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All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Redesigned Nylon 6 Variants with Enhanced Recyclability, Ductility, and Transparency

Geminal (gem−) disubstitution in heterocyclic monomers is an effective strategy to enhance polymer chemical recyclability by lowering their ceiling temperatures. However, the effects of specific substitution patterns on the monomer's reactivity and the resulting polymer's properties are largely unexplored. Here we show that, by systematically installing gem-dimethyl groups onto ϵ-caprolactam (monomer of nylon 6) from the α to ϵ positions, both the redesigned lactam monomer's reactivity and the resulting gem-nylon 6’s properties are highly sensitive to the substitution position, with the monomers ranging from non-polymerizable to polymerizable and the gem-nylon properties ranging from inferior to far superior to the parent nylon 6. Remarkably, the nylon 6 with the gem-dimethyls substituted at the γ position is amorphous and optically transparent, with a higher T g (by 30 °C), yield stress (by 1.5 MPa), ductility (by 3×), and lower depolymerization temperature (by 60 °C) than conventional nylon 6.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

MEMOTE for standardized genome-scale metabolic model testing

Reconstructing metabolic reaction networks enables the development of testable hypotheses of an organism’s metabolism under different conditions. State-of-the-art genome-scale metabolic models (GEMs) can include thousands of metabolites and reactions that are assigned to subcellular locations. Gene–protein–reaction (GPR) rules and annotations using database information can add meta-information to GEMs. GEMs with metadata can be built using standard reconstruction protocols, and guidelines have been put in place for tracking provenance and enabling interoperability, but a standardized means of quality control for GEMs is lacking. Here we report a community effort to develop a test suite named MEMOTE (for metabolic model tests) to assess GEM quality.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1979

Gravity model improvement using GEOS 3 /GEM 9 and 10/

Although errors in previous gravity models have produced large uncertainties in the orbital position of GEOS 3, significant improvement has been obtained with new geopotential solutions, Goddard Earth Model (GEM) 9 and 10. The GEM 9 and 10 solutions for the potential coefficients and station coordinates are presented along with a discussion of the new techniques employed. Also presented and discussed are solutions for three fundamental geodetic reference parameters, viz. the mean radius of the earth, the gravitational constant, and mean equatorial gravity. Evaluation of the gravity field is examined together with evaluation of GEM 9 and 10 for orbit determination accuracy. The major objectives of GEM 9 and 10 are achieved. GEOS 3 orbital accuracies from these models are about 1 m in their radial components for 5-day arc lengths. Both models yield significantly improved results over GEM solutions when compared to surface gravimetry, Skylab and GEOS 3 altimetry, and highly accurate BE-C (Beacon Explorer-C) laser ranges. The new values of the parameters discussed are given.

Lerch, F. J.↗
NASA NTRS1979

HEAO-1 observations of dwarf novae

Results are reported for X-ray observations of about 20 dwarf novae in optical outburst with the A-2 experiment aboard HEAO 1. It is shown that only U Gem was detected as an X-ray source during optical outburst and that X-ray emission was observed from SS Cyg, EX Hya, and AY Lyr during optical quiescence. The results obtained indicate that: (1) the soft and hard X-ray emission from U Gem and SS Cyg is linked to the optical state of the system; (2) both U Gem and SS Cyg have one soft and one hard X-ray spectral component; (3) the ratio of soft to hard X-ray energy flux from both U Gem and SS Cyg during outburst is about 10; (4) X-ray emission of the strength and temperature seen from SS Cyg and U Gem is not common among dwarf novae; (5) the hard X-ray flux from SS Cyg and EX Hya probably originates in a hot optically thin plasma; and (6) the variability of the hard X-ray flux from SS Cyg and EX Hya suggests a cooling time scale that would limit the characteristic size of the emission region to a value comparable to the dimensions of a white dwarf.

Mason, K.↗
NASA NTRS1986

Comments on Lambeck and Coleman - 'The earth's shape and gravity field: A report of progress from 1958 to 1982'

The accuracy and validation of global gravity models based on satellite data are discussed, responding to the statistical analysis of Lambeck and Coleman (1983) (LC). Included are an evaluation of the LC error spectra, a summary of independent-observation calibrations of the error estimates of the Goddard Earth Models (GEM) 9 and L2 (Lerch et al., 1977, 1979, 1982, 1983, and 1985), a comparison of GEM-L2 with GRIM-3B (Reigber et al., 1983), a comparison of recent models with LAGEOS laser ranging, and a summary of resonant-orbit model tests. It is concluded that the accuracy of GEMs 9, 10, and L2 is much higher than claimed by LC, that the GEMs are in good agreement with independent observations and with GRIM-3B, and that the GEM calibrations were adequate. In a reply by LC, a number of specific questions regarding the error estimates are addressed, and it is pointed out that the intermodel discrepancies of the greatest geophysical interest are those in the higher-order coefficients, not discussed in the present comment. It is argued that the differences among the geoid heights of even the most recent models are large enough to call for considerable improvements.

Lerch, F. J.↗
NASA NTRS1989

Gravitational model improvement at the Goddard Space Flight Center

Major new computations of terrestrial gravitational field models were performed by the Geodynamics Branch of Goddard Space Flight Center (GSFC). This development has incorporated the present state of the art results in satellite geodesy and have relied upon a more consistent set of reference constants than was heretofore utilized in GSFC's GEM models. The solutions are complete in spherical harmonic coefficients out to degree 50 for the gravity field parameters. These models include adjustment for a subset of 66 ocean tidal coefficients for the long wavelength components of 12 major ocean tides. This tidal adjustment was made in the presence of 550 other fixed ocean tidal terms representing 32 major and minor ocean tides and the Wahr frequency dependent solid earth tidal model. In addition 5-day averaged values for Earth rotation and polar motion were derived for the time period of 1980 onward. Two types of models were computed. These are satellite only models relying exclusively on tracking data and combination models which have incorporated satellite altimetry and surface gravity data. The satellite observational data base consists of over 1100 orbital arcs of data on 31 satellites. A large percentage of these observations were provided by third generation laser stations (less than 5 cm). A calibration of the model accuracy of the GEM-T2 satellite only solution indicated that it was a significant improvement over previous models based solely upon tracking data. The rms geoid error for this field is 110 cm to degree and order 36. This is a major advancement over GEM-T1 whose errors were estimated to be 160 cm. An error propagation using the covariances of the GEM-T2 model for the TOPEX radial orbit component indicates that the rms radial errors are expected to be 12 cm. The combination solution, PGS-3337, is a preliminary effort leading to the development of GEM-T3. PGS-3337 has incorporated global sets of surface gravity data and the Seasat altimetry to produce a model complete to (50,50). A solution for the dynamic ocean topography to degree and order 10 was included as part of this adjustment.

Marsh, J. G.↗
NASA NTRS1994

Chemically anomalous, pre-accretionally irradiated grains in interplanetary dust -- interstellar grains?

Ultrafine-grained matrix is a unique and fundamental building block of chondritic porous (CP) interplanetary dust particles. Most IDPs so far determined to be of cometary origin belong to the CP class. The matrix in CP IDPs is not homogeneous but rather a loose mixture of discrete single crystals (e.g., olivine, pyroxene, Fe sulfides) and polyphase grains. The petrographic diversity observed among the polyphase grains suggest that they were formed under variable physiochemical conditions. One particular class of polyphase grains are a dominant component in cometary IDPs. Although their occurrence is well documented, the terminology used to describe them is confused. They have been called many names. Here they are simply called GEMS (Glass with Embedded Metal and Sulfides). The bulk compositions of GEMS are within a factor of 3 chondritic (solar) for all major elements except C. Quantitative thin-film X-ray (EDS) analyses have shown that GEMS are systematically depleted in Mg and Si, enriched in S, Fe, and Ni, and stoichiometrically enriched in O. Electron energy-loss spectroscopy (EELS) suggests that the excess O is present as hydroxyl (-OH) groups. These same chemical 'anomalies' were observed in solar-wind-irradiated amorphous rims on the surfaces of IDPs, suggesting that the compositions of GEMS reflect prior exposure to ionizing radiation. In order to test this hypothesis, a sample of Allende (CV3) matrix was exposed to proton flux. Radiation-damaged amorphous rims on olivine and pyroxene crystals in the Allende sample were found to be depleted in Mg and Ca, enriched in S, Fe, and Ni, and stoichiometrically enriched in O. Thus, the compositions of GEMS are indeed consistent with exposure to ionizing radiation. This study suggests that chemical as well as isotopic anomalies may be used to identify presolar interstellar grains in primitive meteoritic materials.

Bradley, J. P.↗
NASA NTRS2007

Global Environmental Micro Sensors Test Operations in the Natural Environment

ENSCO, Inc. is developing an innovative atmospheric observing system known as Global Environmental Micro Sensors (GEMS). The GEMS concept features an integrated system of miniaturized in situ, airborne probes measuring temperature, relative humidity, pressure, and vector wind velocity. In order for the probes to remain airborne for long periods of time, their design is based on a helium-filled super-pressure balloon. The GEMS probes are neutrally buoyant and carried passively by the wind at predetermined levels. Each probe contains onboard satellite communication, power generation, processing, and geolocation capabilities. ENSCO has partnered with the National Aeronautics and Space Administration's Kennedy Space Center (KSC) for a project called GEMS Test Operations in the Natural Environment (GEMSTONE) that will culminate with limited prototype flights of the system in spring 2007. By leveraging current advances in micro and nanotechnology, the probe mass, size, cost, and complexity can be reduced substantially so that large numbers of probes could be deployed routinely to support ground, launch, and landing operations at KSC and other locations. A full-scale system will improve the data density for the local initialization of high-resolution numerical weather prediction systems by at least an order of magnitude and provide a significantly expanded in situ data base to evaluate launch commit criteria and flight rules. When applied to launch or landing sites, this capability will reduce both weather hazards and weather-related scrubs, thus enhancing both safety and cost-avoidance for vehicles processed by the Shuttle, Launch Services Program, and Constellation Directorates. The GEMSTONE project will conclude with a field experiment in which 10 to 15 probes are released over KSC in east central Florida. The probes will be neutrally buoyant at different altitudes from 500 to 3000 meters and will report their position, speed, heading, temperature, humidity, and pressure via satellite. The GEMS data will be validated against reference observations provided by current weather instrumentation located at KSC. This paper will report on the results of the GEMSTONE project and discuss the challenges encountered in developing an airborne sensor system.

Adams, Mark L.↗
NASA NTRS1973

A gravitational field model for the earth.

Two models of the earth's gravitational field have been computed. The first, Goddard Earth Model 1 (GEM 1), has been derived from satellite tracking data. The second, Goddard Earth Model 2 (GEM 2), has been derived from a combination of satellite tracking and surface gravimetric data. The satellite data consisted primarily of optical data processed on 300 weekly orbital arcs for 25 close earth satellites. Surface gravity data were employed in the form of 5 x 5 deg mean free-air gravity anomalies providing about 70% world coverage. Station locations were obtained for 46 tracking sites by combining electronic, laser, and additional optical tracking data with the above satellite data. Analysis of the radial positions of these stations and a value of mean gravity on the geoid indicated a mean equatorial radius for the earth of about 6378.145 meters. Results of geopotential tests on satellite data not used in the solution show that better agreement was obtained with the GEM 1 and GEM 2 models than with the 1969 Smithsonian Standard Earth II model.

Smith, D. E.↗
NASA NTRS1985

On the accuracy of recent Goddard gravity models

The Goddard Space Flight Center (GSFC) has occupied a central position within NASA with respect to the development of earth gravity models. The gravity models at Goddard, which are referred to as the Goddard earth models (GEM's) have been under development for more than 15 years. The fields have increased in size and (apparent) accuracy with the inclusion of new tracking data, better nongravitational force modeling, and more orbits over a wide range of inclinations and mean motions. The usefulness of the considered models depends largely on accuracy estimates. The present paper is concerned with a reevaluation of earlier accuracy assessments, taking into account the accuracies of the GEM 9 and the GEM-L2 models. It is found that GEM 9 is about 30 percent more accurate than originally estimated in 1979 from older gravimetry data.

Lerch, F. J.↗
NASA NTRS1994

Cooling of the white dwarf in U Geminorum between outbursts

We have obtained far-ultraviolet (1150-1610 A) spectra of U Gem with the Faint Object Spectrograph on the Hubble Space Telescope approximately 13 and 70 days after the end of a normal dwarf nova outburst of the system. Both spectra appear dominated by the White Dwarf (WD) in U Gem. At 1400 A, the flux from U Gem declined approximately 28% between the two observations. Detailed comparison of the spectra with solar abundance WD models suggest that average surface temperature of the WD surface cooled from approximately 39,400 K to approximately 32,100 K between the two observations. The main features which are not fitted well by WD models are absorption due to N V lambda lambda-1239, 1243 and emission at Lyman-alpha. These observations provide unambiguous confirmation that the WD in U Gem cools during quiescence, as was suggested by analyses of far-ultraviolet spectra obtained with International Ultraviolet Explorer (IUE) and Hopkins Ultraviolet Telescope (HUT).

Long, Knox S.↗
NASA NTRS1995

Starspot evolution, differential rotation, and magnetic cycles in the chromospherically active binaries lambda andromedae, sigma Geminorum, II Pegasi, and V711 Tauri

We have analyzed 15-19 yr of photoelectric photometry, obtained manually and with automated telescopes, of the chromospherically active binaries lambda And, sigma Gem, II Peg, and V711 Tau. These observations let us identify individual dark starspots on the stellar surfaces from periodic dimming of the starlight, follow the evolution of these spots, and search for long-term cyclic changes in the properties of these starspots that might reveal magnetic cycles analogous to the Sun's 11 yr sunspot cycle. We developed a computer code to fit a simple two-spot model to our observed light curves that allows us to extract the most easily determinable and most reliable spot parameters from the light curves, i.e., spot longitudes and radii. We then used these measured properties to identify individual spots and to chart their life histories by constructing migration and amplitude curves. We identified and followed 11 spots in lambda And, 16 in sigma Gem, 12 in II Peg, and 15 in V711 Tau. Lifetimes of individual spots ranged from a few months to longer than 6 yr. Differential rotation coefficients, estimated from the observed range of spot rotation periods for each star and defined by equation (2), were 0.04 for lambda And, 0.038 for sigma Gem, 0.005 for II Peg, and 0.006 for V711 Tau, versus 0.19 for the Sun. We searched for cyclic changes in mean brightness, B-V color index, and spot rotation period as evidence for long-term cycles. Of these, long-term variability in mean brightness appears to offer the best evidence for such cycles in these four stars. Cycles of 11.1 yr for lambda And, 8.5 yr for sigma Gem, 11 yr for II Peg, and 16 yr V711 Tau are implied by these mean brightness changes. Cyclic changes in spot rotation period were found in lambda And and possibly II Peg. Errors in B-V were too large for any long-term changes to be detectable.

Henry, Gregory W.↗
NASA NTRS2002

XTE Observations of Intermediate Polars: RXTE TOO Observations of Supernovae

Two Intermediate Mars were observed with XTE (X-Ray Timing Explorer): PQ Gem and AO Psc. A very preliminary analysis for PQ Gem was presented at the Annapolis Workshop on Magnetic Cataclysmic Variables. At about the same time, the XTE team created a new background estimator for faint sources. The PQ Gem data must be reanalyzed using the new background estimator. The data for AO Psc have been analyzed and await the analysis of PQ Gem.

Schlegel, E.↗
NASA NTRS2002

The Evolution of Disks and Winds in Dwarf Nova Outbursts - FUSE

This project was a project to study the FUV spectra of two proto-typical dwarf novae, U Gem and SS Cygni, through an outburst cycle. The luminosity of the boundary layer in the two systems, as evidenced by earlier EUVE observations, is different in the two systems. Our intensive study of the two systems was intended to (1) probe the ionization and kinematic structure of the wind as a function of system brightness, (2) isolate the contributions of the disk to the FUV spectra, and (3) examine physical conditions and abundances of material just being accreted onto the disk from the secondary. The U Gem and SS Cyg observations took place in March and October 2000, respectively. The data obtained with FUSE was of excellent quality. Analysis of the both observations is now essentially complete, although some modeling of the SS Cyg spectra is ongoing, as we complete an ApJ manuscript on this object. Our main results for U Gem are as follows: The plateau spectra have continuum shapes and fluxes that are approximated by steady state accretion disk model spectra with an accretion rate 7x10(exp 9) Msolar/yr. The spectra also show numerous absorption lines of H I, He II, and 2-5 times ionized transitions of C, N, O, P, S, and Si. There are no emission features in the spectra, with the possible exception of a weak feature on the red wing of the 0 VI doublet. The absorption lines are narrow (FWHM approx. 50 km/s), too narrow to arise from the disk photosphere, and at low velocities (less than or equal to 700 km/s). The S VI and O VI doublets are optically thick. The absorption lines in the plateau spectra show orbital variability: in spectra obtained at orbital phases between 0.53 and 0.79, low-ionization absorption lines appear and the central depths of the preexisting lines increase. The increase in line absorption occurs at the same orbital phases as previously observed EUV and X-ray light-curve dips. If the absorbing material is in (near-) Keplerian rotation around the disk, it must be located at large disk radii. The final observation occurred when U Gem was about 2 mag from optical quiescence. The spectra are dominated by emission from an approx. 43,000 K, metal-enriched white dwarf (WD). The inferred radius of the WD is 4.95x10(exp 8) cm, close to that observed in quiescence. Allowing for a hot heated region on the surface of the WD improves the fit to the spectrum at short (less than 960 A) wavelengths. Our main results for SS Cyg are as follows: The first two of four observations of SS Cyg show disk dominated spectra with accretion rates of order 10(exp -8) Msolar/yr. Except for narrow interstellar features (atomic and molecular H), the lines are all broad consistent with a disk or wind origin. The O VI line in the spectra is mostly of wind origin as detailed modeling with our Monte Carlo code (developed in part using funds from this project) show. The continua from spectra in observations 3 and 4, observed during the decline phase, are not well fit with steady-state disks, and show considerable resemblance to quiescent spectra obtained with HUT. The most probable interpretation for the emission features seen in the spectrum in the last two observations is that they arise from a photo-illuminated choronosphere above the disk, rather than a wind.

Long, Knox↗
NASA NTRS2006

Generic Environment for Simulating Launch Operations

GEM-FLO (A Generic Simulation Environment for Modeling Future Launch Operations) is a computer program that facilitates creation of discrete-event simulation models of ground processes in which reusable or expendable launch vehicles (RLVs) are prepared for flight. GEM-FLO includes a component, developed in Visual Basic, that generates a graphical user interface (GUI) and a component, developed in the Arena simulation language, that creates a generic discrete-event simulation model. Through the GUI, GEM-FLO elicits RLV design information from the user. The design information can include information on flight hardware elements, resources, and ground processes. GEM-FLO translates the user s responses into mathematical variables and expressions that populate the generic simulation model. The variables and expressions can represent processing times, resource capacities, status variables, and other process parameters needed to configure a simulation model that reflects the ground processing flow and requirements of a specific RLV. Upon execution of the model, GEMFLO puts out data on many measures of performance, including the flight rate, turnaround time, and utilization of resources. This information can serve as the basis for determining whether design goals can be met, and for comparing characteristics of competing RLV designs

Steele, Martin↗
NASA NTRS2012

Experimenting with the GMAO 4D Data Assimilation

The Global Modeling and Assimilation Office (GMAO) has been working to promote its prototype four-dimensional variational (4DVAR) system to a version that can be exercised at operationally desirable configurations. Beyond a general circulation model (GeM) and an analysis system, traditional 4DV AR requires availability of tangent linear (TL) and adjoint (AD) models of the corresponding GeM. The GMAO prototype 4DVAR uses the finite-volume-based GEOS GeM and the Grid-point Statistical Interpolation (GSI) system for the first two, and TL and AD models derived ITom an early version of the finite-volume hydrodynamics that is scientifically equivalent to the present GEOS nonlinear GeM but computationally rather outdated. Specifically, the TL and AD models hydrodynamics uses a simple (I-dimensional) latitudinal MPI domain decomposition, which has consequent low scalability and prevents the prototype 4DV AR ITom being used in realistic applications. In the near future, GMAO will be upgrading its operational GEOS GCM (and assimilation system) to use a cubed-sphere-based hydrodynamics. This versions of the dynamics scales to thousands of processes and has led to a decision to re-derive the TL and AD models for this more modern dynamics, thus taking advantage of a two-dimensional MPI decomposition and improved scalability properties. With the aid of the Transformation of Algorithms in FORTRAN (l'AF) automatic adjoint generation tool and some hand-coding, a version of the cubed-sphere-based TL and AD models, with a simplified vertical diffusion scheme, is now available, enabling multiple configurations of standard implementations of 4DV AR in GEOS. Concurrent to this development, collaboration with the National Centers for Environmental Prediction (NCEP) and the Earth System Research Laboratory (ESRL) has allowed GMAO to implement a hybrid-ensemble capability within the GEOS data assimilation system. Both 3Dand 4D-ensemble capabilities are presently available thus allowing GMAO to now evaluate the performance and benefit of various ensemble and variational assimilation strategies. This presentation will cover the most recent developments taking place at GMAO and show results from various comparisons from traditional techniques to more recent ensemble-based ones.

Todling, R.↗
NASA NTRS2013

Lifetime Estimation of a Time Projection Chamber X-ray Polarimeter

The Gravity and Extreme Magnetism Small Explorer (GEMS) X-ray polarimeter Instrument (XPI) was designed to measure the polarization of 23 sources over the course of its 9 month mission. The XPI design consists of two telescopes each with a polarimeter assembly at the focus of a grazing incidence mirror. To make sensitive polarization measurements the GEMS Polarimeter Assembly (PA) employed a gas detection system based on a Time Projection Chamber (TPC) technique. Gas detectors are inherently at risk of degraded performance arising from contamination from outgassing of internal detector components or due to loss of gas. This paper describes the design and the materials used to build a prototype of the flight polarimeter with the required GEMS lifetime. We report the results from outgassing measurements of the polarimeter subassemblies and assemblies, enclosure seal tests, life tests, and performance tests that demonstrate that the GEMS lifetime is achievable. Finally we report performance measurements and the lifetime enhancement from the use of a getter.

Dimethyl ether↗
NASA NTRS2018

HST/GHRS Observations of Cool, Low-Gravity Stars. VI. Mass-Loss Rates and Wind Parameters for M Giants

The photon-scattering winds of M giants absorb parts of the chromospheric emission lines and produce self-reversed spectral features in high-resolution Hubble Space Telescope (HST)/GHRS spectra. These spectra provide an opportunity to assess fundamental parameters of the wind, including flow and turbulent velocities, the optical depth of the wind above the region of photon creation, and the star’s mass-loss rate. This paper is the last paper in the series “GHRS Observations of Cool, Low-Gravity Stars”; the last several have compared empirical measurements of spectral emission lines with models of the winds and mass loss of K giants and supergiants. We have used the Sobolev with Exact Integration radiative transfer code, along with simple models of the outer atmosphere and wind, to determine and compare the wind characteristics of the two M-giant stars, gamma Cru (M3.5III) and mu Gem (M3IIIab), with previously derived values for low-gravity K-stars. The analysis specifies the wind parameters and calculates line profiles for the Mg II resonance lines, in addition to a range of unblended Fe II lines. Our line sample covers a large range of wind opacities and, therefore, probes a range of heights in the atmosphere. Our results show that mu Gem has a slower and more turbulent wind than gamma Cru. Also, mu Gem has a weaker chromosphere, in terms of surface flux, with respect to gamma Cru. This suggests that mu Gem is more evolved than gamma Cru. Comparing the two M giants in this work with previously studied K-giant and supergiant stars (alpha Tau, gamma Dra, and lambda Vel) reveals that the M giants have slower winds than the earlier giants, but exhibit higher mass-loss rates. Our results are interpreted in the context of the winds being driven by Alfvén waves.

chromospheric emission lines↗