions of Nb and W makes V-based phases attractive. However, the high voltage and poor reversibility typically associated with V redox have made V-rich WR phases less studied than Nb- and W-rich phases. Here, we show that a new V-rich Wadsley–Roth phase, V 7 Nb 6 O 29 , achieves excellent rate capability and 80% capacity retention after 228 cycles with a relatively low average voltage of 1.76 V vs Li/Li + compared with other V-rich WR phases. Single-crystal X-ray diffraction reveals a P4/m space group with repeating 2 × 2 × ∞ and 3 × 3 × ∞ blocks of V 4+ and Nb 5+ octahedra. Finally, combined neutron pair distribution function analysis, X-ray absorption spectroscopy, and density functional theory calculations show that V redox is the primary source of capacity and that cycling stability is provided by the stable octahedral coordination adopted by V 4+ in the material.

25 ENERGY STORAGE↗
DOE OSTI2026

Reduction of Np(v) to Np(iv) using oxalic acid: rethinking decades of nuclear processing conventions

Actinide oxalate precipitation has been ubiquitous in nuclear processing since the 1950s due to its simplicity at laboratory and production scales as both a means of actinide purification and as a key intermediate solid phase towards oxide production. Historical processing information has emphasized the need to reduce actinides, including neptunium (Np), to the tetravalent or trivalent state with chemical reducing agents prior to oxalate precipitation. This work revisits the established method and reveals that oxalic acid has an unexpected role as a reducing agent for Np(v/vi). Also, the study uncovers insights into the direct precipitation of Np(iv) oxalate from neptunyl solutions, as identified by spectroscopic and X-ray diffraction analyses. These findings challenge the long-standing notion that redox adjustment of actinides is necessary for oxalate processing.

Gilson, Sara [ORNL] (ORCID:0009000706842064)↗
DOE OSTI2022

Coordinated time variability of multi-phase ultra-fast outflows in J132216.25 + 052446.3

ABSTRACT We present a time variability analysis of broad absorption lines (BAL; spread over the velocity range of 5800–29 000 km s−1) seen in the spectrum of J132216.25 + 052446.3 (zem = 2.04806) at ten different epochs spanning over 19 yr. The strongest absorption component (BAL-A; spread over 5800–9900 km s−1) is made up of several narrow components having velocity separations close to C iv doublet splitting. The C iv, N v, and Si iv absorption from BAL-A show correlated optical depth variability without major changes in the velocity structure. A very broad and shallow absorption (BAL-C; spread over the velocity range 15 000–29 000 km s−1) emerged during our monitoring period coinciding with a dimming episode of J1322 + 0524. All the identified absorption lines show correlated variability with the equivalent widths increasing with decreasing flux. This together with the C iv emission line variability is consistent with ionization being the main driver of the correlated variability. The observed UV-continuum variations are weaker than what is required by the photoionization models. This together with a scatter in the C iv equivalent width at a given continuum flux can be understood if variations of the C iv ionizing photons are much larger than that of the UV continuum, the variations in the ionizing photon and UV fluxes are not correlated and/or the covering factor of the flow varies continuously. We suggest BAL-A is produced by a stable clumpy outflow located beyond the broad emission line region and BAL-C is a newly formed wind component located near the accretion disc and both respond to changes in the ionizing continuum.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1981

IUE observations of mass ejection by the close binary system AO Cassiopeiae

It is noted that 11 high-resolution spectra in the far-ultraviolet and two high-resolution spectra in the mid-ultraviolet were obtained. A high-velocity stellar wind exists as indicated by narrow shortward-displaced absorption features superposed on the P Cygni lines of N V, Si IV, and C IV. Absorption lines caused by N IV and C III are present and show nonorbital velocities of about -50 to -150 km/sec. Several weak photospheric lines of the primary star are detected. A few lines of Fe IV and Fe V are detectable near phase 0.50 and, less prominently, near phase 0.00. It is noted that the He II absorption line appears doubled except near phases 0.00 and 0.50 and that the weaker component appears to be attributable to the secondary component of the system. The mean velocity of the stellar wind is -1879 + or - 51(p.e.) km/sec and is nearly constant over the period of observation, although the absorption strength is found to vary.

Mccluskey, G. E.↗
NASA NTRS1982

Energy distribution in the strongly interacting binary system SX Cassiopeiae

IUE spectra and optical scans covering the 110-680 nm interval were obtained in a search for a source which would resolve the anomalous presence of strong Balmer emission lines in the SX Cas eclipsing binary system, which is inconsistent with the usual spectral classification of the components as A6 III + G6 III. The IUE spectra unexpectedly show such strong emission lines as those of C IV, N V and Si IV, which require higher temperatures that the already anomalously high Balmer lines, and a continuum several magnitudes higher than the extrapolated continuum of an A6 star. A model in which the UV continuum originates in the transition zone between the A6 star and an accretion disk fails to reproduce the observed energy distribution. A revision of component spectral types to B7 + K3 III removes the UV excess.

Plavec, M. J.↗
NASA NTRS1982

Ultraviolet spectroscopy of the nova-like variable V3885 Sagittarii /= CD -42 deg 14462/

Low-dispersion long and short wavelength IUE spectra of the nova-like system V3885 Sgr were obtained on 1979 August 24 UT. The UV spectrum exhibits strong, high-temperature absorption lines of C III, C IV, He II, N IV, N V, and Si IV which all have relatively large negative velocities of 600-1000 km/s at their line centers. The C IV (1550 A) features shows a P Cygni-type profile with a blueshifted absorption line; the presence of the P Cygni-type feature strongly suggests a significant mass outflow from the system in the form of a hot stellar wind. The observed continuum fluxes are fitted with theoretical accretion disk model fluxes, and a tentative physical interpretation of the observed spectral properties is presented.

Guinan, E. F.↗
NASA NTRS1983

Kinetics of the reactions of the acid anhydrides with aromatic amines in aprotic solvents

Work has revealed that diamine derivatives of diphenylmethane (IV), diphenyl ether (V), benzophenone (IV), fluorene (VII), and fluorenone (VIII) polymerizations with pyromellitic dianhydride in DMA were dependent on the basicity of the amine compound. The correlation between the basicity of the amine and its reactivity with phthalic anhydride was determined. Basicity measurements were made by potentiometric titration of each amine in an acetonitrile-water solvent system, from which the pKa of the amine could be determined. Reactivity was defined in terms of the second order rate constant derived form spectrophotometric examination of the reaction between each amine and phthalic anhydride in DMA. This reaction was expected to proceed in either one (for a monoamine) or two (for a diamine) stages.

Sugg, E.↗
NASA NTRS1986

Orbital variability in the wind of the massive X-ray binary HD 153919/4U1700-37

High resolution IUE spectra of HD 153919, the optical counterpart to 401700-37, were examined for evidence of the Hatchett-McCray effect. Although the resonance lines of C IV, N V, and Si IV are too heavily saturated to be very useful, the subordinate line of N IV at 1718 A clearly shows orbital variability in the correct sense to be explained as the removal of parent ions by the X-ray flux from the neutron star.

Howarth, Ian D.↗
NASA NTRS1987

The peculiar early-type emission line supergiant S 18/SMC - An optical and ultraviolet study

Spectroscopic observations of S 18/SMC, obtained in the visible at CTIO, the AAT, and ESO and in the UV with the IUE SWP and LWR instruments during 1978-1983, are reported. The data are presented in tables and spectra and characterized in detail. The variability of the object in He II, C IV, N IV, N V, and Si IV and the lack of detectable photometric variation between 120 and 1000 nm are discussed in terms of a stellar-envelope model with mass-loss rate greater than or equal to 0.00001 solar mass/yr and N abundance 3-5 times the solar value, corresponding to a transitional phase between extreme mass loss (near the Humphrey-Davidson limit) and the presupernova stage. The FUV flux is tentatively attributed to an extremely hot He-star or neutron-star companion.

Shore, S. N.↗
NASA NTRS1989

The winds of O-stars. II - The terminal velocities of stellar winds of O-type stars

The SEI method (Lamers et al., 1987) is used to obtain P Cygni profiles of the UV resonance lines of C IV, N V, and S IV and of the subordinate UV lines of N IV and C III observed in the spectra of 27 O-type stars. Theoretical profiles which include the turbulence effects agree well with the observations, and they can account for the deep absorption troughs, the shape of the violet absorption wings, and the wavelength of the emission peak. The resulting terminal velocities of the stellar winds are found to be systematically lower by about 400 km/s than previous estimates obtained using the Sobolev approximation (Castor and Lamers, 1979), suggesting that the narrow absorption components, observed in the UV resonance lines of O and B stars, reach the terminal velocity of the winds.

Groenewegen, M. A. T.↗
NASA NTRS1991

Search for correlated UV and x ray absorption of NGC 3516

NGC 3516, a low-luminosity Seyfert galaxy, is one of a small fraction of Seyfert galaxies that exhibit broad absorption in a resonance line. In order to determine whether the UV and x ray absorption in NGC 3516 are related, 5 IUE observations were obtained, quasi-simultaneously with 4 Ginga observations. The results are presented and discussed. The following subject areas are covered: short-term UV variability; emission lines; galactic absorption lines; the C IV, N V, and Si IV absorption features; lower limit on the carbon column density; estimate of the distance from the absorber to the continuum source; variability in the continuum and absorption; a comparison with BAL QSO's; and the x ray-UV connection.

Martin, Christopher↗
NASA NTRS1991

The binary Feige 24 - The mass, radius, and gravitational redshift of the DA white dwarf

Observations are reported which refine the binary ephemeris of the Feige 24 system, which contains a peculiar hot DA white dwarf and an M dwarf with an atmosphere illuminated by extreme ultraviolet radiation from the white dwarf. With the new ephemeris and a set of IUE high-dispersion spectra, showing phase-dependent redshifted C IV, N V, and Si IV resonance lines, the orbital velocity, and hence the mass (0.54 + or - 0.20 solar masses), and the gravitational redshift of the white dwarf (14.1 + or - 5.2 km/s) are determined independently. It is shown that the measured Einstein redshift is consistent with an estimated radius for the white dwarf obtained from a model atmosphere solid angle and a parallax measurement. This radius is twice the Hamada-Salpeter radius for the given mass and offers a prospect to investigate the presence of a massive hydrogen envelope in that white dwarf star.

Vennes, Stephane↗