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NASA NTRS1989

Lunar meteorites - Siderophile element contents, and implications for the composition and origin of the moon

Data for 10 siderophile elements in all of the known lunar meteorites except for Y793274 are reported. Bulk compositional data for Ni, Ge, Cd, Re, Os, Ir, and Au were obtained from radiochemical neutron activation analysis (Warren et al., 1986). Data for Fe, Co, and Zn, and additional data for Ni, Ir, and Au were obtained by instrumental neutron activation analysis (Kallemeyn et al., 1988). Except for the case of Au in Y791197, there was good agreement between the results obtained by the two methods. The differences observed between the lunar-meteoritic regolith samples and central nearside highlands regolith samples are discussed.

Warren, Paul H.↗

NASA NTRS1989

A test of the smoothness of the elemental abundances of carbonaceous chondrites

Analyses of several carbonaceous chondrites (including the Orgueil samples 626, 629, and 630; and Ivuna samples 627, 628, and 631) for elements from Fe through Ru were performed using proton-induced X-rays, in order to test the smoothness of the elemental abundances in these chondrites. In general, the results confirm previously published abundance curves. The abundances were exceptionally smooth and strongly decreasing in the mass region 60-75. From the mass number 75 to 101, a smooth curve could be drawn, within limits of intersample variability, except for Y peak. Over the whole periodic table, a large number of peaks of probable nucleosynthetic origin could be identified.

Burnett, D. S.↗

NASA NTRS1989

Theoretical studies of the first- and second-row transition-metal methyls and their positive ions

The metal-carbon bond-dissociation energies (D0) and geometries for the first- and second-row transition-metal methyl neutrals and positive ions are determined. The computed D0 values for the positive ions compare favorably with experiment, except for RuCH3(+), RhCH3(+), and PdCH3(+), where the experimental values are 10-15 kcal/mol larger. The computed D0 values for the hydride and methyl positive ions are similar for all metals in both transition rows, except for Cu and Ag. However, for the neutral systems, the D0 values for the methyls are smaller, especially on the right-hand side of both transition rows, where the differences approach 15 kcal/mol.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1989

Cosmogenic helium and volatile-rich fluid in Sierra Leone alluvial diamonds

Noble gas measurements were carried out on two identical splits of a finely powdered harshly acid-washed sample derived from fragments of a single alluvial diamond from Sierra Leone, with essentially identical results obtained for both splits. Isotopic ratios for Ar, Kr, and Xe were found to be atmospheric. Their elemental abundances were high relative to published data, owing to the effect of shock implantation in the crushing step, as was verified in a supplementary experiment. No Ne was detected above the blank level. The He-3 was exceptionally abundant, while He-4 was exceptionally depleted, possibly due to the acid wash. The He-3/He-4 ratio was anomalously high at an R/Ra value of 246 + or - 16. The results support the hypothesis that the He-3 excess in diamonds is cosmogenic.

Mcconville, P.↗

NASA NTRS1989

Flight Motor Set 360L003 (STS-29R)

The redesigned solid rocket motor (RSRM) flight set 360L003 was launched on March 13, 1989 as part of NASA space shuttle mission STS-29R. As was the case with flight sets 360L001 and 360L002 (STS-26R and STS-27R), both motors (360L003A and 360L003B) performed in an excellent manner. Evaluation of the ground environment instrumentation measurements verified thermal model analysis data and showed agreement with predicted environmental effects. The right-hand aft field joint primary heater failed during the countdown; the secondary heater was activated and performed as designed. All other field joint heaters and aft skirt thermal conditioning systems had no anomalies. Shuttle thermal imager infrared readings compared favorably with measured ground environment instrumentation data. No thermal launch commit criteria violations occurred at any time. Evaluation of the development flight instrumentation showed exceptional propulsion performance. All ballistic parameters closely matched the predicted values and were well within the required specification levels. Girth and biaxial strain gage measurements compared closely with corresponding gages on previous flight motors, static tests, and with preflight predictions. Adequate safety factors were verified. (Some ignition transient spiking was noted in a few girth gages; the spiking was determined not to be representative of actual case behavior, but an instrumentation phenomena.) The accelerometers again measured high vibration amplitude levels during the ignition transient and the reentry Max Q phases. Postflight inspection showed that all combustion gas was contained by the insulation in the field and case-to-nozzle joints. No anomalous insulation erosion patterns were found, and the seals that did directly contain motor pressure showed no heat effects, erosion, or blowby. All anomalies identified were a result of splashdown damage, with the exception of fretting in the case field joint interference (nonsealing) surfaces and a prelaunch field joint heater failure. The disposition of all anomalies and the complete results are reported.

Riehr, Glen A.↗

NASA NTRS1989

Interpretation and modeling of the averaged equations for a fluid-solid flow

A self-consistent derivation of the conservation laws is given for flows of a fluid-solid mixture. A unified analytical framework for obtaining constitutive relations is provided. This analysis uses a control volume/control surface approach that is widely used in fluid mechanics. All terms in the governing equations and the constitutive relations are written in terms of the mass-weighted averages except solid concentration. It is believed that the mass-weighted average is the natural bridge between micromechanics and constitutive relations. The derived momentum equations contain terms that differ from all existing models except that of Prosperetti and Jones (1984). However, their assumptions are not needed here. Special attention is given to the solid phase pressure. The physical basis of the previously assumed form for this pressure (Givler 1987) becomes clear. A number of related phenomena are also discussed. These include the anti-diffusion and anisotropic normal stresses. The energy equations are also different from existing models.

Shen, Hayley H.↗

NASA NTRS1990

Flight motor set 360L006 (STS-34). Volume 1: System overview

Flight motor set 360L006 was launched at approximately 11:54 a.m. Central Daylight Time (CDT) on 18 October 1989 as part of NASA space shuttle mission STS-34. As with all previous redesigned solid rocket motor launches, overall motor performance was excellent. All ballistic contract end item (CEI) specification parameters were verified with the exceptions of ignition interval and rise rates. Ignition interval and rise rates could not be verified due to the elimination of developmental flight instrumentation from fourth flight and subsequent, but the low sample rate data that were available showed nominal propulsion performance. All ballistic and mass property parameters closely matched the predicted values and were well within the required CEI specification levels that could be assessed, with the exception of the RH-motor vacuum-delivered specific impulse. It exceeds the upper-limit CEI specification due to a bias imposed on the raw data by the OPT/Taber gage measurement differences. Evaluation of the ground environment instrumentation measurements again verified thermal model analysis data and showed agreement with predicted environmental effects. No launch commit criteria thermal violations occurred. Postflight inspection again verified superior performance of the insulation, phenolics, metal parts, and seals. Postflight evaluation indicated both nozzles performed as expected during flight, although splashdown loads tore the left-hand, 45-deg actuator bracket from the nozzle. All combustion gas was contained by insulation in the field and nozzle-to-case joints. Recommendations were made concerning improved thermal modeling and measurements. The rationale for these recommendations, the disposition of all anomalies, and complete result details are contained.

Garecht, Diane M.↗

NASA NTRS1989

Stratospheric ozone - Impact of human activity

The current knowledge of the chemistry of the stratosphere is reviewed, with particular consideration given to the measurements from the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment and from the Airborne Antarctic Ozone Experiment. Analysis of the ATMOS data at 30 deg N suggests that the current understanding of the contemporary-stratosphere chemistry at mid-latitudes is relatively complete, except for possible problems with the diurnal variations of N2O5 at low altitudes, and with ClNO3 at higher altitudes. Except for some difficulties with these two compounds, the data from ATMOS agree well with the gas phase models for nitrogen and chlorine species at 30 deg N in spring. It is emphasized that, in addition to the HOCl mechanism proposed by Solomon et al. (1986), the ClO-BrO scheme proposed by McElroy et al. (1986), and the ClO dimer mechanism introduced by Molina and Molina (1987), other processes exist that are responsible for ozone removal.

Mcelroy, Michael B.↗

NASA NTRS1990

Theoretical line shapes for rotational spectra of HCl in Ar

An interaction potential for HCl-Ar recently derived from spectra of van der Waals complexes (Hutson,1988) has been used to obtain converged close-coupling scattering S matrices from which pressure broadening (linewidth, line shift, and line coupling) cross sections have been computed within the Fano-Ben-Reuven formalism. Linewidths agree well with experimental data with the exception of the 0-1 line at low temperatures (an error of about 15 percent at 125 K). Line shifts, especially the largest, for the 0-1 line, are also in reasonable accord with experimental data. Line coupling is predicted to be quite small. The coupled-states molecular scattering approximation is found to be accurate except at very low collision energies. The infinite-order sudden approximations, on the other hand, is not reliable for this system. Inelastic scattering out of the spectroscopic levels accounts for only a fraction of the linewidth at thermal energies, especially in the lower rotational levels.

Green, Sheldon↗

NASA NTRS1991

Alloy Has High Fatigue Strength In Hydrogen

Experimental nickel-base alloy exhibits exceptional low-cycle-fatigue strength in hydrogen. Alloy one of many intended to be produced by strategy of formulating compositions having potential for exceptional low-cycle-fatigue strength in air, casting these alloys into single crystals, and processing them in such ways that their microstructures contain minimal numbers of both sites favoring initiation of fatigue and sites having high surface energies for entrapment of, and infiltration by, hydrogen.

Cetel, Alan D.↗

NASA NTRS1990

Space shuttle development Motor No. 9 (DM-9), volume 1

The results obtained during the December 23, 1987 static firing of the DM-9 test article are presented. The DM-9 full-scale static test article employed redesigned solid rocket motor (RSRM) field joint capture feature hardware with J-seal insulation configuration, and nozzle-to-case joint radial bolt design with bonded insulation configuration. The nozzle incorporated RSRM components, including a thicker cowl with involuted outer boot ring. The nozzle employed redundant and verifiable seals in all five joints, and room temperature vulcanization backfill in three joints. With very few exceptions, the DM-9 test article was flight configuration. The test was conducted under extreme weather conditions: temperature of 25 F and wind at 15 to 20 mph. Ballistics performance values were within specification requirements. The RSRM field joint (J-seal) insulation configuration functioned as predicted with no indication of hot gases reaching the capture feature O-rings. There was a blowhole in the polysulfide adhesive in the nozzle-to-case joint, but no evidence of hot gases past the wiper O-ring. Nozzle design changes appeared to perform nominally, with the exception of the outer boot ring, which suffered partial structural breakup late in the test. Field joint heaters maintained the controlling resistance temperature device temperature within the specified requirements during heater operation. The thrust vector control system operated properly. The redesigned water deluge system, temperature conditioning equipment, and other test support equipment performed as planned.

Garecht, Diane M.↗

NASA NTRS1990

Evolution of a superbubble blastwave in a magnetized medium

Researchers investigate the effects of interstellar magnetic fields on the evolution and structure of interstellar superbubbles, using both analytic and numerical magnetohydrodynamic (MHD) calculations. These cavities of hot gas, surrounded by shells of cold dense material preceded by a shock wave result from the combined action of stellar winds and supernova explosions in OB associations. If the medium in which a superbubble goes off is homogeneous and unmagnetized, the blast wave expands isotropically. As the interstellar gas flows through the shock, it cools significantly and gets strongly compressed such that thermal pressure remains approximately equal to ram pressure. Hence, the swept up material is confined to a very thin shell. However, if the ambient medium is permeated by a uniform magnetic field B sub o approx. 3 mu G (typical value for the interstellar matter (ISM)), the configuration loses its spherical symmetry, and, due to magnetic pressure, the shell of swept up material does not remain thin. Researchers found the following qualitative differences: (1) Except in the immediate vicinity of the magnetic poles, the shell is supported by magnetic pressure. (2) The refraction of field lines at the shock and the thermal pressure gradient along the shell both contribute to accelerating the gas toward the equator. The resulting mass flux considerably decreases the column density at the magnetic poles. (3) Away from the poles, magnetic tension in the shell causes the field lines (particularly the inner boundary) to elongate in the direction of B sub o. In contrast, the shock wave radius increases with increasing theta. (4) The reduced inertia of a parcel in the polar neighborhood makes it easier to decelerate, and accounts for the dimple which appears at the poles in numerical simulations. This dimple also results from the necessity to call on intermediate shocks in order to insure a smooth transition between a purely thermal shock at the poles and a magnetic shock in the rest of the shell. (5) The shock wave propagates faster than in the absence of magnetic field, except near the poles where the reduced mass of the shell allows it to be more efficiently decelerated.

Ferriere, Katia M.↗

NASA NTRS1989

The autocorrelation function of the North Pole dust

The angular scales on which local interstellar dust is distributed are so far rather unknown as are the geometrical shapes of the dust features. From the about 5000 color excesses resulting from a north polar survey with 4 to 5 stars per square degree the two-point autocorrelation function is derived for separations ranging from 10 min to 3 deg. For intercloud lines of sight, -0.020 is less than E(b - y) is less than -0.010 mag, the average cross products (E sub 1 x E sub 2)(sub theta) show no variation with separation theta(1,2) whereas products of cloud column densities, 0.030 is less than E(b - y) is less than 0.040 mag, seem to prefer discrete separations either less than 20 min, around 75 min, or finally at about 150 min. Surprisingly the two point autocorrelation function omega(sub E) = E(sub 1) x E(sub 2)/E squared - 1 equals 0 except for any separation except theta = 0. Omega(sub E)(theta)'s absence of variation is unexpected because omega(sub H)(theta) is known to vary exponentially above b = 40 deg for separations less than 3 deg. Atomic hydrogen and dust may thus not be entirely mixed or the moments (E sub 1 x E sub 2)(sub theta) may not characterize the dust distribution.

Knude, Jens↗

NASA NTRS1990

Distorted-wave born approximation calculations for turbulence scattering in an upward-refracting atmosphere

Weiner and Keast observed that in an upward-refracting atmosphere, the relative sound pressure level versus range follows a characteristic 'step' function. The observed step function has recently been predicted qualitatively and quantitatively by including the effects of small-scale turbulence in a parabolic equation (PE) calculation. (Gilbert et al., J. Acoust. Soc. Am. 87, 2428-2437 (1990)). The PE results to single-scattering calculations based on the distorted-wave Born approximation (DWBA) are compared. The purpose is to obtain a better understanding of the physical mechanisms that produce the step-function. The PE calculations and DWBA calculations are compared to each other and to the data of Weiner and Keast for upwind propagation (strong upward refraction) and crosswind propagation (weak upward refraction) at frequencies of 424 Hz and 848 Hz. The DWBA calculations, which include only single scattering from turbulence, agree with the PE calculations and with the data in all cases except for upwind propagation at 848 Hz. Consequently, it appears that in all cases except one, the observed step function can be understood in terms of single scattering from an upward-refracted 'skywave' into the refractive shadow zone. For upwind propagation at 848 Hz, the DWBA calculation gives levels in the shadow zone that are much below both the PE and the data.

Gilbert, Kenneth E.↗

NASA NTRS1990

An experimental study of the turbulent boundary layer on a transport wing in subsonic and transonic flow

The upper surface boundary layer on a transport wing model was extensively surveyed with miniature yaw probes at a subsonic and a transonic cruise condition. Additional data were obtained at a second transonic test condition, for which a separated region was present at mid-semispan, aft of mid-chord. Significant variation in flow direction with distance from the surface was observed near the trailing edge except at the wing root and tip. The data collected at the transonic cruise condition show boundary layer growth associated with shock wave/boundary layer interaction, followed by recovery of the boundary layer downstream of the shock. Measurements of fluctuating surface pressure and wingtip acceleration were also obtained. The influence of flow field unsteadiness on the boundary layer data is discussed. Comparisons among the data and predictions from a variety of computational methods are presented. The computed predictions are in reasonable agreement with the experimental data in the outboard regions where 3-D effects are moderate and adverse pressure gradients are mild. In the more highly loaded mid-span region near the trailing edge, displacement thickness growth was significantly underpredicted, except when unrealistically severe adverse pressure gradients associated with inviscid calculations were used to perform boundary layer calculations.

Spaid, Frank W.↗

NASA NTRS1989

Flight motor set 360T004 (STS-30R). Volume 1: System overview

The fourth NASA space shuttle flight incorporating redesigned solid rocket motors began on 4 May 1989. The flight motors were designated 360Q004A (left-hand) and 360H004B (right-hand); the mission was designated STS-30R. Overall engine performance was excellent. The low sample rate data that was available showed exceptional propulsion performance. All ballistic and mass property parameters closely matched the predicted values and were well within the required contract end item specification levels that could be assessed. No strain, vibration, or aft skirt heating environments could be addressed due to developmental flight instrumentation deletion. Infrared readings from the shuttle thermal imager were considered very good when compared with ground environment instrumentation readings taken during both the aborted and the actual countdowns. However, hand-held infrared gun reading/ground environment instrumentation comparisons were considered poor during both countdowns, with the exception of the T - 3 hour timeframe during the actual launch. Postflight inspection again verified superior performance of the insulation, phenolics, metal parts, and seals. All combustion gas was contained by the insulation in the field and case-to-nozzle joints. Inadequate parachute performance on the left-hand booster caused high splashdown loads, which resulted in a displaced nozzle and factory joint weatherseal unbond anomalies. Recommendations were made concerning improved thermal modeling and instruments. The rationale for these recommendations, the dispositions of all anomalies, and complete result details are given.

Ricks, Glenn A.↗

NASA NTRS1991

The spin down of the radio pulsars: Braking index

Presently, the value of the retardation dP/dt is well known for most radio pulsars. It is negative for all cases except one and is of the order of 10(exp -15). That single case is when the pulsar, which is located in the star globular system, can have a considerable acceleration leading to the opposite sign of P'= dP/dt due to the Doppler effect. Careful measurements of the period, P, also allow one to determine the variation of this retardation with the course of time- P'' = d(exp 2)P/dt(exp 2). The results of these measurements are usually represented in the form of the dimensionless retardation index n = omega'' omega/omega(exp 2)= 2 - P''P/P(exp 2) (omega is the angular velocity). The data for 21 pulsars are given. The parameter, n, is strongly undetermined both in value and sign in all cases except for four pulsars. Changes of the rotation period, P, and the inclination angle, chi, the angle between the axes of rotation and the magnetic moment are caused by two processes: the regular retardation and nutation due to deviation from the strict spherical shape of the neutron star. Losses which are caused by the currents flowing in the magnetosphere of the neutron star and by being closed on the star surface are considered. Such losses are critical for the neutron star magnetosphere which is full of dense plasma. Since the radio emission is generated in the dense plasma of the polar magnetosphere, then practically all radio pulsars are retarded by the current mechanism. The formula for the braking index is presented along with other aspects of the investigation.

Beskin, V. S.↗

NASA NTRS1990

Atmospheric degradation mechanisms of hydrogen containing chlorofluorocarbons (HCFC) and fluorocarbons (HFC)

The current knowledge of atmospheric degradation of hydrogen containing chlorofluorocarbons (HCFC 22 (CHClF2), HCFC 123 (CHCl2CF3), HCFC 124 (CHClFCF3), HCFC 141b (CFCl2CH3), HCFC 142b (CF2ClCH3)) and fluorocarbons (HFC 125 (CHF2CF3), HFC 134a (CH2FCF3), HFC 152a (CHF2CH3)) is assessed. Except for the initiation reaction by OH radicals, there are virtually no experimental data available concerning the subsequent oxidative breakdown of these molecules. However, from an analogy to the degradation mechanisms of simple alkanes, some useful guidelines as to the expected intermediates and final products can be derived. A noteable exception from this analogy, however, appears for the oxi-radicals. Here, halogen substitution induces new reaction types (C-Cl and C-C bond ruptures) which are unknown to the unsubstituted analogues and which modify the nature of the expected carbonyl products. Based on an evaluation of these processes using estimated bond strength data, the following simplified rules with regards to the chlorine content of the HCFC's may be deduced: (1) HCFC's containing one chlorine atom such as 22 and 142b seem to release their chlorine content essentially instantaneous with the initial attack on the parent by OH radicals, and for HCFC 124, such release is apparently prevented; (2) HCFC's such as 123 and 141b with two chlorine atoms are expected to release only one of these instantaneously; and the second chlorine atom may be stored in potentially long-lived carbonyl compounds such as CF3CClO or CClFO.

Zellner, Reinhard↗