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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Detection of acetylene in the infrared spectrum of comet Hyakutake

Comets are rich in volatile materials, of which roughly 80% (by number) are water molecules. Considerable progress is being made in identifying the other volatile species, the abundances of which should enable us to determine whether comets formed primarily from ice-covered interstellar grains, or from material that was chemically processed in the early solar nebula. Here we report the detection of acetylene (C2H2) in the infrared spectrum of comet C/1996 B2 (Hyakutake). The estimated abundance is 0.3-0.9%, relative to water, which is comparable to the predicted solid-phase abundance in cold interstellar clouds. This suggests that the volatiles in comet Hyakotake may have come from ice-covered interstellar grains, rather than material processed in the accretion disk out of which the Solar System formed.

Acetylene/analysis↗
DOE OSTI2017

Influence of Surface and Bulk Water Ice on the Reactivity of a Water-forming Reaction

On the surface of icy dust grains in the dense regions of the interstellar medium, a rich chemistry can take place. Due to the low temperature, reactions that proceed via a barrier can only take place through tunneling. The reaction H+H{sub 2}O{sub 2}⟶H{sub 2}O+OH is such a case with a gas-phase barrier of ∼26.5 kJ mol{sup −1}. Still, the reaction is known to be involved in water formation on interstellar grains. Here, we investigate the influence of a water ice surface and of bulk ice on the reaction rate constant. Rate constants are calculated using instanton theory down to 74 K. The ice is taken into account via multiscale modeling, describing the reactants and the direct surrounding at the quantum mechanical level with density functional theory (DFT), while the rest of the ice is modeled on the molecular mechanical level with a force field. We find that H{sub 2}O{sub 2} binding energies cannot be captured by a single value, but rather they depend on the number of hydrogen bonds with surface molecules. In highly amorphous surroundings, the binding site can block the routes of attack and impede the reaction. Furthermore, the activation energies do not correlate with the binding energies of the same sites. The unimolecular rate constants related to the Langmuir–Hinshelwood mechanism increase as the activation energy decreases. Thus, we provide a lower limit for the rate constant and argue that rate constants can have values up to two order of magnitude larger than this limit.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1985

Search for a shock wave around the Crab Nebula

The region surrounding the Crab Nebula is searched for the existence of a shock wave with the imaging instruments of the Einstein Observatory. The search is complicated by the scattering of nebula and pulsar X-rays from the imperfectly polished surfaces of the telescope mirror, as well as from interstellar grains along the line of sight. Both of these effects lead to the appearance of X-ray emission, in the form of an X-ray halo, beyond the boundaries of the nebula filaments. It is shown that the size, shape, and intensity of the halo around the Crab Nebula, above the contribution of mirror scattering, is consistent with what is expected from the scattering from interstellar grains. The upper limit on the X-ray emission from a shock wave is about 1 percent of the total 0.5-4 keV luminosity of the Crab, or about 2 x 10 to the 35th ergs/sec (assuming a distance of 2.2 kpc). This figure applies to a shell whose angular radius is 9 arcminutes. The upper limit is smaller (larger) for a shell of larger (smaller) size. This upper limit is an order of magnitude or more below the flux of Cas A, Tycho, and Kepler SNRs, which are 2 to 3 times younger, but it is still above that of SN 1006.

Mauche, C. W.↗
NASA NTRS1984

On the formation of meteoritic chondrules by aerodynamic drag heating in the solar nebula

During the formation of the solar nebula, interstellar grains were falling into the nebula with velocities of the order of 10 km/s at the radial distance where the meteorites were to form. This kinetic energy is 20 times the amount of thermal energy needed to melt the grains. The grains were decelerated by aerodynamic drag in the nebula. Where grain-rich parcels of interstellar material fell into the nebula, heat generated by drag could not be radiated away because of the opacity imparted to the system by the grains, and high temperatures were reached. In this situation presolar aggregations of grains would melt to form chondrules. Many of the properties of chondrules (and also Ca/Al-rich inclusions) are consistent with their formation by this means. The infall-heating concept provides a new framework in which the formation and significance of chondritic meteorites can be understood.

Wood, J. A.↗
DOE OSTI2013

REACTIVE DESORPTION AND RADIATIVE ASSOCIATION AS POSSIBLE DRIVERS OF COMPLEX MOLECULE FORMATION IN THE COLD INTERSTELLAR MEDIUM

The recent discovery of terrestrial-type organic species such as methyl formate and dimethyl ether in the cold interstellar gas has proved that the formation of organic matter in the Galaxy begins at a much earlier stage of star formation than was previously thought. This discovery represents a challenge for astrochemical modelers. The abundances of these molecules cannot be explained by the previously developed ''warm-up'' scenario, in which organic molecules are formed via diffusive chemistry on surfaces of interstellar grains starting at 30 K, and then released to the gas at higher temperatures during later stages of star formation. In this article, we investigate an alternative scenario in which complex organic species are formed via a sequence of gas-phase reactions between precursor species formed on grain surfaces and then ejected into the gas via efficient reactive desorption, a process in which non-thermal desorption occurs as a result of conversion of the exothermicity of chemical reactions into the ejection of products from the surface. The proposed scenario leads to reasonable if somewhat mixed results at temperatures as low as 10 K and may be considered as a step toward the explanation of abundances of terrestrial-like organic species observed during the earliest stages of star formation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Why Interstellar Ice Dust Grains Should Be Elongated

Models of interstellar dust alignment assume that dust grains are elongated, but none of these models explain why dust grains should be elongated. On the other hand, models of interstellar dust grain growth assume that dust grains are spherical and not elongated. We show that when dusty plasma effects and the dipole moment of water molecules are together taken into account, ice grains in interstellar space should be prolate ellipsoids and not spheres. Dusty plasma analysis shows that an ice grain is charged to a negative potential that has magnitude nearly equal to that of the electron temperature. Several different mechanisms causing deviation from sphericity are identified; these mechanisms involve the interaction of the dipole moment of water molecules with electric fields associated with ice grain charging. These mechanisms include the focusing of water molecule trajectories, the migration of water molecules in a quasi-liquid layer on the grain surface toward regions where the electric field is strongest, the enhancement of this migration by the bombardment of energetic protons that gain energy upon falling into the ice grain negative potential, and mutual repulsion by electric charges having the same sign. Furthermore, the aspect ratio is established shortly after the ice grain is formed, and then is maintained as the grain grows.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2017

Interstellar and Solar Nebula Materials in Cometary Dust

Laboratory studies of cometary dust collected in the stratosphere and returned from comet 81P/Wild 2 by the Stardust spacecraft have revealed ancient interstellar grains and molecular cloud organic matter that record a range of astrophysical processes and the first steps of planetary formation. Presolar materials are rarer meteorites owing to high temperature processing in the solar nebula and hydrothermal alteration on their asteroidal parent bodies. The greater preservation of presolar materials in comets is attributed to their low accretion temperatures and limited planetary processing. Yet, comets also contain a large complement of high temperature materials from the inner Solar System. Owing to the limited and biased sampling of comets to date, the proportions of interstellar and Solar System materials within them remains highly uncertain. Interstellar materials are identified by coordinated isotopic, mineralogical, and chemical measurements at the scale of individual grains. Chondritic porous interplanetary dust particles (CP IDPs) that likely derive from comets are made up of 0.1 - 10 micron-sized silicates, Fe-Ni-sulfides, oxides, and other phases bound by organic material. As much as 1% of the silicates are interstellar grains that have exotic isotopic compositions imparted by nucleosynthetic processes in their parent stars. Crystalline silicates in CP IDPs dominantly have normal isotopic compositions and probably formed in the Solar System. 81P samples include isotopically normal refractory minerals that resemble Ca-Al rich inclusions and chondrules common in meteorites. The origins of sub-micron amorphous silicates in IDPs are not certain, but at least a few % of them are interstellar grains. The remainder have isotopic compositions consistent with Solar System origins and elemental compositions that are inconsistent with interstellar grain properties, thus favoring formation in the solar nebula [4]. The organic component in comets and primitive meteorites has large enrichments in D/H and N-15/N-14 relative to terrestrial materials. These isotopic signatures are probably due to low temperature chemical processes in cold molecular clouds or the outermost reaches of the protoplanetary disk. The greatest isotopic anomalies are found in sub-micron organic nanoglobules that show chemical signatures of interstellar chemistry. The observation that cometary dust is mostly composed of isotopically normal minerals within isotopically anomalous organic matter is difficult to reconcile with the formation models of each component. The mineral component likely formed in high temperature processes in the inner Solar System, while the organic fraction shows isotopic and chemical signatures of formation near 10 K. Studying more primitive remnants of the Solar System starting materials would help in resolving this paradox. Comets formed across a vast expanse of the outer disk under differing thermal and collisional regimes, and some are likely to be better preserved than others. Finding truly pristine aggregates of presolar materials may require return of a pristine sample of comet nucleus material.

Messenger, Scott↗
DOE OSTI2016

THE 6 μ m FEATURE AS A TRACER OF ALIPHATIC COMPONENTS OF INTERSTELLAR CARBONACEOUS GRAINS

An unidentified infrared emission (UIE) feature at 6.0 μ m is detected in a number of astronomical sources showing the UIE bands. In contrast to the previous suggestion that this band is due to C=O vibrational modes, we suggest that the 6.0 μ m feature arises from olefinic double-bond functional groups. These groups are likely to be attached to aromatic rings, which are responsible for the major UIE bands. The possibility that the formation of these functional groups is related to the hydrogenation process is discussed.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1993

Main-sequence stars with circumstellar solid material - The Vega phenomenon

The detection of solid grains with temperatures of 50 to 125 K and fractional bolometric luminosities in the range 10 exp -5 to 10 exp -3 early in the IRAS mission around three nearby A main-sequence stars, Alpha Lyrae (Vega), Alpha Piscis Austrinus (Fomalhaut), and Beta Pictoris, is discussed. Spatial resolution of the emission indicates that: the grains are larger than interstellar grains, the material probably lies in disks in the stellar equatorial planes, the disks extend to distances of 100 to 1000 AU from the stars, and zones a few tens of AU in radius around the central stars are relatively empty. Subsequent surveys of IRAS data reveal more than 100 main-sequence stars of all spectral classes having unresolved excesses with similar temperatures and fractional luminosities to the three prototypes. Some stars with excesses have estimated ages of 1 to 5 Gyr. Thus, main-sequence FIR excesses appear to be widespread and are present in systems old enough to be probably past the stage of active planet formation.

Backman, Dana E.↗
NASA NTRS1993

Fingerprints of carbon, nitrogen, and silicon isotopes in small interstellar SiC grains from the Murchison meteorite

We report ion microprobe determinations of the carbon, nitrogen, and silicon isotopic compositions of small SiC grains from the Murchison CM2 chondrite. Analyses were made on samples containing variable numbers of grains and on 14 individual grains. In some cases the multiple-grain sample compositions were probably dominated by only one or two grains. Total ranges observed are given. Only a few grains show values near the range limits. Both the total ranges of carbon and nitrogen isotopic compositions, and even the narrower ranges typical for the majority of the grains, are similar to those observed for larger SiC grains. Two rare components appear to be present in the smaller-size fraction, one characterized by C-12/C-13 about 12-16 and the other by very heavy nitrogen. The carbon and nitrogen isotopic compositions qualitatively may reflect hydrostatic H-burning via the CNO cycle and He-burning in red giants, as well as explosive H-burning in novae. The silicon isotopic compositions of most grains qualitatively show what is the signature of He-burning. The silicon isotopic composition of one grain, however, suggests a different process.

Hoppe, Peter↗
NASA NTRS1979

Ultraviolet observations of interstellar molecules and grains from Spacelab

The paper presents observational results obtained on interstellar grains and molecules and suggests promising areas for Spacelab research. Regarding grains, useful data can be expected on the shape of the ultraviolet extinction curve for new interstellar regions, on the nature of UV extinction at short wavelengths, the presence of structure in the UV extinction curve comparable to the visible-wavelength diffuse bands, and the polarization properties of grains in UV wavelengths. The advances in observations of molecules will include the ability to prove more heavily-obscured regions, coverage of wavelength regions inadequately studied with previous instruments, and the capability of observing in optical absorption species detected in the same line of sight in radio emission.

Snow, T. P., Jr.↗
NASA NTRS1974

Evolutionary characteristics of a bimodal grain model

A bimodal model of interstellar grains consisting of silicate cores of size approximately 0.06 micron with modified ice mantles of approximately 0.1 micron and very small particles of silicate and/or graphite of size approximately 0.005 micron is followed through various stages of evolution. Starting with a distribution of core-mantle cylinders producing average wavelength dependence of polarization and extinction, changes in physical and optical characteristics of the model are studied going first into regions of dense cloud condensation and coming out at the other end of star formation into young H2 regions. Physical justification is presented to show that not only in dense clouds must the core mantle grains be larger than normal, but also in young H2 regions.

Greenberg, J. M.↗
NASA NTRS1994

Formation of iron metal and grain coagulation in the solar nebula

The interstellar grain population in the giant molecular cloud from which the sun formed contained little or no iron metal. However, thermal processing of individual interstellar silicates in the solar nebula is likely to result in the formation of a population of very small iron metal grains. If such grains are exposed to even transient magnetic fields, each will become a tiny dipole magnet capable of interacting with other such dipoles over spatial scale orders of magnitude larger than the radii of individual grains. Such interactions will greatly increase the coagulation cross-section for this grain population. Furthermore, the magnetic attraction between two iron dipoles will significantly increase both the collisional sticking coefficient and the strength of the interparticle binding energy for iron aggregates. Formation of iron metal may therefore be a key step in the aggregation of planetesimals in a protoplanetary nebula. Such aggregates may have already been observed in protoplanetary systems. The enhancement in the effective interaction distance between two magnetic dipoles is directly proportional to the strength of the magnetic dipoles and inversely proportional to the relative velocity. It is less sensitive to the reduced mass of the interacting particles (alpha M(exp -1/2)) and almost insensitive to the initial number density of magnetic dipoles (alpha n(sub o)(exp 1/6)). We are in the process of measuring the degree of coagulation in our condensation flow apparatus as a function of applied magnetic field and correlating these results by means of magnetic remanance acquisition measurements on our iron grains with the strength of the magnetic field to which the grains are exposed. Results of our magnetic remanance acquisition measurements and the magnetic-induced coagulation study will be presented as well as an estimate of the importance of such processes near the nebular midplane.

Nuth, Joseph A., III↗