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At least 181 records · Page 10

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NASA NTRS1985

The parental magma for some rocks from the Norite 1 subzone of the Stillwater Complex - A lunar analog study

Single samples from three successive homogeneous but contrasting layers (anorthosite, anorthositic norite, and norite) in the Stillwater Complex Norite 1 subzone were subjected to detailed petrographic and major and trace element chemical analyses. The petrography and the element chemistry of the three layers are found to be generally consistent with formation from a common magma, although a simple model of liquidus phases and trapped magma is not quite consistent with petrography and chemistry. Changes of oxidation level from layer to layer are indicated by both iron in plagioclase and by the distribution coefficient for Eu required for compatibility with a common parent. Such oxidation changes can explain qualitatively the Mg/Fe variation otherwise attributed to trapped liquid. The data demonstrate that for individual lunar highlands igneous rocks, a general picture of the parent magma can be derived, but detailed petrochemical comparisons using a simple trapped liquid model might deny a common parentage for two samples when such in fact existed.

Ryder, G.↗

NASA NTRS1985

Error analyses for a gravity gradiometer mission

This paper addresses the usefulness of an orbiting gravity gradiometer as a sensor for mapping the fine structure of the earth gravity field. The exact knowledge of this field is essential for studies of the solid earth and the dynamics of the oceans. Although the earth gravity tensor, measured by a gradiometer assembly, has nine components, only five components are independent. This latter fact is as a consequence of the symmetry and conservative nature of the earth's gravity field. The most dominant component is the radial one. The error analyses considered here are therefore based only upon a single axis gradiometer sensing this radial component. The expected global gravity and geoid errors for a 50 x 50-km (1/2 x 1/2 deg) area utilizing a spaceborne gradiometer with a precision of 0.001 EU in a 160-km circular polar orbit are about 3 mGAL and 5 cm, respectively.

Kahn, W. D.↗

NASA NTRS1985

Chondrules in the Qingzhen type-3 enstatite chondrite Possible precursor components and comparison to ordinary chondrite chondrules

The mineral composition of chondrules from a fragment of Qingzhen (EH3) fall was analyzed by neutron activation method. Unlike the ordinary chondrite (OC) chondrules (Gooding and Keil, 1981), the Qingzhen radial pyroxene (RP) and porphyritic pyroxene (PP) chondrules have similar bulk compositions. Porphyritic olivine-pyroxene (POP) chondrules are richer than PP and RP chondrules in refractory lithophiles and siderophiles. Elements in each of the following sets intercorrelate significantly: (1) Fe-Co-Ni-Ir-Au, probably derived from a metal component; (2) Ca-Eu-Se, which suggests an oldhamite-rich precursor; (3) Al-Sc-Hf, occurring in high concentrations in POP chondrules, this set suggesting the existence of a refractory lithophile-rich and olivine-rich component; (4) Na REE; and (5) Cl-Br. Sets (2) and (4) were not precursors of OC. The interelement ratios of refractory lithophiles such as Ca, Al, Ti, Sc, and REE are similar to CI ratios, suggesting that they originated in the earliest phases as silicates, which were sulfurized before chondrule formation.

Grossman, J. N.↗

NASA NTRS1985

Shock modelling in transonic and supersonic flow

Numerical simulation studies of problems in transonic flow are conducted in connection with the design of aircraft flying near the speed of sound, while recently there has also been a great deal of interest in supersonic and hypersonic flow calculations. Three important models for inviscid compressible gasdynamics are utilized in the study of these flow problems, taking into account the transonic small disturbance equation (TSD), the transonic full potential equation (FP), and the full Euler equations for compressible gasdynamics (EU). The present paper has the objective to provide a description of shock capturing methods recently developed for each model. The design principles behind the algorithms are also examined, giving attention to consistency, conservative form, monotone and sharp discrete shocks, and a bound on the variation, which prevents spurious oscillations.

Osher, S.↗

NASA NTRS1986

A potpourri of pristine moon rocks, including a VHK mare basalt and a unique, augite-rich Apollo 17 anorthosite

The anorthosite fragment, 76504,18, the first of the Apollo 17's pristine anorthosites, was found to have: (1) a higher ratio of high-Ca pyroxine to low-Ca pyroxene, (2) higher Na in its plagioclase, (3) higher contents of incompatible elements, and (4) a higher Eu/Al ratio in comparison to ferroan anorthosites. With a parent melt having a negative Eu anomaly, 76504,18 closely resembles a typical mare basalt. This anorthosite was among the latest to be formed by plagioclase flotation above a primordial magmasphere; typical mare basalt regions accumulated at about the same time or even earlier. Another fragment 14181c, a very high potassium basalt, was studied and found to be similar to typical Apollo 14 mare basalt though it has a K/La ratio of 1050. It is suggested that this lithology formed after a normal Apollo 14 mare basaltic melt partially assimilated granite. New data for siderphile elements in Apollo 12 mare basalts indicate that only the lowest of earlier data are trustworthy as being free of laboratory contamination.

Warren, P. H.↗

NASA NTRS1986

Growth-induced anisotropy in bismuth - Rare-earth iron garnets

The bismuth-doped rare-earth iron garnets, (R3-x-yBixPby)Fe5O12 (Bi:RIG, R = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y), were prepared under constant growth conditions to investigate the influence of ionic species on the bismuth-based growth-induced uniaxial anisotropy K(u) exp g. The effect of ionic species on growth-induced anisotropy in Bi:RIG was not consistent with the ionic size model of site ordering. In particular, Bi:SmIG, Bi:EuIG, and Bi:TbIG displayed high growth-induced anisotropies, up to 331,000 erg/cu cm at room temperature for x of about 0.5. The temperature dependence of these K(u) exp gs was somewhat higher than that of the well studied Bi:YIG. The site ordering of Bi can be modeled by assuming that small, low-oxygen-coordination BiOw exp +3-2 w melt complexes have a strong site selectivity for small, high-oxygen coordination sites at the growth interface.

Fratello, V. J.↗

NASA NTRS1986

Rare earth element patterns in Archean high-grade metasediments and their tectonic significance

REE data on metasedimentary rocks from two different types of high-grade Archean terrains are presented and analyzed. The value of REEs as indicators of crustal evolution is explained; the three geologic settings (in North America, Southern Africa, and Australia) from which the samples were obtained are described; and the data are presented in extensive tables and graphs and discussed in terms of metamorphic effects, the role of accessory phases, provenance, and tectonic implications (recycling, the previous extent of high-grade terrains, and a model of Archean crustal growth). The diversity of REE patterns in shallow-shelf metasediments is attributed to local provenance, while the Eu-depleted post-Archean patterns are associated with K-rich plutons from small, stable early Archean terrains.

Taylor, Stuart Ross↗

NASA NTRS1987

Chemical composition and origin of Apollo 15 impact melts

Fourteen Apollo 15 impact melt rocks were analyzed for major (fused bead microprobe) and trace element (INAA) abundances, and the compositions of these Apennine Front rocks were compared with samples from other landing sites. The rocks show a wide range in trace element abundances, although all but one have a typical KREEP incompatible element pattern and have low-K Fra Mauro basaltic or medium-K Fra Mauro basaltic compositions. The melt chemistries appear to form five groups (labeled A to E in order of decreasing incompatible elements), with the compositions unlike nearly all other impact melts and regoliths from highland sites. All groups except Group A may represent single impact events (either Imbrian or post-Imbrian). One unique sample has a non-KREEP incompatible element pattern, with low abundances and a positive Eu anomaly. Its target is believed to be either a pre-Imbrian melt or exotic.

Ryder, Graham↗

NASA NTRS1988

Does subduction zone magmatism produce average continental crust

The question of whether present day subduction zone magmatism produces material of average continental crust composition, which perhaps most would agree is andesitic, is addressed. It was argued that modern andesitic to dacitic rocks in Andean-type settings are produced by plagioclase fractionation of mantle derived basalts, leaving a complementary residue with low Rb/Sr and a positive Eu anomaly. This residue must be removed, for example by delamination, if the average crust produced in these settings is andesitic. The author argued against this, pointing out the absence of evidence for such a signature in the mantle. Either the average crust is not andesitic, a conclusion the author was not entirely comfortable with, or other crust forming processes must be sought. One possibility is that during the Archean, direct slab melting of basaltic or eclogitic oceanic crust produced felsic melts, which together with about 65 percent mafic material, yielded an average crust of andesitic composition.

Ellam, R. M.↗

NASA NTRS1988

The early archaean crustal history of West Greenland as recorded by detrital zircons

The isotope systematics of some of the oldest samples on Earth from both Greenland and Australia was discussed. The antiquity was confirmed of the 4.1 to 4.2 Ga zircons from Western Australia; the model Lu-Hf age of these zircons, as measured with the ANU ion probe is 4.14 + or - 0.24 Ga, although the oldest preserved rock units there are anorthosites with a Lu-Hf model age of about 3.73 Ga. U-Pb ion probe ages of detrital zircons ranging between 2.87 and 3.89 Ga from an Akilia association quartzite was reported, whose age of deposition is probably around 3.8 Ga. It was argued that the younger age in this range are discordant because of late Pb-loss, probably associated with a high grade metamorphic event at about 3.6 Ga. It was also argued that the earliest crust in West Greenland and elsewhere is about 3.9 Ga, but in some places, such as Western Australia, crustal evolution took place much earlier, perhaps starting as far back as 4.3 Ga. This would account for the presence in that terrane of abundant K rich granitoid, the paucity of tonalitic and trondhjemitic materials, and the existence of Eu anomalies in early Archean sediments.

Kinny, P. D.↗

NASA NTRS1988

Recent developments in gravity gradiometry from the Space-Shuttle-borne tethered satellite system

This paper describes the current development of a noncryogenic gravity gradiometer for future use on board the tethered satellite system (TSS). The paper also proposes a way of testing a single-axis prototype of such an instrument that makes use of the free-fall technique in vacuum. This gravity gradiometer has a design sensitivity of the order of 0.01 EU in 10-s integration time. Because of the small size and light weight, a noncryogenic gravity gradiometer is a valid candidate to fit the limited accommodation capability of the TSS deployed from the Shuttle and maintained, for several days, at an altitude of 120-130 km. This unique capability improves the resolution and accuracy achievable in reconstructing the earth gravity field, in particular at short wavelengths. A preliminary analysis of the dynamics of the TSS satellite indicates the potential of such satellite as a low-altitude research platform for gravity gradiometry.

Lorenzini, Enrico C.↗

NASA NTRS1988

Temperature and composition dependencies of trace element partitioning - Olivine/melt and low-Ca pyroxene/melt

This paper presents a systematic thermodynamic analysis of the effects of temperature and composition on olivine/melt and low-Ca pyroxene/melt partitioning. Experiments were conducted in several synthetic basalts with a wide range of Fe/Mg, determining partition coefficients for Eu, Ca, Mn, Fe, Ni, Sm, Cd, Y, Yb, Sc, Al, Zr, and Ti and modeling accurately the changes in free energy for trace element exchange between crystal and melt as functions of the trace element size and charge. On the basis of this model, partition coefficients for olivine/melt and low-Ca pyroxene/melt can be predicted for a wide range of elements over a variety of basaltic bulk compositions and temperatures. Moreover, variations in partition coeffeicients during crystallization or melting can be modeled on the basis of changes in temperature and major element chemistry.

Colson, R. O.↗

NASA NTRS1988

Partitioning of rare earth elements between hibonite and melt and implications for nebular condensation of the rare earth elements

The effect of oxygen fugacity on the partitioning of REEs between hibonite and silicate melt is investigated in hibonite-growth experiments at 1470 C. The experimental procedures and apparatus are described, and the results are presented in extensive tables and graphs and characterized in detail. The absolute activity coefficients in hibonite are estimated as 330 for La, 1200 for Eu(3+), and 24,000 for Yb. It is inferred that ideal solution behavior cannot be assumed when calculating REE condensation temperatures for (Ca, Al)-rich inclusions in carbonaceous chondrites.

Drake, Michael J.↗

NASA NTRS1988

Chemistry of the older supracrustals of Archaean age around Sargur

In the Archaeans of the Karnataka craton two stratigraphically distinct volcano-sedimentary sequences occur, namely the older supracrustals of the Sargur type and the younger Dharwar greenstones. The dividing line between these is the 3 by old component of the Peninsular gneiss. The trace and rare earth element chemistry of the Sargur metasediments show, in general, marked similarity to the Archaean sediments. The significant departures are in the nickel and chromium abundances. The REE data of the Sargur pelites of the Terakanambi region represented by Silli-gt-bio-feldspar schists and paragneisses show LREE enrichment and flat to depleted HREE pattern. Banded iron formations have very low REE abundance. They show slightly enriched LREE and flat to depleted HREE pattern. REE abundance in the Mn-horizons is comparable to that of the Archaean sediments. Mn-horizons show enriched LREE and flat HREE with anamolous Eu. REE patterns of these bands is well evolved and has similarities with PAAS.

Janardhan, A. S.↗

NASA NTRS1989

Abundances of the elements - Meteoritic and solar

New abundance tables have been compiled for C1 chondrites and the solar photosphere and corona, based on a critical review of the literature to mid-1988. The meteorite data are generally accurate to + or - 5-10 percent. Significant discrepancies between the sun and meteorites occur only for Fe, Mn, Ge, Pb, and W; other well-determined elements agree to + or - 9 percent on the average. There is no evidence for group fractionations in C1 chondrites of cosmochemically similar elements (refractories, siderophiles, volatiles, etc.), but a selective fractionation of Fe cannot be ruled out. Abundances of odd-A nuclides between A = 65 and 209 show a generally smooth trend, with elemental abundances conforming to the slope defined by isotopic abundances. Significant irregularities occur in the Nd-Sm-Eu region, however, suggesting that the abundance curve is dependably smooth only down to about 20 percent level.

Anders, Edward↗

NASA NTRS1989

Allan Hills 84025 - The second brachinite, far more differentiated than brachina, and an ultramafic achondritic clast from L chondrite Yamato 75097

New bulk-compositional and petrographic data tend to confirm that dunitic-wehrlitic meteorite ALH84025 is a second brachinite. It is suggested here that ALH84025 originated as an olivine heteradcumulate, whereas Brachina, or ALH84025, originated as an olivine orthocumulate. The tendency for pyroxenes among brachinites to be high-Ca may be a consequence of a relatively low MgO/FeO ratio, and/or high Na/Ca and K/Ca ratios in the bulk parent body. New data for a 2.5-cm dunite-melatroctolite clast from L6 chondrite Y75097 are reported. This clast has experience depletion of middle REE, except for a large (+) Eu anomaly. The clast as a whole is enriched in phosphates, but almost exclusively in its least-metamorphosed 'core' portion, whereas the analyzed samples represent phosphate-poor portions. It is suggested that this bizarre assemblage probably originated as an achondrite containing cumulus olivine, plagioclase, and phosphate, not necessarily all from a single igneous source rock.

Warren, P. H.↗

NASA NTRS1989

The evolution of complex type B Allende inclusion - An ion microprobe trace element study

Results are presented of a detailed trace-element and isotopic analyses of the constituent phases in each of the major textural parts (mantle, core, and islands) of a Type B refractory inclusion, the USNM 5241 inclusion from Allende, first described by El Goresy et al. (1985). The REE data on 5241 were found to be largely consistent with a model in which the mantle and the core of 5241 formed sequentially out of a single melt by fractional crystallization. The numerical models of REE evolution in the 5241 melt, especially that of Eu, require that a significant mass of spinel-free island material was assimilated into the evolving melt during the last half of the solidification history of 5241. The trace element results pbtained thus strongly support the interpretation of El Goresy et al. (1985) that the spinel-free islands in the 5241 are trapped xenoliths.

Macpherson, Glenn J.↗

NASA NTRS1990

Structure and superconducting properties of ((Ln(1-x)Ln*(x) 1/2 (Ba(1-y)Sr(y) 1/3 Ce 1/6) 8Cu6O(z)

A variety of new oxide superconductors were prepared. The crystallographic structures of the oxides were all tetragonal and of the (Ln(+), Ce)4(Ln(+),Ba)4Cu6Oz (Ln(+) = Nd, Sm or Eu) type which had been previously discovered by Akimitsu et al. As the Sr content, y, increased when Ln = Ln(excited state) = Nd, the oxygen content, z, monotonically increased and the superconducting transition temperature, T(sub c), varied exhibiting a maximum. When z was controlled directly by means of high oxygen pressure sintering techniques, T(sub c) was changed accordingly. T(sub c's) of samples with different combinations of Ln and Ln(excited state) and different values of x and y were found to depend on the magnitude of the bond valence sum for a Cu atom located in the bottom plane of the Cu-O5 pyramid. Transport and magnetization measurements were carried out to investigate the magnetic field dependence of superconducting properties and to determine the phenomenological parameters. The Hall coefficients were positive below room temperature and varied yielding a maximum with respect to temperature.

Yamauchi, H.↗