SEARCH · Engineering Papers

Results for “FeO”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10

All sources NASA NTRS DOE OSTI

NASA NTRS1977

Internal structure and properties of Mars

Theoretical physical models of the Martian interior are presented in the light of recent and revised data and constraints. These models include thermal evolution, densities, and seismic-wave velocities. The interior of Mars appears to be earthlike in many respects. Although thermal models indicate that Mars has passed its peak of evolution, it may still have an asthenosphere and may be moderately active tectonically. Mars has an Fe-FeS core with a radius of 1500-2000 km. The mantle is enriched in FeO with an olivine composition of about Fo75. Theoretically determined seismic-wave velocities are relatively well constrained in the mantle, with upper-mantle P-wave velocities ranging from 7.64 to 7.80 km/sec. However, there are wide variations in P-wave velocity in the core, dependent on composition. The shadow zone due to the core is larger than earth's.

Johnston, D. H.↗

NASA NTRS1977

Formation and composition of the moon

Many of the properties of the Moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr, and the REE and the depletion in Fe, Rb, K, Na, and other volatiles can be understood if the Moon represents a high-temperature condensate from the solar nebula. Thermodynamic calculations show that Ca-, Al-, and Ti-rich compounds condense first in a cooling nebula. The initial high temperature mineralogy is gehlenite, spinel, perovskite, Ca-Al-rich pyroxenes, and anorthite. Inclusions in carbonaceous chondrites such as the Allende meteorite are composed primarily of these minerals and, in addition, are highly enriched in refractories such as REE relative to carbonaceous chondrites. These inclusions can yield basalt and anorthosite in the proportions required to eliminate the europium anomaly, leaving a residual spinel-melilite interior. A deep interior high in Ca-Al does not imply an unacceptable mean density or moment of inertia for the Moon. The inferred high-U content of the lunar interior, both from the Allende analog and the high heat flow, indicates a high-temperature interior. The model is consistent with extensive early melting, with shallow melting at 3 AE, and with presently high deep internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C.

Anderson, D. L.↗

NASA NTRS1977

Rare earth and trace element geochemistry of a fragment of Jurassic seafloor, Point Sal, California

Rocks from an ophiolite suite once on the seafloor were analyzed for rare earth elements (REE), Sc, Co, Na2O, Cr, Zn and FeO. Strontium isotope exchange noted in some of the lavas is attributed to basalt-seawater interaction; the Ce abundance in smectite- and zeolite-bearing lavas may also be due to prolonged exposure to seawater. The higher grades of metamorphic rock, however, show no variation from the usual flat or slightly light REE depleted profiles. Plutonic igneous rock, all light REE depleted, have total REE abundances varying by a factor of 100 between the dunites and diorites. In order of decreasing REE abundance are hornblende, clinopyroxene, plagioclase, orthopyroxene and olivine. Calculations of REE contents of liquids in equilibrium with early cumulative clinopyroxenes suggest that the parent to the stratiform sequence was more depleted in light REE than the parent to the lava pile.

Menzies, M.↗

NASA NTRS1977

High-silica glass inclusions in olivine of Luna-24 samples

Optical examination of nine polished grain mounts of Luna-24 drill-core material (0.09-0.50 mm size) revealed melt inclusions in olivine crystals. Two inclusions consist of clear glass with exceptionally high Si, yet contain no visible daughter minerals and have had no reaction effects with the olivine walls. Their compositions (one has SiO2 93.8, Al2O3 1.51, FeO 2.32, MgO 1.61, CaO 0.06, Na2O less than 0.05, K2O 0.11, total 99.41%; the other is similar) are unique and quite unlike the high-Si high-K melt of granitic composition that is found as inclusions in late-stage minerals of these (and the Apollo) samples, from silicate liquid immiscibility. The host olivines are Fo73 and Fo51. The origin of the melt in the inclusions and the lack of reaction effects are perplexing unsolved problems.

Roedder, E.↗

NASA NTRS1978

The mantle of Mars - Some possible geological implications of its high density

The high density of the Martian mantle probably implies an iron-rich composition expressed by a higher concentration of FeO than that in the earth's mantle. Examination of high-pressure mineralogies suggests that the model Martian mantle has an oxide-garnet wehrlite phase assemblage. This mantle model would be likely to yield ultrabasic (ferrobasaltic) melts of very low viscosity. The prevalence of low-viscosity material is consistent with large eruption rate and copious lava flow on the planet. Furthermore, ferro-kimberlite volcanic ash may be an abundant constituent in the Martian soil, especially if there was much volatile material within the early accreting Mars.

Mcgetchin, T. R.↗

NASA NTRS1977

Comparison of orbital chemistry with crustal thickness and lunar sample chemistry

A correlation between orbital chemistry (FeO, Al2O3, Mg/Al, MgO/FeO, Th) and the lunar crustal thickness is examined. The correlation suggests either lack of complete homogenization by lateral or vertical mixing, or lateral variation in the differentiation process. In addition, links between orbital chemistry and lunar sample chemistry are investigated. In regions with crustal thickness between 100 and 110 km, gabbroic anorthosites are very abundant, while in regions with crustal thickness of about 80 km anorthositic gabbros are frequent. Special attention is given to the distribution of low-potassium Fra Mauro basalt, found in high concentrations in regions with 50 to 60 km crustal thickness.

Schonfeld, E.↗

NASA NTRS1977

Applications of dynamic crystallization studies - Lunar olivine-normative basalts

Dynamic crystallization studies were performed on two synthetic glasses similar in composition to the mare olivine-normative basalt samples 12009 and 15555. The effects of viscosity (primarily a function of FeO) and the initial temperature of cooling on mineral chemistry, texture, and temperature of appearance of phases were investigated. Olivine compositions seem to indicate that, for the two types of melt cooled at the same rate, there are no significant differences in the degree of undercooling at which olivine nucleates, but it is found that olivine-nucleated densities differ. The cooling rate of 15555 is estimated. Since the temperature at which cooling is initiated affects texture, mineral chemistry, and temperature of appearance of phases so greatly, caution is recommended in the application of experimental data to natural rock systems.

Bianco, A. S.↗

NASA NTRS1975

On high-alumina mare basalts

Aluminous mare basalts have been found at several lunar sites, although they are not abundant. A group of crystalline clasts in breccia 14063 are also aluminous mare basalts with higher TiO2, Na2O, Mg/Fe ratio and lower FeO than other aluminous mare basalts. Composition of ilmenite clinopyroxene, and plagioclase confirm that crystallization took place from a melt with high TiO2 and Mg/Fe. A review of ages and siderophile trace-element abundances for aluminous mare basalts, suggests they are not hybrid rocks produced by melting of a mare + terra rock mix, but are pristine igneous melts from the lunar interior. Consideration of rare-earth element abundances indicate the source for aluminous mare basalts is pyroxenitic, with variable clinopyroxene/orthopyroxene ratio, and is not significantly different from the sources(s) of normal mare basalts.

Ridley, W. I.↗

NASA NTRS1975

Pyroxene-phyric basalt 15075 - Petrography and petrogenesis

Sample 15075 is a holocrystalline gabbroic rock that can be classified as a coarse-grained variant of the Apollo 15 pyroxene-phyric basalt group. The phenocrysts of pyroxene show spectacular compositional zoning, from hypersthene-pigeonite, through subcalcic augite, to 'ferropyroxenes.' The predominant trend of differentiation is one of Fe enrichment, which is also reflected in the progressive increase of FeO content in the normally zoned plagioclase. As in other samples of pyroxene-phyric basalts, the plagioclase in 15075 did not crystallize until the pyroxenes had reached a subcalcic augite composition; the onset of plagioclase and Fe-rich pyroxene coprecipitation is marked by sharp discontinuity in the Ca/(Fe + Mg) and Ti/Al trends of the pyroxene.

Taylor, L. A.↗

NASA NTRS1975

Evolution of the moon between 4.6 and 3.3 AE

A model of lunar evolution is proposed. At 4.6 AE an outer shell 60-100 km thick of an initially homogeneous moon was totally molten following accretion. 'Highland basalt' represents remnants of the chilled crust of this molten layer and, therefore, the mean lunar composition. Melt from the partially molten region below the outer shell intruded into it, enriching it in FeO, SiO2, radiogenic, and trivalent trace LIL (large ion lithop) elements. Fractional crystallization of the outer shell produced toward its base a mafic cumulate zone less than 40 km thick, the upper 60 km being anorthosite. The radiogenic elements concentrated together with dense residual melt in the upper parts pf the mafic cumulate zone. Between 4.6 and 4.3 AE a second differentiation led to localized enrichment from below of radiogenic elements in the plagioclase-rich, high-Mg/Mg + Fe residuum below the outer 100-km-thick shell. Melting at these enriched sites at about 4.0 AE produced to KREEP basalts. Later melting at sites of radiogenic element enrichment in the outer 100-km-thick shell produced the mare basalts.

Hollister, L. S.↗

NASA NTRS1978

The Yamato-74659 ureilite and some new findings on the Yamato achondritic pyroxenes

A cube-like fragment with an approximately 4 mm edge was taken from the Yamato-74659 meteorite for the mineralogical and crystallographic examination discussed in the present paper. An analysis of powdered fragments by a standard wet chemical method showed that it matched to weathered ureilite. The chemical composition was found to differ from other ureilites in that the FeO content (8.83 wt%) is the lowest among known ureilites and it is richer in SiO2 contents (42.91 wt%).

Takeda, H.↗

NASA NTRS1978

VLT mare basalts - Impact mixing, parent magma types, and petrogenesis

Available major-element compositions of very low-Ti (VLT) mare basalt lithic fragments and glasses are examined. Many of the lithic fragments contain relic mineral and sometimes lithic clasts, which suggests that many samples of VLT mare basalt glasses and lithic fragments were formed by impact melting. Therefore, some may have compositions that represent mixtures of VLT mare basalts and other types of rocks, not authentic igneous rock compositions. In spite of this problem, a number of possible parent magma compositions are identified. These hypothetical magmas vary in CaO/Al2O3(0.9-1.1), FeO (17 to 24 wt. %), Fe/(Fe + Mg) (0.34-0.46), and K2O (0-0.2 wt. %). Each may have differentiated to produce a wide variety of derivative magmas. Calculations involving olivine fractionation from the proposed parent magmas indicate the Luna 24 ferrobasalts might have formed from a magma whose composition is similar to that of a group of high-MgO (about 13-14 wt. %) Apollo 17 VLT mare basalt glasses.

Taylor, G. J.↗

NASA NTRS1978

Trace element composition of Luna 24 Crisium VLT basalt

The origins of the individual particles analyzed from the Luna 24 core and the information they provide on the trace-element composition of Mare Crisium basalt are considered. Previous analyses of several Luna 24 soil fragments are reviewed. It is concluded that: (1) the average trace-element concentrations for 12 VLT basalt fragments are the best available estimates for bulk samples of Crisium VLT basalt; (2) there is weak evidence that the average Crisium basalt might have a small positive Eu anomaly relative to chondritic matter; (3) the soils contain components from sources other than the Crisium VLT basalt; and (4) there is no convincing information in concentrations of rare-earth elements, Co, Sc, FeO, or Na2O among the analyzed fragments to indicate more than one parent basalt.

Haskin, L. A.↗

NASA NTRS1979

Mesosiderites and howardites - Igneous formation and possible genetic relationships

Neutron activation data are presented for major, minor, and trace elements in whole rock howardites and silicates from mesosiderites. Compositions of howardites and mesosiderites are similar and intermediate between those of eucrites and diogenites. It is indicated that mesosiderites have a higher normative silica component than howardites. It appears that this results partly from a higher content of a highly evolved igneous component and partly from in situ reduction of FeO to Fe followed by magnetic separation of metal prior to analysis. It is shown that light rare earth elements are enriched in some mesosiderites.

Mittlefehldt, D. W.↗

NASA NTRS1978

Depositional and surface exposure history of the Shorty Crater core 74001/2 - FMR and magnetic studies

Surface exposure (maturity) indices and concentrations of FeO and metallic iron were determined at 0.5-cm intervals of the Apollo 17 core section, which sampled a pyroclastic deposit on the rim of Shorty Crater. The determinations showed that all of the soil in the core is extremely immature. An exposure history of the core is proposed: accumulation (about 3.6 billion years ago), shallow burial (during the first 20 million years), deep burial (till about 10-15 million years ago), followed by excavation (10-15 million years ago), and in situ reworking (till the present).

Morris, R. V.↗

NASA NTRS1978

The surface exposure /maturity/ of lunar soils - Some concepts and I sub s/FeO compilation

Surface exposure (or, equivalently, maturity) indices of lunar soils are a measure of residence time of soil in the upper one millimeter of the regolith. Several concepts concerning the use of and terminology associated with maturity indices are discussed. For reasons which include its generally-applicable nature and large data base, the ferromagnetic resonance (FMR) surface exposure (maturity) index I sub s/FeO (the ratio of the value of the intensity in arbitrary units of the FMR resonance at g equal to about 2.1 to the FeO concentration) is particularly suitable and useful. A compilation of values of I sub s/FeO for 164 Apollo surface and trench soils and six Luna 24 core soils is given.

Morris, R. V.↗

NASA NTRS1978

Mare basalt types on the front side of the moon - A summary of spectral reflectance data

A unit map of nearside basalt types has been prepared from all telescopic spectral reflectance data currently available for lunar soils. Four parameters were chosen (UV/VIS ratio, albedo, 1 micron band strength, 2 micron band strength) to distinguish and map each of 13 mare basalt types and three additional volcanic groups. Multispectral imagery and albedo maps were used to define unit boundaries while spectra were used to examine the 1 and 2 micron bands and calibrate and quantify the multispectral images. Although the volume of each basalt type is not known, it is clear from the unit map that only 1/3 to 1/2 of the surface basalt types are likely to be represented in the returned lunar samples. For mature lunar soils a single parameter alone does not provide chemical information, but when the four are used together, TiO2 and in some cases FeO can be estimated. Further study of the mineralogy of unsampled lunar basalts requires precise spectra to 2.5 microns with higher spectra and spatial resolution.

Pieters, C. M.↗

NASA NTRS1980

Predicting major element mineral/melt equilibria - A statistical approach

Empirical equations have been developed for calculating the mole fractions of NaO0.5, MgO, AlO1.5, SiO2, KO0.5, CaO, TiO2, and FeO in a solid phase of initially unknown identity given only the composition of the coexisting silicate melt. The approach involves a linear multivariate regression analysis in which solid composition is expressed as a Taylor series expansion of the liquid compositions. An internally consistent precision of approximately 0.94 is obtained, that is, the nature of the liquidus phase in the input data set can be correctly predicted for approximately 94% of the entries. The composition of the liquidus phase may be calculated to better than 5 mol % absolute. An important feature of this 'generalized solid' model is its reversibility; that is, the dependent and independent variables in the linear multivariate regression may be inverted to permit prediction of the composition of a silicate liquid produced by equilibrium partial melting of a polymineralic source assemblage.

Hostetler, C. J.↗