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At least 181 records · Page 10

All sources NASA NTRS DOE OSTI

DOE OSTI2022

Yield stress and flow behavior of enzyme liquefied slurries from corn cobs and corn stover pellets

With the increase in population, the world will depend on renewable sources to meet the increasing energy needs. The use of lignocellulosic biomass as a renewable source has been proven efficient for conversion to cellulosic ethanol and capable of contributing to thresholds for energy demand while reducing greenhouse gases by 90% when compared with fossil fuels. However, limitations in feeding and flow within biorefineries is encountered when system plugging occurs due to biomass compaction and a high yield stress for slurries formed during its processing, thereby preventing transport of biomass materials between plant unit operations. In some cases, this leads to unexpected plant shutdowns increasing industrial operational costs. As an alternative, enzyme-assisted liquefaction for slurry creation from corn stover at solids loadings up to 30% is reported in this work. Two different kinds of biomass (pelleted corn stover and cobs) were liquefied in a fed-batch process using commercial enzymes Celluclast 1.5L or Ctec-2 at 1FPU or 3 FPU per gram of dry solids in 10 mM sodium citrate buffer solution (pH 4.8). Pellets were fed into a 1 L stirred bioreactor according to a pre-defined fed-batch protocol over the first 5 hours until reaching 30% of solids loading. After 6, 24 and 96 hours, samples were taken and characterized with respect to their sugar composition, rheology and water absorption. Successful slurry creation with dramatically reduced yield stress was achieved for corn stover for both assessed enzymes. Yield stresses of 178±7 Pa (3 FPU, Celluclast 1.5L) and 79±6 Pa (3 FPU, Ctec-2) were measured for corn stover at 24 hours, compared to 6,000 Pa for samples without enzyme. Yield stress was 155± 29 Pa (3FPU, Ctec-2) and 257 ± 72 Pa (1 FPU,Celluclast 1.5L) for corn cobs at 24 hours. Yield stress decreased when residence time increased with an enhanced fluidity noted for higher enzyme concentrations. A profile for 6, 24 and 96h of yield stress measurements is presented.

Guitierrez, Diana↗

DOE OSTI2020

We Just Want to Pump…You Up! Forecasting Grid-Connected Heat Pump Water Heater Energy Savings and Load Shifting Potential for the Southeast U.S.

Heat pump water heaters (HPWH) can achieve energy savings of 60-70% compared to conventional electric-resistance water heaters. However, even with a favorable simple payback period within the typical product lifetime, HPWHs make up only 1% of all electric water heaters sold in the residential sector. Market adoption is challenged, in part, by the lack of effective energy efficiency programs in the U.S. region with the greatest amount of residential electric water heaters. The recent integration of connected functionality into HPWHs offers the capability to shift load without undue negative impact on customers. This capability can provide value to utilities with peak load constraints, motivating them to promote HPWHs for the first time. This paper will present a methodology to forecast connected HPWH energy use and extrapolate load shifting potential for the Southeast U.S. region. The methodology leverages data from a robust connected HPWH field study conducted in the Pacific Northwest. A coefficient of performance (COP) relationship for HPWHs was developed using ambient and inlet water temperature data to forecast HPWH performance on a month-by-month basis. Using the forecasted COP, HPWH operating hours were calculated for meeting load, which serve as the proxy to extrapolate load shifting potential from the Pacific Northwest to the Southeast. As a use case, analytical results are presented for a specific utility. This methodology, in combination with market analysis, facilitates the development of customized energy savings and load shifting forecasts to understand the potential impacts of launching connected HPWH programs in specific utility service territories.

heat pump water heater, energy savings, load shift↗

DOE OSTI2024

Improving Cost and Efficiency of the Scalable Solid Oxide Fuel Cells Power System

The objective of this project was to design and develop a 20kW range small-scale solid oxide fuel cells (SOFC) power system for applications such as data centers and commercial buildings. The original plan included a 5,000 hours demonstration and a Techno-Economic Analysis (TEA) which were dropped as part of project termination. The original project plan was to use a stack with a cross-flow cell design which had previously been tested for 500 hours at a community college in Malta, NY. However, it was decided to move to the advanced R-SOFC co-flow cell developed under Department of Energy Award DE-FE0031971. The advanced cell design has the advantage of a larger active area for the same manufacturing footprint which results in fewer required cells for the same stack power, hence a higher volumetric power density (kW/L) and lower cost per kW than the original cross-flow cell design. A full SOFC system Simulink model was developed and calibrated with testing data from a fuel cell stack and BOP (balance of plant) components. The simulation results from the calibrated model showed an acceptable match with the experimental data. A structural analysis conducted for various load scenarios indicated no high stress areas for all spatial directions. Major electrical system components were acquired, built and successfully tested. System sensors were verified and validated against controls. Safety checks, a diagnostic check, PID tuning, and control software commissioning tasks were also conducted. The power electronics prototype was delivered and trial testing completed. Balance of Plant component testing and simulation work was conducted to characterize Reformer-Heat Exchanger heat transfer and backpressure and reformer catalyst methane conversion and product selectivity. Simulations were conducted to design the Anode and Cathode fluid passages and size the air-air and fuel-fuel heat exchangers. A Burner operation map was created from test data and the Anode Gas Recirculation blower was tested to evaluate its durability. The SOFC system used a horizontal style design where components sit directly on a casting with a direct connection to the skid. This design has efficient packaging and a small footprint with approximate dimensions of 750 mm x 700 mm x 1700 mm. An SOFC system was built and successfully tested at the Malta, NY facility The system for over 500 hours under load of which over 300 hours was at full load of 20 kW.

30 DIRECT ENERGY CONVERSION↗

NASA NTRS1994

Non-isolated 30 kW class arcjet PCU

A 30 kW class arcjet Power Conditioning Unit, PCU, was built and tested during this Phase 2 SBIR contract. The PCU is an improved version of two previously developed PCU's. All of these units are 3-phase, 20 kHz buck regulators with current mode feed back to modulate the duty cycle to control the arcjet current at any selected operating point. The steady state control can assure arcjet stability despite the negative dynamic resistance of the arc discharge. The system also has a circuit to produce a high voltage start pulse to breakdown the gas and initiate the arc. The start pulse is formed by temporarily switching a short current path across the output terminals with a special solid state switching array. The switches then open rapidly, and the energy stored in the output inductors of the buck regulator produces a pulse of approximately 2500 V for approximately 500 nsec. The system was tested and modified until the transition to steady operation occurred after start up with a very small surge current overshoot. The system also can withstand a direct short circuit across the output without damage. The automatic feed back control simply reduces the duty cycle to hold the current at the set point. When the short is removed the full power output is immediately restored. This latest version arcjet PCU is conduction cooled to remove waste heat by conduction to the base plate. This unit is closer to flight a type of design than the previous functional bread boards. Waste heat is small because the PCU has a very high efficiency, 296 percent. The PCU was extensively tested with resistor loads to simulate operation with an arcjet. The unit was tested with ammonia arcjets at the Jet Propulsion Laboratory. Approximately 400 hours of testing were completed, with several starts. Many hours were also demonstrated with resistive loads. Some testing with hydrogen arcjets was also carried out at NASA LeRC. This system concept is now the design base for the ATTD program.

Wong, See-Pok↗

DOE OSTI2022

Physically Realistic Estimates of Electric Water Heater Demand Response Resource

Multiple grid integration studies have examined the value of demand response, including from water heaters, to bulk power systems. Common shortcomings of these studies include physically unrealistic assumptions. For example, studies often assume that all electric water heater load can be shed for up to an hour to provide capacity or contingency service, that all electric water heater load is shiftable, and that round-trip efficiencies for shifting service are 100%. Another issue is that simply summing up estimates of individual water heaters' flexibility bounds, an attractive idea for constructing the MW-scale resources necessary for direct inclusion in grid investment and operational models, can result in significant overestimates of actual resource, because, e.g., a water heater with the ability to reduce load may not be able sustain the reduction for as long as the aggregate model suggests is possible. This presentation demonstrates the impact of estimating the flexibility of electric water heaters with physically realistic models suitable for grid service analysis. Electric water heater flexibility representations are constructed based on ResStock simulations of New England. Specifically, we examine contingency resource (related to capacity, shed, and contingency reserve services) and energy shifting resource from electric resistance and heat pump water heaters. Different estimation methods are compared; and the surrogate models' event responses are validated against events directly simulated in EnergyPlus. We also demonstrate the impact of using electric water heaters for contingency reserves and energy shifting in detailed models of possible future ISO New England power systems.

building energy modeling↗

NASA NTRSDate not supplied

Fracture Mechanics Testing of Titanium 6AL-4V in LMP-103S Propellant

Propellant tank safe-life analysis is a spacecraft propulsion subsystem Launch Range processing requirement. The material property inputs for the safe-life analysis include the stress intensity factor for environment-assisted cracking (KEAC). The KEAC for titanium alloy Ti 6Al-4V in LMP-103S propellant was determined experimentally using an innovative test method following ASTM E1681, Standard Test Method for Determining Threshold Stress Intensity Factor for Environment-Assisted Cracking of Metallic Materials. This effort was a collaboration between NASA Goddard Space Flight Center and NASA Kennedy Space Center to expose the test specimens in the propellant, while loaded in the test fixtures, for 1000- hour (42 days) at 50°C. Two test rounds have been completed to date; 1) testing mechanically loaded specimens but without propellant and 2) testing mechanically loaded specimens wetted with LMP-103S propellant. The dry test was to evaluate the crack growth without exposure to the LMP-103S propellant, and further assess the un-wetted stress intensity factor for the full 1000-hour duration. The second round of testing included the propellant soak for the requisite 1000- hour at 50°C. Current results show that the threshold intensity factor for environment-assisted cracking (exposed to LMP103S) is 22.5 ksi√in for the bulk material and 36. 2 ksi√in for the weld material. A generic ‘candidate’ tank geometry and material thickness is developed for a damage tolerance of known surface cracks below the nondestructive inspection technique detection limit. Evaluations with and without the use of a threshold intensity factor for environment-assisted cracking is performed for the required 4x propellant tank service life using the software tool NASGRO. SP2024_00239

Green propulsion↗

DOE OSTI2023

Liquefaction of different corn stover fractions assisted by enzyme-biomass deconstruction

Recalcitrant properties of different sources of lignocellulosic biomass represent challenges in materials processing within a biorefinery, as well as enzyme efficient deconstruction to fermentable sugars. Limitations include lignin derived enzyme inhibitors, enzyme inhibition by hydrolysis products, and resistance to mixing due to rheological properties of lignocellulosic particulates at high solids loadings. Consequently, we examined conditions that might be used to achieve liquid slurries (i.e., liquefaction) at solids loadings of 300 g/L before the material enters the biorefinery through a pretreatment step. This work explores enzyme-assisted liquefaction in a fed-batch process using the commercial enzymes Celluclast 1.5L or Ctec-2 at 1FPU/g or 3 FPU/g of dry solids, basis. Corn stover pellets were fed into a 1 L stirred bioreactor containing enzyme solution over a 5-hour period until reaching 30% solids loading (dry wgt / vol basis). After 6, 24 and 96 hours from the start of the run, samples were taken and characterized with respect to their sugar composition, rheology, water absorption and enzyme activity. Slurries with dramatically reduced yield stresses were achieved for corn stover. Yield stresses of 178±7 Pa (3 FPU, Celluclast 1.5L) and 79±6 Pa (3FPU, Ctec-2) were measured for corn stover at 24 hours, compared to 6,000 Pa for samples without enzyme.Yield stress was 155± 29 Pa (3FPU, Ctec-2) and 257 ± 72 Pa (1 FPU, Celluclast 1.5L) for corn cobs at 24 hours.A profile based on 6, 24 and 96h of yield stress measurements and sugar conversion is presented. Enzyme activity is measured and the impact of liquefaction on an integrated processing in a biorefinery operation is discussed.

Gutierrez, Diana↗

DOE OSTI2026

Experimental characterization and analysis of phase change material-based thermal energy storage system for refrigerated display case

Refrigerated display cases that are used to store and exhibit food products in supermarkets and retail spaces consume a significant portion of the buildings’ total electricity. Importantly, the refrigeration-related energy cost and demand charges are greatly affected by the time-of-use electricity pricing and demand rates, which are at their maximum during peak hours, typically when refrigeration energy consumption is also high. Using energy storage to shift the refrigeration load from peak to off-peak hours can greatly reduce the operational costs in the supermarket. This study demonstrates a phase change material-based thermal energy storage (TES) system, specifically designed in stackable units, that can be integrated with an open vertical refrigerated display case. We perform numerical and experimental characterization that includes finite-difference modeling for the TES, prototype fabrication, and laboratory evaluation, followed by a preliminary system-level analysis to predict the impact of TES on the refrigerated case performance, energy use, and energy cost. The results show that the dedicated latent TES for refrigerated cases can provide a specific energy of 50.4 Wh/kg and a specific power of 15.5 W/kg. The TES can be charged during 12 h of the off-peak period and discharged at various rates during 4 to 6 h of the peak period, thereby shifting the refrigeration load from the peak to the off-peak period. Consequently, annual cost savings up to 19% can be achieved, depending on the thermal load, the summer/winter peak electricity pricing, and the transition temperature of the phase change material used.

25 ENERGY STORAGE↗

DOE OSTI2023

EV charging site day-ahead load prediction in a synthetic environment for RL based grid-informed charging

Ensuring grid health in the face of increasing demand for power is an emerging challenge especially due to transportation electrification. A free market approach to influencing electric vehicle (EV) load through grid-informed hourly dynamic pricing is introduced in this work. The setting of charging price is done by a reinforcement learning (RL) agent that learns the complicated dynamics by interacting with a synthetic environment. This synthetic environment is a combination of distribution feeder simulation, EV charger user behavior dynamics, and EV charging simulation. A key module in this synthetic environment involves obtaining the day-ahead charging profile of EV charging stations based on real-world past data. The day-ahead prediction is also useful in other traditional optimizations related to EV charge scheduling. The proposed approach involves using EV charging data from two different past time horizons – one to determine the shape of the daily profile and the other to determine a scaling value to capture actual energy consumption. Real-world charging data over many years from the ACN charging network has been used to demonstrate the ability to predict the day-ahead profile with only charge session data. Both Python and MATLAB have been used for data cleaning, processing, analysis, and prediction.

Suryanarayana, Harish↗

DOE OSTI2025

A New Hybrid Quantum-Classical Algorithm for Solving the Unit Commitment Problem

Solving problems related to planning and operations of large-scale power systems is challenging on classical computers due to their inherent nature as mixed-integer and nonlinear problems. Quantum computing provides new avenues to approach these problems. We develop a hybrid quantum-classical algorithm for the Unit Commitment (UC) problem in power systems which aims at minimizing the total cost while optimally allocating generating units to meet the hourly demand of the power loads. The hybrid algorithm combines a variational quantum algorithm (VQA) with a classical Benders-type heuristic. The resulting algorithm computes approximate solutions to UC in three stages: i) a collection of UC vectors capable meeting the power demand with lowest possible operating costs is generated based on VQA; ii) a classical sequential least squares programming (SLSQP) routine is leveraged to find the optimal power level corresponding to a predetermined number of candidate vectors; iii) in the last stage, the approximate solution of UC along with generating units power level combination is given. To demonstrate the effectiveness of the presented method, three different systems with 3 generating units, 10 generating units, and 26 generating units were tested for different time periods. In addition, convergence of the hybrid quantum-classical algorithm for select time periods is proven out on IonQ's Forte system.

Aboumrad, Willie [IonQ, Inc]↗

DOE OSTI2021

Multi-Time Scale Coordinated Control and Scheduling of Inverter-Based TCLs With Variable Wind Generation

To address microgrid tie flow errors caused by wind generation variability, here we propose and develop a multi-time scale coordinated control and scheduling strategy for inverter-based thermostatically controlled loads (TCLs). First, in hour-time scale, inverter-based TCLs with adjusting temperature set-point are modeled as virtual generators to compensate tie flow deviations in the day-ahead plan. Next, in minute-time scale, virtual batteries representing operating behaviors of inverter-based TCLs with frequency control are scheduled determined by the control of virtual generators in hour-time scale. The virtual batteries are scheduled to smooth out tie flow errors corresponding to day-ahead plan and hour-time scale schedules. The multi-time scale control methods are coordinated to employ the response potential of inverter-based TCLs and response curve-based methods are proposed to control inverter-based TCLs considering the customer privacy. The multi-time scale stochastic schedules which are based on response curves of inverter-based TCLs are coordinated to accommodate wind generation variability. Simulation results demonstrate that the microgrid tie flow errors are effectively mitigated by the proposed multi-time scale coordinated control and scheduling of inverter-based TCLs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2022

Evi-Pro Lite API

This application programing interface provides output from NREL's EVI-Pro model and is used to power the EVI-Pro Lite tool at https://afdc.energy.gov/evi-pro-lite. These endpoints provide daily (24-hour) fleet-level charging load profiles for a variety of customizable scenarios.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2022

Evi-Pro Lite API

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2026

Evi-Pro Lite API

This application programing interface provides output from NLR's EVI-Pro model and is used to power the EVI-Pro Lite tool at https://afdc.energy.gov/evi-pro-lite. These endpoints provide daily (24-hour) fleet-level charging load profiles for a variety of customizable scenarios.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS1978

Solid Polymer Electrolyte (SPE) fuel cell technology program

Many previously demonstrated improved fuel cell features were consolidated to (1) obtain a better understanding of the observed characteristics of the operating laboratory-sized cells; (2) evaluate appropriate improved fuel cell features in 0.7 sq ft cell hardware; and (3) study the resultant fuel cell capability and determine its impact on various potential fuel cell space missions. The observed performance characteristics of the fuel cell at high temperatures and high current densities were matched with a theoretical model based on the change in Gibbs free energy voltage with respect to temperature and internal resistance change with current density. Excellent agreement between the observed and model performance was obtained. The observed performance decay with operational time on cells with very low noble metal loadings (0.05 mg/sq cm) were shown to be related to loss in surface area. Cells with the baseline amount of noble catalyst electrode loading demonstrated over 40,000 hours of stable performance.

Source record↗

NASA NTRS1983

Experimental creep data for a built-up aluminum/titanium structure subjected to heating and loading

Experimental creep, temperature, and strain data resulting from a laboratory experiment on a built-up aluminum/titanium structure are presented. The structure and the experiment are described in detail. A heating and loading experiment lasting approximately six hours is conducted on a test structure. Considerable creep strain resulted from compressive stresses in the heated skin. Large residual stresses were found after the experiment was completed. The residual stresses in the substructure frames were large enough to preclude further cycles of creep experiments with this built-up structure because of concern that the frame webs would buckle.

Jenkins, J. M.↗

NASA NTRS1985

CELCAP: A Computer Model for Cogeneration System Analysis

A description of the CELCAP cogeneration analysis program is presented. A detailed description of the methodology used by the Naval Civil Engineering Laboratory in developing the CELCAP code and the procedures for analyzing cogeneration systems for a given user are given. The four engines modeled in CELCAP are: gas turbine with exhaust heat boiler, diesel engine with waste heat boiler, single automatic-extraction steam turbine, and back-pressure steam turbine. Both the design point and part-load performances are taken into account in the engine models. The load model describes how the hourly electric and steam demand of the user is represented by 24 hourly profiles. The economic model describes how the annual and life-cycle operating costs that include the costs of fuel, purchased electricity, and operation and maintenance of engines and boilers are calculated. The CELCAP code structure and principal functions of the code are described to how the various components of the code are related to each other. Three examples of the application of the CELCAP code are given to illustrate the versatility of the code. The examples shown represent cases of system selection, system modification, and system optimization.

Source record↗

NASA NTRS1986

Galileo probe battery systems design

NASA's Galileo mission to Jupiter will consist of a Jovian orbiter and an atmospheric entry probe. The power for the probe will be derived from two primary power sources. The main source is composed of three Li-SO2 battery modules containing 13 D-size cell strings per module. These are required to retain capacity for 7.5 years, support a 150 day clock, and a 7 hour mission sequence of increasing loads from 0.15 to 9.5 amperes for the last 30 minutes. This main power source is supplemented by two thermal batteries (CaCrO4-Ca) for use in firing the pyrotechnic initiators during the atmospheric staging events. This paper describes design development and testing of these batteries at the system level.

Dagarin, B. P.↗