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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Ultralean combustion in general aviation piston engines

The role of ultralean combustion in achieving fuel economy in general aviation piston engines was investigated. The aircraft internal combustion engine was reviewed with regard to general aviation requirements, engine thermodynamics and systems. Factors affecting fuel economy such as those connected with an ideal leanout to near the gasoline lean flammability limit (ultralean operation) were analyzed. A Lycoming T10-541E engine was tested in that program (both in the test cell and in flight). Test results indicate that hydrogen addition is not necessary to operate the engine ultralean. A 17 percent improvement in fuel economy was demonstrated in flight with the Beechcraft Duke B60 by simply leaning the engine at constant cruiser power and adjusting the ignition for best timing. No detonation was encountered, and a 25,000 ft ceiling was available. Engine roughness was shown to be the limiting factor in the leanout.

Chirivella, J. E.↗
NASA NTRS2012

Development of Modeling Capabilities for Launch Pad Acoustics and Ignition Transient Environment Prediction

This paper presents development efforts to establish modeling capabilities for launch vehicle liftoff acoustics and ignition transient environment predictions. Peak acoustic loads experienced by the launch vehicle occur during liftoff with strong interaction between the vehicle and the launch facility. Acoustic prediction engineering tools based on empirical models are of limited value in efforts to proactively design and optimize launch vehicles and launch facility configurations for liftoff acoustics. Modeling approaches are needed that capture the important details of the plume flow environment including the ignition transient, identify the noise generation sources, and allow assessment of the effects of launch pad geometric details and acoustic mitigation measures such as water injection. This paper presents a status of the CFD tools developed by the MSFC Fluid Dynamics Branch featuring advanced multi-physics modeling capabilities developed towards this goal. Validation and application examples are presented along with an overview of application in the prediction of liftoff environments and the design of targeted mitigation measures such as launch pad configuration and sound suppression water placement.

West, Jeff↗
DOE OSTI2024

Systematic characterization of selenium speciation in coal fly ash

Millions of tons of coal fly ashes (CFAs) are produced annually during coal combustion in the U.S., which are commonly beneficially used in the concrete industry or disposed of in ash ponds. CFAs contain trace amounts of a range of toxic heavy metals including selenium (Se). Because the toxicity of Se is dependent on its speciation, investigating Se speciation in CFAs as affected by coal source and combustion conditions can help understand the related environmental and human health impacts during disposal or beneficial reuse. In this study, a set of representative CFA samples were characterized for Se speciation using synchrotron X-ray absorption spectroscopy (XAS) and micro-X-ray fluorescence spectromicroscopy (μ-XRF/XAS). Se-containing particles were highly heterogeneous, and individual particles might contain multiple oxidation states including Se(0), Se(IV), and Se(VI). Principal component analysis was performed for sample characteristics including Al 2 O 3 , SiO 2 , CaO, FeO, loss on ignition, average particle size, Se concentration, and Se oxidation state. Selective catalytic reduction (SCR), which is used to limit nitrogen oxide (NO x ) emissions during coal combustion, was found to be associated with the presence of reduced Se oxidation states, with up to 90% Se(0) observed in samples with SCR. Alongside SCR, FeO content may also influence Se speciation.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1974

Apollo 16 mission report. Supplement 2: Service Propulsion system final flight evaluation

The Apollo 16 Mission was the sixteenth in a series of flights using Apollo flight hardware and included the fifth lunar landing of the Apollo Program. The Apollo 16 Mission utilized CSM 113 which was equipped with SPS Engine S/N 66 (Injector S/N 137). The engine configuration and expected performance characteristics are presented. Since previous flight results of the SPS have consistently shown the existence of a negative mixture ratio shift, SPS Engine S/N 66 was reorificed to increase the mixture ratio for this mission. The propellant unbalance for the two major engine firings is compared with the predicted unbalance. Although the unbalance at the end of the TEI burn is significantly different than the predicted unbalance, the propellant mixture ratio was well within limits. The SPS performed six burns during the mission, with a total burn duration of 575.3 seconds. The ignition time, burn duration and velocity gain for each of the six SPS burns are reported.

Smith, R. J.↗
NASA NTRS1996

Chemical Characterization and Reactivity Testing of Fuel-Oxidizer Reaction Product (Test Report)

The product of incomplete reaction of monomethylhydrazine (MMH) and nitrogen tetroxide (NTO) propellants, or fuel-oxidizer reaction product (FORP), has been hypothesized as a contributory cause of an anomaly which occurred in the chamber pressure (PC) transducer tube on the Reaction Control Subsystem (RCS) aft thruster 467 on flight STS-51. A small hole was found in the titanium-alloy PC tube at the first bend below the pressure transducer. It was surmised that the hole may have been caused by heat and pressure resulting from ignition of FORP. The NASA Johnson Space Center (JSC) White Sands Test Facility (WSTF) was requested to define the chemical characteristics of FORP, characterize its reactivity, and simulate the events in a controlled environment which may have lead to the Pc-tube failure. Samples of FORP were obtained from the gas-phase reaction of MMH with NTO under laboratory conditions, the pulsed firings of RCS thrusters with modified PC tubes using varied oxidizer or fuel lead times, and the nominal RCS thruster firings at WSTF and Kaiser-Marquardt. Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), ion chromatography (IC), inductively coupled plasma (ICP) spectrometry, thermogravimetric analysis (TGA) coupled to FTIR (TGA/FTIR), and mechanical impact testing were used to qualitatively and quantitatively characterize the chemical, thermal, and ignition properties of FORP. These studies showed that the composition of FORP is variable but falls within a limited range of compositions that depends on the fuel loxidizer ratio at the time of formation, composition of the post-formation atmosphere (reducing or oxidizing), and reaction or postreaction temperature. A typical composition contains methylhydrazinium nitrate (MMHN), ammonium nitrate (AN), methylammonium nitrate (MAN), and trace amounts of hydrazinium nitrate and 1,1-dimethylhydrazinium nitrate. The thermal decomposition reactions of FORP compositions used in this study were unremarkable, Neither the various compositions of FORP, the pure major components of FORP, nor mixtures of FORP with propellant-system corrosion products showed any unusual thermal activity when decomposed under laboratory conditions. Off-limit thruster operations were simulated by rapid mixing of liquid MMH and liquid NTO in a confined space. The test hardware was constructed with pressure- and temperature-measurement devices to determine if the expected fuel oxidizer reaction would result in increased energy release when FORP, FORP constituents, or propellant-system corrosion products were present. These tests demonstrated that FORP, MMHN, AN, or Inconel corrosion products can induce a mixture of MMH and NTO to produce component-damaging energies. The simulation-test program was not extensive enough to provide statistical probabilities for these events but did show that such events can occur. Damaging events required FORP or metal salts to be present at the initial mixing of MMH and NTO. Based on the results of these studies, it is suggested that removal or mitigation of a buildup of these materials may decrease the incidence of these high-energy, potentially damaging events.

Source record↗
NASA NTRSDate not supplied

Lunar Landing and Launch Pad Construction – Concepts and Criteria

When a lander vehicle launches or lands on the Moon, the rocket engine exhaust plume impinges on the surface and interacts with the regolith to create blast ejecta and associated cratering of the surface. Lunar regolith blast ejecta travels at high velocities (>2,000 m/s) for long distances (kilometers) in a vacuum environment [1] creating hazards for surrounding assets and it can also impact the bottom of the lander vehicle, risking damage to the engines, thermal insulation and sensors. Ballistic particles can possibly enter cislunar space and achieve orbit as debris, if the ejecta is sufficiently energetic. The cratering and regolith erosion can endanger the vehicle itself by affecting the soil stability under the landing gear. Landing on unpredictable terrain with varying topography, natural craters and rock hazards is also hazardous risks tipping a lander at dangerous angles in extreme conditions that may also violate maximum slope angles for subsequent launch operations. During launch (Figure 1), an overpressure pulse created by the ignition of the rocket engines can pose significant ejecta risks to the vehicle. Dust clouds raised during landing limit the efficacy of sensors and reduce visibility for the astronaut pilots, creating significant real-time risk during landing site selection by the pilot or computer navigation system. Future lunar spaceports will require mitigations to these launch and landing risks [2]. There are four main objectives of this effort:1) To establish the state of the art in LLP construction methodologies. 2) To propose criteria for trade studies of LLP concepts. 3) To publicly share the authors’ ideas for potential LLP solutions. 4) To serve as the starting point for future development of LLP technologies. Establishing the state of the art in the area of off-Earth Launch & Landing Pad concepts will base-line the work that has been completed thus far and highlight the wide span between current Technology Readiness Levels (TRLs)and operational readiness. The authors aim to communicate the need for funding in this area in the near term by illustrating that there is much work to be completed before a truly viable option exists. Setting forth criteria for trade studies of LLP concepts is important for several reasons. The first and most straightforward is to establish a framework for performing trade studies on LLP concepts. This will enable NASA to select the most promising concepts for continued development, and it will also help technology developers understand how their concepts compare with others and the priorities of development effort.

landing pad↗
NASA NTRS1946

Effect of Fuel Composition, Engine Operating Variables, and Spark-Plug Type and Condition on Preignition-Limited Performance of an R-2800 Cylinder

The preignition characteristics of the R-2800 cylinder, as effected by fuel consumption, engine operating variables, and spark plug type and condition, were evaluated. The effects on preignition-limited performance of various percentages of aromatics (benzene, toluene, cumene, xylene) in a base fuel of triptane were investigated. Two paraffins (triptane and S + 6.0 ml TEL/gal) and two refinery blends (28-R and 33-R) were preignition rated. The effect of changes in the following engine operating variables on preignition limit was determined: inlet-air temperature, rear spark plug gasket temperature, engine speed, spark advance, tappet clearance, and oil consumption. Preignition limits of the R-2800 cylinder using Champion C34S and C35S and AC-LS86, LS87, and LS88 spark plugs were established and the effect of spark plug deterioration was investigated. No definite trends in preignition-limited indicated mean effective pressure were indicated for aromatics as a class when increased percentages of different aromatics were added to a base fuel of triptane. Three types of fuel (aromatics, paraffins, and refinery blends) showed a preignition range for this cylinder from 65 to 104 percent when based on the performance of S plus 6.0 ml TEL per gallon as 100 percent. The R-2800 cylinder is therefore relatively insensitive to fuel composition when compared to a CFR F-4 engine, which had a pre-ignition range from 72 to 100 percent for the same fuels. Six engine operating variables were investigated with the following results: preignition-limited indicated mean effective pressure decreased, with increases in engine speed, rear spark plug gasket temperature, inlet-air temperature, and spark advance beyond 20 F B.T.C. and was unaffected by rate of oil consumption or by tappet clearance. Spark plugs were rated over a range of preignition-limited indicated mean effective pressure from 200 to 390 pounds per square inch at a fuel-air ratio of 0.07 in the following order of increased resistance to preignition: AC-LS97, AC-LS88, Champion C358, AC-LS86, and Champion C34S. Spark plug deterioration in the form of cracks in the porcelain had been broken away from the center electrode and were retained in the spark plug cavity, the preignition limit was decreased as much as 57 percent. When the broken pieces had been removed, the preignition limit increased from that of the undamaged porcelain as the weight of removed porcelain was increased.

Pfender, John F.↗
NASA NTRS1996

Propulsion Selection for 85kft Remotely Piloted Atmospheric Science Aircraft

This paper describes how a 3 stage turbocharged gasoline engine was selected to power NASA's atmospheric science unmanned aircraft now under development. The airplane, whose purpose is to fly sampling instruments through targeted regions of the upper atmosphere at the exact location and time (season, time of day) where the most interesting chemistry is taking place, must have a round trip range exceeding 1000 km, carry a payload of about 500 lb to altitudes exceeding 80 kft over the site, and be able to remain above that altitude for at least 30 minutes before returning to base. This is a subsonic aircraft (the aerodynamic heating and shock associated with supersonic flight could easily destroy the chemical species that are being sampled) and it must be constructed so it will operate out of small airfields at primitive remote sites worldwide, under varying climate and weather conditions. Finally it must be low cost, since less than $50 M is available for its development. These requirements put severe constraints on the aircraft design (for example, wing loading in the vicinity of 10 psf) and have in turn limited the propulsion choices to already-existing hardware, or limited adaptations of existing hardware. The only candidate that could emerge under these circumstances was a propeller driven aircraft powered by spark ignited (SI) gasoline engines, whose intake pressurization is accomplished by multiple stages of turbo-charging and intercooling. Fortunately the turbocharged SI powerplant, owing to its rich automotive heritage and earlier intensive aero powerplant development during WWII, enjoys in addition to its potentially low development costs some subtle physical advantages (arising from its near-stochiometric combustion) that may make it smaller and lighter than either a turbine engine or a diesel for these altitudes. Just as fortunately, the NASA/industry team developing this aircraft includes the same people who built multi-stage turbocharged SI powerplants for unmanned military spyplanes in the early 1980's. Now adapting hardware developed for reconaissance at 65-70 kft to the interests of atmospheric science at 80-90 kft, their efforts should yield an aero powerplant that pushes the altitude limits of subsonic air breathing propulsion.

Bents, David J.↗
DOE OSTI2025

Modeling the Nucleation and Growth of Lead Sulfate Particles on Lead Electrodes

Lead-acid batteries (LABs) play a pivotal role in the energy storage sector with applications spanning from starting-lighting-ignition batteries to grid energy storage. Passivation of lead negative electrodes by PbSO 4 particles is a fundamental mechanism limiting the performance of LAB. In this regard, an electrochemical model is developed that simulates the nucleation and growth (N&G) dynamics of PbSO 4 particles on a flat lead electrode, responsible for its passivation. The model considers the electrochemical reactions between lead electrode and sulfuric acid, N&G of PbSO 4 particles, passivation of the lead surface, and the ternary transport of PbSO 4 (aq), bisulfate, and protons in H 2 SO 4 electrolyte. The model is validated with a dataset of cyclic voltammetry (CV) responses collected at several scan rates and H 2 SO 4 concentrations. The model shows remarkable qualitative and quantitative agreement with the experimental data including CV peak features, discharge capacity, and particle size. The model was employed to explore key N&G quantities, such as supersaturation, nucleation rate, particle count, growth rate, particle size, and surface coverage, and to examine how their interactions influence electrode utilization. Parametric studies were also conducted to evaluate how scan rates and acid concentrations influence the previously mentioned N&G quantities and, subsequently, the utilization of the electrode.

25 ENERGY STORAGE↗
NASA NTRS1973

Solid propellant rocket motor

The characteristics of a solid propellant rocket engine with a controlled rate of thrust buildup to a desired thrust level are discussed. The engine uses a regressive burning controlled flow solid propellant igniter and a progressive burning main solid propellant charge. The igniter is capable of operating in a vacuum and sustains the burning of the propellant below its normal combustion limit until the burning propellant surface and combustion chamber pressure have increased sufficiently to provide a stable chamber pressure.

Dowler, W. L.↗
NASA NTRS1976

The plasmatron: Advanced mode thermionic energy conversion

A theory of the plasmatron was developed. Also, a wide range of measurements were obtained with two versatile, research devices. To gain insight into plasmatron performance, the experimental results are compared with calculations based on the theoretical model of plasmatron operation. Results are presented which show that the plasma arc drop of the conventional arc (ignited) mode converter can be suppressed by use of an auxiliary ion source. The improved performance, however, is presently limited to low current densities because of voltage losses due to plasma resistance. This resistance loss could be suppressed by an increase in the plasma electron temperature or a decrease in spacing. Plasmatron performance characteristics for both argon and cesium are reported. The argon plasmatron has superior performance. Results are also presented for magnetic cutoff effects and for current distributing effects. These are shown to be important factors for the design of practical devices.

Hansen, L. K.↗
NASA NTRS1983

Coupling of Transport and Chemical Processes in Catalytic Combustion

Catalytic combustors have demonstrated the ability to operate efficiently over a much wider range of fuel air ratios than are imposed by the flammability limits of conventional combustors. Extensive commercial use however needs the following: (1) the design of a catalyst with low ignition temperature and high temperature stability, (2) reducing fatigue due to thermal stresses during transient operation, and (3) the development of mathematical models that can be used as design optimization tools to isolate promising operating ranges for the numerous operating parameters. The current program of research involves the development of a two dimensional transient catalytic combustion model and the development of a new catalyst with low temperature light-off and high temperature stablity characteristics.

Bracco, F. V.↗
NASA NTRS1991

Gravitational Effects on Cellular Flame Structure

An experimental investigation has been conducted of the effect of gravity on the structure of downwardly propagating, cellular premixed propane-oxygen-nitrogen flames anchored on a water-cooled porous-plug burner. The flame is subjected to microgravity conditions in the NASA Lewis 2.2-second drop tower, and flame characteristics are recorded on high-speed film. These are compared to flames at normal gravity conditions with the same equivalence ratio, dilution index, mixture flow rate, and ambient pressure. The results show that the cellular instability band, which is located in the rich mixture region, changes little under the absence of gravity. Lifted normal-gravity flames near the cellular/lifted limits, however, are observed to become cellular when gravity is reduced. Observations of a transient cell growth period following ignition point to heat loss as being an important mechanism in the overall flame stability, dominating the stabilizing effect of buoyancy for these downwardly-propagating burner-anchored flames. The pulsations that are observed in the plume and diffusion flame generated downstream of the premixed flame in the fuel rich cases disappear in microgravity, verifying that these fluctuations are gravity related.

Dunsky, C. M.↗
DOE OSTI2024

Diagnosing up-scattered deuterium–tritium fusion neutrons produced in burning plasmas at the National Ignition Facility (invited)

In the push to higher performance fusion plasmas, two critical quantities to diagnose are α-heat deposition that can improve and impurities mixed into the plasma that can limit performance. In high-density, highly collisional inertial confinement fusion burning plasmas, there is a significant probability that deuterium–tritium (DT) fusion products, 14.1 MeV neutrons and 3.5 MeV α-particles, will collide with and deposit energy onto (“up-scatter”) surrounding deuterium and tritium fuel ions. These up-scattered D and T ions can then undergo fusion while in-flight and produce an up-scattered neutron (15–30 MeV). These reaction-in-flight (RIF) neutrons can then be uniquely identified in the measured neutron energy spectrum. Further, the magnitude, shape, and relative size of this spectral feature can inform models of stopping-power in the DT plasma and hence is directly proportional to α-heat deposition. In addition, the RIF spectrum can be related to mix into the burning fuel, particularly relevant for high-Z shell and other emerging National Ignition Facility platforms. The neutron time-of-flight diagnostic upgrades needed to obtain this small signal, ~10 –5 times the primary DT neutron peak, will be discussed. Results from several gain > 1 implosions will be shown and compared to previous RIF spectra. Finally, comparisons of experimental data to a simplified computational model will be made.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1994

Theoretical Basis for Estimated Test Times and Conditions for Drop Tower and Space-Based Droplet Burning Experiments With Methanol and N-Heptane

In order to develop an extensive envelope of test conditions for NASA's space-based Droplet Combustion Experiment (DCE) as well those droplet experiments which can be performed using a drop tower, the transient vaporization and combustion of methanol and n-heptane droplets were simulated using a recently developed fully time-dependent, spherically symmetric droplet combustion model. The transient vaporization of methanol and n-heptane was modeled to characterize the instantaneous gas phase composition surrounding the droplet prior to the introduction of an ignition source. The results for methanol/air showed that the entire gas phase surrounding a 2 mm methanol droplet deployed in zero-g .quickly falls outside the lean flammability limit. The gas phase surrounding an identically-sized n-heptane droplet, on the other hand, remains flammable. The combustion of methanol was then modeled considering a detailed gas phase chemical kinetic mechanism (168 steps, 26 species) and the effect of the dissolution of flame-generated water into the liquid droplet. These results were used to determine the critical ignition diameter required to achieve quasi-steady droplet combustion in a given oxidizing environment. For droplet diameters greater than the critical ignition diameter, the model predicted a finite diameter at which the flame would extinguish. These extinction diameters were found to vary significantly with initial droplet diameter. This phenomenon appears to be unique to the transient heat transfer, mass transfer and chemical kinetics of the system and thus has not been reported elsewhere to date. The extinction diameter was also shown to vary significantly with the liquid phase Lewis number since the amount of water present in the droplet at extinction is largely governed by the rate at which water is transported into the droplet via mass diffusion. Finally, the numerical results for n-heptane combustion were obtained using both 2 step and 96 step semi-emperical chemical kinetic mechanisms. Neither mechanism exhibited the variation of extinction diameter with initial diameter.

Marchese, Anthony J.↗
NASA NTRS1999

Experimental Verification of Material Flammability in Space

The flammability in microgravity of three US-furnished materials, Delrin, polymethylmethacrylate (PMMA), and high-density polyethylene, was determined using a Russian-developed combustion tunnel on Mir. Four 4.5-mm-diameter cylindrical samples of each plastic were ignited under concurrent airflow (in the direction of flame spread) with velocities from no flow to 8.5 cm/s. The test results identify a limiting air-flow velocity V(sub lim) for each material, below which combustion ceases. Nominal values are V(sub lim) < 0.3 cm/s for Delrin, 0.5 cm/s for PMMA, and 0.3 to 0.5 cm/s for polyethylene. These values are lower than those obtained in prior ground testing. Nevertheless, they demonstrate that flow shutoff is effective for extinguishment in the microgravity environment of spacecraft. Microgravity test results also show that the plastic materials maintain a stable melt ball within the spreading flame zone. In general, as the concurrent flow velocity V decreases, the flame-spread rate V(sub F) decreases, from an average (for all three materials) of V(sub F)= 0.5-0.75 mm/s at V = 8.5 cm/s to V(sub F)= 0.05-0.01 mm/s at V = 0.3-0.5 cm/s. Also, as V decreases, the flames become less visible but expand, increasing the probability of igniting an adjacent surface.

Ivanov, A. V.↗
NASA NTRS1986

Thermal and flammability characterization of graphite composites

Thermal, mechanical, and flammability properties of graphite composites fabricated with XU71775/H795, a bismaleimide/vinyl-polystyrylpyridine formulation; H795, a bismaleimide; Cycom 6162, a phenolic; and PSP 6022M, a polystyrylpyridine and two types of graphite reinforcement were evaluated and compared with a composite made with an epoxy resin as a matrix. The measured properties included limiting-oxygen index, smoke evolution, thermal degradation products, total-heat release, heat-release rates, mass loss, flame spread, ignition resistance, thermogravimetric analysis, and selected mechanical properties. It was found that the combination of XU71775/H795 with the graphite tape was the optimum design giving the lowest heat release rate.

Kourtides, D. A.↗
NASA NTRS1987

Review of thermal properties of graphite composite materials

Flammability, thermal, and selected mechanical properties of composites fabricated with epoxy and other thermally stable resin matrices are described. Properties which were measured included limiting-oxygen index, smoke evolution, thermal degradation products, total-heat release, heat-release rates, mass loss, flame spread, ignition resistance, thermogravimetric analysis, and selected mechanical properties. The properties of 8 different graphite composite panels fabricated using four different resin matrices and two types of graphite reinforcement are described. The resin matrices included: XU71775/H795, a blend of vinyl polystyryl pyridine and bismaleimide; H795, a bismaleimide; Cycom 6162, a phenolic; and PSP 6022M, a polystyryl pyridine. The graphite fiber used was AS-4 in the form of either tape or fabric. The properties of these composites were compared with epoxy composites. It was determined that the blend of vinyl polystyryl pyridine and bismaleimide (XU71775/H795) with the graphite tape was the optimum design giving the lowest heat release rate.

Kourtides, D. A.↗