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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1981

Ultraviolet emission of the Vela supernova remnant and the Cygnus Loop

Ultraviolet emission spectra of several filaments in the Vela supernova remnant and the Cygnus Loop are compared with theoretical models of radiative shocks. Shock velocities range from 85 to 130 km/s. Little or no grain depletion is apparent. Several of the observed filaments deviate from the steady-flow models in the sense that much of the photoionization-recombination zone is absent. It is shown that resonance line scattering within the emitting region can account for the weakness of the C II 1335 and C IV 1550 lines. Evaporation fronts, which are basic to the McKee and Ostriker picture of supernova remnant evolution, do not contribute significantly to the observed emission. Some discrepancies in UV emission predicted by different sets of shock models are traced to differing atomic rates used in the calculations. A fluorescent emission line of H2 may be observable in some supernova remnants.

Raymond, J. C.↗

NASA NTRS1990

Far-infrared spectroscopy of NGC 6946, IC 342, and Arp 299

Researchers investigated the physical conditions in the infrared bright galaxies NGC 6946, IC 342, and Arp 299 through measurements of far-infrared emission lines from Si II, O I, C II, and O III using the facility Cooled Grating Spectrometer on the Kuiper Airborne Observatory. These data are interpreted using our theoretical models for photodissociation regions and H II regions. For the central 45 inches of these galaxies, researchers determined that the dominant excitation mechanism for the far infrared radiation (FIR) lines is far ultraviolet radiation (FUR) radiation from young stars, and the authors derived the total mass, density, and temperature of the warm atomic gas and the typical sizes, number densities, and filling factors for the interstellar clouds.

Lord, Steven D.↗

NASA NTRS1959

Interactions Between Oxygen and Nitrogen: O[Single Bond]N, O[Single Bond]N (sub 2), and O (sub 2)[Single Bond]N (sub 2)

Potential energy curves for 0-N interactions corresponding to the X (sup 2) II (sub t/2), X (sup 2) II (sub 3/2), A (sup 2) Eta (sup plus), B (sup 2) II, C (sup 2) II, D (sup 2) Eta (sup plus), E (sup 2) Eta (sup plus), and B prime (sup 2 delta) states of nitric oxide have been calculated from spectroscopic data by the Rydberg- Klein-Rees method. Curves for the (sup 4) II, (sup 2) Eta, (sup 4) Eta, (sup 6) Eta, and (sup 6) II states have been obtained from limited spectroscopic results and from relations derived from approximate quantum-mechanical calculations. Two semi-independent calculations have been made, and are in good agreement with each other. The quantum-mechanical relations also lead to approximate curves for the O[Single Bond]N, and O[Single Bond]N (sub 2) interactions over a limited range. The O (sub 2)[Single Bond]N (sub 2) interaction is consistent with one valid at larger separation distances which has been derived from high-temperature gas viscosity data.

Vanderslice, Joseph T.↗

NASA NTRS1982

The carbon abundance in the Magellanic Clouds from IUE observations of H II regions

Results are given of observations of the UV spectra of several H II regions in the Magellanic Clouds, with emphasis on obtaining the carbon abundance from the UV lines of C II, C III, and C IV. The observations and results are described, and theoretical model calculations are presented of the H II regions and the relative abundances of H, He, C, N, O, S, Cl, and Ar computed from the UV and visual spectra. In addition, the abundance results for the Magellanic Clouds are compared with the sun, the Orion Nebula, and galactic planetary nebulae. In comparison with solar abundances, carbon is found to be depleted relative to hydrogen in the Magellanic Clouds by an amount larger than that of nitrogen and oxygen in the SMC and by an amount between that of nitrogen and oxygen in the LMC. It is noted that the results are consistent with a scenario that nitrogen and oxygen have greater primary yields in massive stars than carbon, which may be produced predominantly in less massive stars (such that C/N and C/O in galaxies are initially very low and subsequently increase with evolution). Subsequently, the C/N ratio may decrease as secondary production of nitrogen in less massive stars becomes significant.

Dufour, R. J.↗

NASA NTRS1991

Emission lines in the long period Cepheid l Carinae

For the Cepheid (l) Carinae with a pulsation period of 35.5 days we have studied the emission line fluxes as a function of pulsational phase in order to find out whether we see chromosphere and transition layer emission or whether we see emission due to an outward moving shock. All emission lines show a steep increase in flux shortly before maximum light suggestive of a shock moving through the surface layers. The large ratio of the C IV to C II line fluxes shows that these are not transition layer lines. During maximum light the large ratio of the C IV to C II line fluxes also suggests that we see emission from a shock with velocities greater than 100 km/sec such that C IV emission can be excited. With such velocities mass outflow appears possible. The variations seen in the Mg II line profiles show that there is an internal absorption over a broad velocity band independent of the pulsational phase. We attribute this absorption to a circumstellar 'shell'. This 'shell' appears to be seen also as spatially extended emission in the O I line at 1300 angstrom, which is probably excited by resonance with Ly beta.

Boehm-Vitense, Erika↗

NASA NTRS1994

Emission lines in the long-period Cepheid l Carinae

For the Cepheid l Carinae, with a pulsation period of 35.5 days, we have studied the emission-line fluxes as a function of pulsational phase in order to find out whether we see chromospheric and transition-layer emission due to an outward-moving shock. All emission lines show a steep increase in flux shortly before maximum light, suggestive of a shock moving through the surface layers. The large ratio of C IV to C II line fluxes shows that these are not transition-layer lines. During maximum light the large ratio of the large ratio of the C IV to C II line fluxes also suggests that we see emission from a shock with velocities greater than 100 km/s such that C IV emission can be excited. With such velocities mass outflow appears possible. The variations seen in the MG II line profiles show that there is an external absorption over a broad velocity band independent of the pulsation phase. We attribute this absorption to a circumstellar 'shell.' This 'shell' appears to be seen also as spatially extended emission in the O I line at 1300 A, which is probably excited by resonance with Ly beta.

Bohm-Vitense, Erika↗

NASA NTRS1991

Probing the Galactic halo along the 3C 273 sight line using IUE

High-resolution spectra of the QSO 3C 273 were obtained in 1989 and added to two spectra recorded in 1982. The coadded spectra represent 600,000 s of integration at a resolution of 30 km/s from 1200 to 2000 A. The line of sight passes through the Virgo Cluster the entire halo of the Milky Way, at Galactic latitude b = 64 deg, and foreground X-ray-emitting material from local disturbed gas. The observed equivalent width of Galactic C IV is greater than the equivalent width of C II, a situation that is uncommon in local gas but is often found in QSO absorption line systems. The lines of C IV, Al III, and Si IV may arise in an extended halo or may be associated with local disturbed gas in a radio loop. The remaining detected species (H I, C II, Si II) arise predominately from the local gas. Most of the gas is probably within 5 kpc, but no firm conclusion is reached. Possible detection of interstellar absorption due to the Virgo Cluster is discussed.

Burks, Geoffrey S.↗

NASA NTRS1984

Far-infrared Spectroscopy of Galaxies: the 158 Micron C(+) Line

The C II 158 micron fine structure line in six gas rich galaxies was investigated. These data are combined with other measurements of the C II line (in various galactic sources) and are compared to studies of the CO J = approaches O rotational line at 2.6 mm, the H I 21 cm line, and the far infrared continuum emission in the same objects.

Crawford, M. K.↗

DOE OSTI2021

Solvated Nickel Complexes as Stoichiometric and Catalytic Perfluoroalkylation Agents**

Abstract The acetonitrile‐solvated [(MeCN)Ni(C 2 F 5 ) 3 ] − was prepared in order to compare and contrast its reactivity with the known [(MeCN)Ni(CF 3 ) 3 ] − towards organic electrophiles. Both [(MeCN)Ni(CF 3 ) 3 ] − and [(MeCN)Ni(C 2 F 5 ) 3 ] − successfully react with aryl iodonium and diazonium salts as well as alkynyl iodonium salts to give fluoroalkylated organic products. Electrochemical analysis of [(MeCN)Ni II (C 2 F 5 ) 3 ] − suggests that, upon electro‐oxidation to [(MeCN) n Ni III (C 2 F 5 ) 3 ], reductive homolysis of a perfluoroethyl radical occurs, with the concomitant formation of [(MeCN) 2 Ni II (C 2 F 5 ) 2 ]. Catalytic C−H trifluoromethylations of electron‐rich arenes were successfully achieved using either [(MeCN)Ni(CF 3 ) 3 ] − or the related [Ni(CF 3 ) 4 ] 2− . Stoichiometric reactions of the solvated nickel complexes reveal that “ligandless” nickel is exceptionally capable of serving as reservoir of CF 3 groups under catalytically relevant conditions.

Shreiber, Scott T.↗

DOE OSTI2021

Solvated Nickel Complexes as Stoichiometric and Catalytic Perfluoroalkylation Agents**

The acetonitrile-solvated [(MeCN)Ni(C 2 F 5 ) 3 ] - was prepared in order to compare and contrast its reactivity with the known [(MeCN)Ni(CF 3 ) 3 ] - towards organic electrophiles. Both [(MeCN)Ni(CF 3 ) 3 ] - and [(MeCN)Ni(C 2 F 5 ) 3 ] - successfully react with aryl iodonium and diazonium salts as well as alkynyl iodonium salts to give fluoroalkylated organic products. Electrochemical analysis of [(MeCN)Ni II (C 2 F 5 ) 3 ] - suggests that, upon electro-oxidation to [(MeCN) n Ni III (C 2 F 5 ) 3 ], reductive homolysis of a perfluoroethyl radical occurs, with the concomitant formation of [(MeCN) 2 Ni II (C 2 F 5 ) 2 ]. Catalytic C-H trifluoromethylations of electron-rich arenes were successfully achieved using either [(MeCN)Ni(CF 3 ) 3 ] - or the related [Ni(CF 3 ) 4 ] 2- . Stoichiometric reactions of the solvated nickel complexes reveal that “ligandless” nickel is exceptionally capable of serving as reservoir of CF 3 groups under catalytically relevant conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1994

The abundant elements in interstellar dust

We explore the incorporation of the cosmically abundant species O, C, N, Mg, Si, Fe, and S into interstellar dust. Column densities based on Goddard High Resolution Spectrograph 3.5 km/s resolution measurements from the literature for eight individual absorbing regions toward five lines of sight are used. Corrections are applied as needed in order to account for recent improvements in oscillator strengths. In order to acquire the most accurate column densities, and check on the accuracy of the oscillator strengths, we compare column densities based on the very strong Lorentzian damped lines of C II, O I, N I, and Mg II with results for the weak lines of these species, and confirm the previously determined f-values for O I lambda 1335, C II lambda 2325, and N I lambda lambda 1159, 1160. New empirical f-values of 1.25 x 10(exp -3) and 6.25 x 10(exp -4), respectively, are derived for the Mg II weak doublet at 1239 and 1240 A. Assuming a cosmic reference abundance based on solar and B star values, we derive depletions and dust-phase abundances which suggest that more than 70% of the available Mg and Fe is incorporated into dust-grain cores, whereas only 35% of the silicon is. This implies that oxides are important constituents of the grain core population. Mg and Fe atoms are mantled onto grain cores in a ratio of 1.8 to 1, whereas approximately 4.0 Si atoms are in the mantle per Fe atom. Since Si is not expected to accrete onto silicate or graphite grains, other grain cores, perhaps oxides and/or metallic Fe, may provide mantling sites for this species. The abundances of Fe and Mg in mantles would imply that graphite grains must have a substantial coating unless oxides provide significant mantling sites for these species. The abundance of O and N in the dust phase as implied by the solar reference abundance values are difficult to reconcile with the fact that these elements are not expected to participate in mantle formation, and the 3.1 micrometer H2O ice feature is not seen in absorption toward stars similar to those studied. The B star reference abundances for O and N, however, imply that no mantling of these species has occurred. The dust-phase abundance for C implied by solar reference abundances agrees with predictions for the number of graphite grains needed to produce the 2175 A bump. B star reference abundances, however, suggest that the abundance of C in the dust phase is not always sufficient to produce the bump.

Sofia, Ulysses J.↗

NASA NTRS1982

Evolution of chromospheres and coronae in solar mass stars - A far-ultraviolet and soft X-ray comparison of Arcturus /K2 III/ and Alpha Centauri A /G2 V/

IUE far-UV and Einstein Observatory soft X-ray observations for the red giant Arcturus and the nearby yellow dwarf Alpha-Centauri A, which are archetypes of solar mass stars in different stages of evolution, are compared. Evidence is found for neither coronal soft X-ray emission from the red giant, at surface flux levels of only 0.0006 that detected previously for the yellow dwarf, nor C II and IV resonance line emission at surface flux levels of only 0.02 those of the yellow dwarf. The resonance line upper limits and previous detections of the C II intersystem UV multiplet 0.01 near 2325 A provide evidence for an Arcturus outer atmosphere that is geometrically extended, tenuous and cool. The red giant has, in addition, a prominent cool stellar wind. An extensive tabulation of line identifications, widths and fluxes for the IUE far-UV echelle spectra of the two stars is given, and two competing explanations for the Wilson-Bappu effect are discussed.

Ayres, T. R.↗

NASA NTRS1994

Photon-dominated regions around cool stars: The effects of the color temperature of the radiation field

We have investigated the influence of the color temperature of the illuminating radiation field on the chemical and thermal structure of photon-dominated regions (PDRs). We present the results of a study of the photoelectric efficiency of heating by large molecules such as polycyclic aromatic hydrocarbons (PAHs) and very small grains for radiation fields characterized by different effective temperatures. We show that the efficiency for cooler (T(sub eff) approximately = 6000-10,000 K) stars is at most an order of magnitude smaller than that for hotter (T(sub eff) approximately = 20,000-30,000 K) stars. While cooler radiation fields result in less ultraviolet photons capable of heating, the efficiency per absorbed photon is higher, because the grains become less positively charged. We also present detailed calculations of the chemistry and thermal balance for generic PDRs (n(sub 0) approximately = 10(exp 3), G(sub 0) approximately = 10(exp 3)). For cooler radiation fields, the H/H2 and C(+)/C/CO transition layers shift toward the surface of the PDR, because fewer photons are available to photodissociate H2 and CO and to ionize C. The dominant cooling lines are the (C II) 158 micron and the (O I) 63 micron lines for the hotter radiation fields, but cooling by CO becomes dominant for a color temperature of 6000 K or lower. The (C II)/CO and (O I)/CO ratios are found to be very good diagnostics for the color temperature of the radiation field.

Spaans, Marco↗

NASA NTRS1991

Preliminary spectral observations of the Galaxy with a 7 deg beam by the Cosmic Background Explorer (COBE)

The FIR absolute spectrophotometer (FIRAS) on the Cosmic Background Explorer (COBE) has carried out the first all-sky spectral line survey in the FIR region, as well as mapping spectra of the Galactic dust distribution at below 100 microns. Lines of forbidden C I, C II, and N II, as well as of CO are all clearly detected. The mean line intensities are interpreted in terms of the heating and cooling of the multiple phases of the interstellar gas. In addition, an average spectrum of the galaxy is constructed and searched for weak lines. The spectrum of the galaxy observed by FIRAS has two major components: a continuous spectrum due to interstellar dust heated by starlight, and a line spectrum dominated by the strong 158-micron line from singly ionized carbon, with a spatial distribution similar to the dust distribution, and a luminosity of 0.3 percent of the dust luminosity. There are in addition moderately strong 122- and 205.3-micron lines, identified as coming from singly-ionized nitrogen. Maps of the emission by dust and forbidden C II and N II are presented.

Wright, E. L.↗

NASA NTRS1989

Far infrared, submm and mm spectroscopy of the galactic center: Radio arc and +20/+50 km s (exp -1) clouds

The observations of the par improved spectroscopy and the molecular clouds at the galactic center are reported. The results show: the spatial distributions of C(II) 158 microns and molecular line radiation and of the thermal radio continuum emission in the arched filaments of the radio arc are similar; about 2 x 10(exp 4) of the solar mass, or 10 percent of the total gas mass in the radio arc, are contained in C(+) regions; the H(+)/C(+) regions are probably located at the surfaces of the dense molecular clouds in the arc. Profiles, fluxes and spatial distributions of the C(II) fine structure and CO rotational lines are reported. It is demonstrated that the data does not fit models in which the neutral interstellar clouds in the arc are ionized by shocks or by magnetohydrodynamic phenomena. Moreover, that the high temperatures and densities derived previously from NH3 and CS observations may not be characteristic of the bulk of the molecular gas.

Genzel, R.↗

NASA NTRS2012

GASPS Observations of Herbig Ae/Be Stars with PACS/Herschel: The Atomic and Molecular Content of Their Protoplanetary Discs

We observed a sample of 20 representative Herbig Ae/Be stars and five A-type debris discs with PACS onboard of Herschel. The observations were done in spectroscopic mode, and cover far-IR lines of [O I], [C II], CO, CH+, H2O and OH. We have a [O I] 63 micron detection rate of 100% for the Herbig Ae/Be and 0% for the debris discs. [O I] 145 micron is only detected in 25 %, CO J=18-17 in 45 % (and less for higher J transitions) of the Herbig Ae/Be stars and for [C II] 157 micron, we often found spatially variable background contamination. We show the first detection of water in a Herbig Ae disc, HD 163296, which has a settled disc. Hydroxyl is detected as well in this disc. CH+, first seen in HD 100546, is now detected for the second time in a Herbig Ae star, HD 97048. We report fluxes for each line and use the observations as line diagnostics of the gas properties. Furthermore, we look for correlations between the strength of the emission lines and stellar or disc parameters, such as stellar luminosity, UV and X-ray flux, accretion rate, PAH band strength, and flaring. We find that the stellar UV flux is the dominant excitation mechanism of [O I] 63, with the highest line fluxes found in those objects with a large amount of flaring and greatest PAH strength. Neither the amount of accretion nor the X-ray luminosity has an influence on the line strength. We find correlations between the line flux of [O I] 63 and [O I] 145, CO J = 18-17 and [O I] 6300 A, and between the continuum flux at 63 micron and at 1.3 mm, while we find weak correlations between the line flux of [O I] 63 and the PAH luminosity, the line flux of CO J = 3-2, the continuum flux at 63 micron, the stellar effective temperature and the Br(gamma) luminosity. Finally, we use a combination of the [O I] 63 and CO-12 J = 2-1 line fluxes to obtain order of magnitude estimates of the disc gas masses, in agreement of the values we found from detailed modelling of 2 HAEBEs, HD 163296 and HD 169142.

G Meeus↗

NASA NTRS1993

A joint program with Japanese investigators to map carbon 2 line emission from the galaxy

A large portion of the inner galactic plane has been mapped in the far-infrared (C II) line using a balloon-borne survey instrument. Complete coverage is reported from 25 degrees north to 80 degrees south of the galactic center and extending a few degrees on each side of the plane. Effective resolution is 14.1 acrmin (FWHM) and contour levels begin at 2 E -5 ergs/(s x sq. cm x ster). When compared with 100 micron dust emission observed by IRAS the (C II) appears well correlated with the dust emission except for a 10 degree region centered on the galactic center where emission from the gas is much weaker than that from the dust.

Low, Frank J.↗

NASA NTRS1975

A study of interstellar lines in the rocket spectrum of delta Scorpii

Ten interstellar lines in the vacuum UV spectrum of delta Sco are analyzed which were recorded on rocket spectrograms. Two cloud components are resolved which have Doppler widths of 1.55 km/sec (larger cloud) and 2.16 km/sec (smaller cloud). Column densities are derived for C I, C II, N I, O I, Al II, Si II, and Fe II, and abundances relative to atomic hydrogen are determined from them. Silicon and iron are found to be slightly overabundant relative to the solar abundances, while the other elements are underabundant by factors ranging from 1.8 to 8.6. Mean cloud densities of 250 and 150 per cu cm (for the larger and smaller clouds, respectively) are determined, and the average ratios of electron density to hydrogen-atom density are derived using the column densities of C I and C II. It is shown that the iron abundance can be decreased to less than the solar abundance by doubling the velocity dispersion of the iron ions.

Smith, A. M.↗