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At least 181 records · Page 10

Affordable Development and Optimization of CERMET Fuels for NTP Ground Testing

CERMET fuel materials for Nuclear Thermal Propulsion (NTP) are currently being developed at NASA's Marshall Space Flight Center. The work is part of NASA's Advanced Space Exploration Systems Nuclear Cryogenic Propulsion Stage (NCPS) Project. The goal of the FY12-14 project is to address critical NTP technology challenges and programmatic issues to establish confidence in the affordability and viability of an NTP system. A key enabling technology for an NCPS system is the fabrication of a stable high temperature nuclear fuel form. Although much of the technology was demonstrated during previous programs, there are currently no qualified fuel materials or processes. The work at MSFC is focused on developing critical materials and process technologies for manufacturing robust, full-scale CERMET fuels. Prototypical samples are being fabricated and tested in flowing hot hydrogen to understand processing and performance relationships. As part of this initial demonstration task, a final full scale element test will be performed to validate robust designs. The next phase of the project will focus on continued development and optimization of the fuel materials to enable future ground testing. The purpose of this paper is to provide a detailed overview of the CERMET fuel materials development plan. The overall CERMET fuel development path is shown in Figure 2. The activities begin prior to ATP for a ground reactor or engine system test and include materials and process optimization, hot hydrogen screening, material property testing, and irradiation testing. The goal of the development is to increase the maturity of the fuel form and reduce risk. One of the main accomplishmens of the current AES FY12-14 project was to develop dedicated laboratories at MSFC for the fabrication and testing of full length fuel elements. This capability will enable affordable, near term development and optimization of the CERMET fuels for future ground testing. Figure 2 provides a timeline of the development and optimization tasks for the AES FY15-17 follow on program.

Hickman, Robert R.↗

Unitized Regenerative Fuel Cell System Gas Storage/Radiator Development

The ancillary components for Unitized Regenerative Fuel Cell (URFC) Energy Storage System are being developed at the NASA Glenn Research Center. This URFC system is unique in that it uses the surface area of the hydrogen and oxygen storage tanks as radiating heat surfaces for overall thermal control of the system. The waste heat generated by the URFC stack during charging and discharging is transferred from the cell stack to the surface of each tank by loop heat pipes. The heat pipes are coiled around each tank and covered with a thin layer of thermally conductive layer of carbon composite. The thin layer of carbon composite acts as a fin structure that spreads the heat away from the heat pipe and across the entire tank surface. Two different sized commercial grade composite tanks were constructed with integral heat pipes and tested in a thermal vacuum chamber to examine the feasibility of using the storage tanks as system radiators. The storage radiators were subjected to different steady-state heat loads and varying heat load profiles. The surface emissivity and specific heat capacity of each tank were calculated. The results were incorporated into a model that simulates the performance of similar radiators using lightweight, space rated carbon composite tanks.

Jakupca, Ian↗

Proton Exchange Membrane (PEM) Fuel Cells for Space Applications

This presentation will provide a summary of the PEM fuel cell development at the National Aeronautics and Space Administration, Johnson Space Center (NASA, JSC) in support of future space applications. Fuel cells have been used for space power generation due to their high energy storage density for multi-day missions. The Shuttle currently utilizes the alkaline fuel cell technology, which has highly safe and reliable performance. However, the alkaline technology has a limited life due to the corrosion inherent to the alkaline technology. PEM fuel cells are under development by industry for transportation, residential and commercial stationary power applications. NASA is trying to incorporate some of this stack technology development in the PEM fuel cells for space. NASA has some unique design and performance parameters which make developing a PEM fuel cell system more challenging. Space fuel cell applications utilize oxygen, rather than air, which yields better performance but increases the hazard level. To reduce the quantity of reactants that need to be flown in space, NASA also utilizes water separation and reactant recirculation. Due to the hazards of utilizing active components for recirculation and water separation, NASA is trying to develop passive recirculation and water separation methods. However, the ability to develop recirculation components and water separators that are gravity-independent and successfully operate over the full range of power levels is one of the greatest challenges to developing a safe and reliable PEM fuel cell system. PEM stack, accessory component, and system tests that have been performed for space power applications will be discussed.

Bradley, Karla↗

Hydrogen-bromine fuel cell advance component development

Advanced cell component development is performed by NASA Lewis to achieve improved performance and longer life for the hydrogen-bromine fuel cells system. The state-of-the-art hydrogen-bromine system utilizes the solid polymer electrolyte (SPE) technology, similar to the SPE technology developed for the hydrogen-oxygen fuel cell system. These studies are directed at exploring the potential for this system by assessing and evaluating various types of materials for cell parts and electrode materials for Bromine-hydrogen bromine environment and fabricating experimental membrane/electrode-catalysts by chemical deposition.

Charleston, Joann↗

Unitized Regenerative Fuel Cell System Dryer-Humidifier Analytical Model Development

A Unitized Regenerative Fuel Cell (URFC) Energy Storage System is being developed at the NASA Glenn Research Center. This URFC system is unique in that it uses regenerative gas dryers/humidifiers that are mounted on the surface of the gas storage tanks that act as the radiators for thermal control of the URFC system. As the gas storage tanks cool down during URFC charging the regenerative gas dryers/humidifiers dry the hydrogen and oxygen gases produced by electrolysis. As the gas storage tanks heat up during URFC discharging, the regenerative gas dryers/humidifiers humidify the hydrogen and oxygen gases used by fuel cell. An analytical model was developed to simulate the URFC system's regenerative gas dryers/humidifiers. The model is in the form of an EXCEL@ worksheet that allows the investigation of the regenerative gas dryers/humidifier performance as a function of time and position within the regenerative gas dryers/humidifiers, as well as other key system variables. Finite Element Analysis (FEA) modeling of the regenerative gas dryers/humidifier and gas storage tank wall was also done to analyze spatial temperature distribution within the regenerative gas dryers/humidifiers and the localized tank wall. Test results obtained from the testing of the regenerative gas dryers/humidifiers in a thermal vacuum environment were used to corroborate the analyses.

Burke, Kenneth A.↗

The Three-D Flow Structures of Gas and Liquid Generated by a Spreading Flame Over Liquid Fuel

We developed a new experimental technique called: Combined laser sheet particle tracking (LSPT) and laser holographic interferometry (HI), which is capable of measuring the transient behavior of three dimensional structures of temperature and flow both in liquid and gas phases. We applied this technique to a pulsating flame spread over n-butanol. We found a twin vortex flow both on the liquid surface and deep in the liquid a few mm below the surface and a twin vortex flow in the gas phase. The first twin vortex flow at the liquid surface was observed previously by NASA Lewis researchers, while the last two observations are new. These observations revealed that the convective flow structure ahead of the flame leading edge is three dimensional in nature and the pulsating spread is controlled by the convective flow of both liquid and gas.

Tashtoush, G.↗

Unitized Regenerative Fuel Cell System Gas Dryer/Humidifier Analytical Model Development

A lightweight Unitized Regenerative Fuel Cell (URFC) Energy Storage System concept is being developed at the NASA Glenn Research Center (GRC). This Unitized Regenerative Fuel Cell System (URFCS) is unique in that it uses Regenerative Gas Dryers/Humidifiers (RGD/H) that are mounted on the surface of the gas storage tanks that act as the radiators for thermal control of the Unitized Regenerative Fuel Cell System (URFCS). As the gas storage tanks cool down during URFCS charging the RGD/H dry the hydrogen and oxygen gases produced by electrolysis. As the gas storage tanks heat up during URFCS discharging, the RGD/H humidify the hydrogen and oxygen gases used by the fuel cell. An analytical model was developed to simulate the URFCS RGD/H. The model is in the form of a Microsoft (registered trademark of Microsoft Corporation) Excel worksheet that allows the investigation of the RGD/H performance. Finite Element Analysis (FEA) modeling of the RGD/H and the gas storage tank wall was also done to analyze spatial temperature distribution within the RGD/H and the localized tank wall. Test results obtained from the testing of the RGD/H in a thermal vacuum environment were used to corroborate the analyses.

Burke, Kenneth A.↗

Interdisciplinary studies on the development of nuclear-fueled circulatory support systems: Collaboration of industry and academe

The purpose of this report is to acquaint the Houston community with specific areas of available technology, both public and private, to demonstrate to industry how this technology may be acquired and put to use to provide new and useful services for man. Much of the technology utilized in the development of nuclear-fueled circulatory support systems in our laboratories has evolved from industry, NASA, and AEC; our projects involve radiation biology, thermodynamics, energy transfers, hemodynamics, hematology, pathology, and surgery.

Norman, J. C.↗

Development of Advanced Hydrocarbon Fuels at Marshall Space Flight Center

This was a small-scale, hot-fire test series to make initial measurements of performance differences of five new liquid fuels relative to rocket propellant-1 (RP-1). The program was part of a high-energy-density materials development at Marshall Space Flight Center (MSFC), and the fuels tested were quadricyclane, 1-7 octodiyne, AFRL-1, biclopropylidene, and competitive impulse noncarcinogenic hypergol (CINCH) (di-methyl-aminoethyl-azide). All tests were conducted at MSFC. The first four fuels were provided by the U.S. Air Force Research Laboratory (AFRL), Edwards Air Force Base, CA. The U.S. Army, Redstone Arsenal, Huntsville, AL, provided the CINCH. The data recorded in all hot-fire tests were used to calculate specific impulse and characteristic exhaust velocity for each fuel, then compared to RP-1 at the same conditions. This was not an exhaustive study, comparing each fuel to RP-1 at an array of mixture ratios, nor did it include important fuel parameters, such as fuel handling or long-term storage. The test hardware was designed for liquid oxygen (lox)/RP-1, then modified for gaseous oxygen/RP-1 to avoid two-phase lox at very small flow rates. All fuels were tested using the same thruster/injector combination designed for RP-1. The results of this test will be used to determine which fuels will be tested in future test programs.

Bai, S. D.↗

Progress in electrochemical storage for battery systems

Efforts to improve electrochemical systems for space use relate to: (1) improvement of conventional systems; (2) development of fuel cells to practical power systems; and (3) a search for new systems that provide gains in energy density but offer comparable life and performance as conventional systems. Improvements in sealed conventional systems resulted in the areas of materials, charge control methods, cell operations and battery control, and specific process controls required during cell manufacture. Fuel-cell systems have been developed for spacecraft but the use of these power plants is limited. For present and planned flights, nickel-cadmium, silver-zinc, and silver-cadmium systems will be used. Improvements in nickel-cadmium batteries have been applied in medical and commercial areas.

Ford, F. E.↗

Coal liquefaction processes and development requirements analysis for synthetic fuels production

Focus of the study is on: (1) developing a technical and programmatic data base on direct and indirect liquefaction processes which have potential for commercialization during the 1980's and beyond, and (2) performing analyses to assess technology readiness and development trends, development requirements, commercial plant costs, and projected synthetic fuel costs. Numerous data sources and references were used as the basis for the analysis results and information presented.

Source record↗

Hybrid rocket fuel combustion and regression rate study

The objectives of this study are to develop hybrid fuels (1) with higher regression rates and reduced dependence on fuel grain geometry and (2) that maximize potential specific impulse using low-cost materials. A hybrid slab window motor system was developed to screen candidate fuels - their combustion behavior and regression rate. Combustion behavior diagnostics consisted of video and high speed motion pictures coverage. The mean fuel regression rates were determined by before and after measurements of the fuel slabs. The fuel for this initial investigation consisted of hydroxyl-terminated polybutadiene binder with coal and aluminum fillers. At low oxidizer flux levels (and corresponding fuel regression rates) the filled-binder fuels burn in a layered fashion, forming an aluminum containing binder/coal surface melt that, in turn, forms into filigrees or flakes that are stripped off by the crossflow. This melt process appears to diminish with increasing oxidizer flux level. Heat transfer by radiation is a significant contributor, producing the desired increase in magnitude and reduction in flow dependency (power law exponent) of the fuel regression rate.

Strand, L. D.↗

US/CIS integrated NTRE

The paper describes the Nuclear Thermal Energy (NTRE) engine, developed by taking advantage of mature fuel technology developed in the former Soviet Union, thus shortening the development schedule of this engine for moon and Mars explorations. The near-term NTRE engine has a number of features that provide safety, mission performance, cost, and risk benefits. These include: (1) high-temperature long-life CIS fuel, (2) high-pressure recuperated expander cycle, (3) assured restart, (4) long-life cooled nozzle with thin inner wall, (5) long-life turbopumps, (6) heat radiation and electrical power generation, and (7) component integration synergy. Diagrams of the reactor core, the recuperated bottoming cycle flow schematic, and the recuperated bottoming cycle engine schematic are presented.

Bulman, M. J.↗

Fuel Cell Research at NASA GRC

An overview of NASA GRC (Glenn Research Center) initiatives and challenges in fuel cell technology. The research and development of fuel cells and regenerative fuel cell systems for a wide variety of applications, including earth-based and planetary aircraft, spacecraft, planetary surface power, and terrestrial use are discussed.

Perez-Davis, Marla E.↗

Proton Exchange Membrane (PEM) Fuel Cell Status and Remaining Challenges for Manned Space-Flight Applications

The Fuel Cell has been used for manned space flight since the Gemini program. Its power output and water production capability over long durations for the mass and volume are critical for manned space-flight requirements. The alkaline fuel cell used on the Shuttle, while very reliable and capable for it s application, has operational sensitivities, limited life, and an expensive recycle cost. The PEM fuel cell offers many potential improvements in those areas. NASA Glenn Research Center is currently leading a PEM fuel cell development and test program intended to move the technology closer to the point required for manned space-flight consideration. This paper will address the advantages of PEM fuel cell technology and its potential for future space flight as compared to existing alkaline fuel cells. It will also cover the technical hurdles that must be overcome. In addition, a description of the NASA PEM fuel cell development program will be presented, and the current status of this effort discussed. The effort is a combination of stack and ancillary component hardware development, culminating in breadboard and engineering model unit assembly and test. Finally, a detailed roadmap for proceeding fiom engineering model hardware to qualification and flight hardware will be proposed. Innovative test engineering and potential payload manifesting may be required to actually validate/certify a PEM fuel cell for manned space flight.

Reaves, Will F.↗

New High-Temperature Membranes Developed for Proton Exchange Membrane Fuel Cells

Fuel cells are receiving a considerable amount of attention for potential use in a variety of areas, including the automotive industry, commercial power generation, and personal electronics. Research at the NASA Glenn Research Center has focused on the development of fuel cells for use in aerospace power systems for aircraft, unmanned air vehicles, and space transportation systems. These applications require fuel cells with higher power densities and better durability than what is required for nonaerospace uses. In addition, membrane cost is a concern for any fuel cell application. The most widely used membrane materials for proton exchange membrane (PEM) fuel cells are based on sulfonated perfluorinated polyethers, typically Nafion 117, Flemion, or Aciplex. However, these polymers are costly and do not function well at temperatures above 80 C. At higher temperatures, conventional membrane materials dry out and lose their ability to conduct protons, essential for the operation of the fuel cell. Increasing the operating temperature of PEM fuel cells from 80 to 120 C would significantly increase their power densities and enhance their durability by reducing the susceptibility of the electrode catalysts to carbon monoxide poisoning. Glenn's Polymers Branch has focused on developing new, low-cost membranes that can operate at these higher temperatures. A new series of organically modified siloxane (ORMOSIL) polymers were synthesized for use as membrane materials in a high-temperature PEM fuel cell. These polymers have an organic portion that can allow protons to transport through the polymer film and a cross-linked silica network that gives the polymers dimensional stability. These flexible xerogel polymer films are thermally stable, with decomposition onset as high as 380 C. Two types of proton-conducting ORMOSIL films have been produced: (1) NASA-A, which can coordinate many highly acid inorganic salts that facilitate proton conduction and (2) NASA-B, which has been produced and which incorporates strongly acidic (proton donating) functional groups into the polymer backbone. Both of these polymer films have demonstrated significantly higher proton conductivity than Nafion at elevated temperatures and low relative humidities. An added advantage is that these polymers are very inexpensive to produce because their starting materials are commodity chemicals that are commercially available in large volumes.

Kinder, James D.↗