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Results for “Chalcogenides”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Correction to Wide Band Gap Chalcogenide Semiconductors
Abstract not provided.
Analyzing and Tuning the Chalcogen–Amine–Thiol Complexes for Tailoring of Chalcogenide Syntheses
Abstract not provided
In 4 Pb 5.5 Sb 5 S 19 : A Stable Quaternary Chalcogenide with Low Thermal Conductivity
Not provided.
Tuning of Cr?Cr Magnetic Exchange through Chalcogenide Linkers in Cr[subscript 2] Molecular Dimers
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Quasi-One-Dimensional Transition-Metal Chalcogenide Semiconductor (Nb 4 Se 15 I 2 )I 2
Not provided.
Elucidating the Discharge Behavior of Aqueous Zinc Sulfur Batteries in the Presence of Molybdenum(IV) Chalcogenide Catalyst: The Criticality of Interfacial Electrochemistry
The aqueous zinc-sulfur battery holds promise for significant capacity and energy density with low cost and safe operation based on environmentally benign materials. However, it suffers from the sluggish kinetics of the conversion reaction. Here, we highlight the efficacy of molybdenum(IV) sulfide (MoS 2 ) to reduce the overpotential of S-ZnS conversion in aqueous electrolytes and study the discharge products formed at the solid-solid and solid-liquid interfaces using experimental and theoretical approaches. Specifically, the MoS 2 -catalyzed electrochemical conversion reaction is characterized via ex situ X-ray diffraction (XRD), transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS), Raman spectroscopy, synchrotron-based Mo K-edge X-ray absorption spectroscopy (XAS), and in situ synchrotron-based X-ray computed tomography (XCT). Additionally, operando synchrotron-based S K-edge XAS and X-ray fluorescence (XRF) maps are collected to determine the spatial evolution of sulfur-based species at the electrode-electrolyte interface. Further, coupling the operando S K-edge XAS data with the simulated spectra and fitting the data suggested a possible ZnS 2 intermediate phase.