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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

The C-12/C-13 ratio in stellar atmospheres. II - CN and CO in alpha Orionis

The isotopic abundance ratio C-12/C-13 for the M supergiant alpha Orionis is derived from photoelectric high-resolution scans of the CN 2-0 red system and high-resolution interferometric spectra of the CO second-overtone bands. The two molecules yield consistent results and the final value for the C-12/C-13 ratio is 7.0 plus or minus 1.5. Rationale is offered for the causes contributing to an earlier suggestion that C-12/C-13 ratios from CO and CN were in disagreement.

Lambert, D. L.↗
NASA NTRS1975

Observations of the fundamental rotation-vibration band of CN

Three lines of the fundamental rotation-vibration band of CN have been observed in the laboratory using a King furnace. The transition moment squared has been found to be .00075 plus or minus .00031 atomic units. In addition, the transition moment squared of the 0-0 band of the red system of CN has been measured to be 0.48 plus or minus 0.28 atomic units (an oscillator-strength of .00033 plus or minus .0019).

Treffers, R. R.↗
NASA NTRS1977

Spectral absorption coefficients for the fundamental and first overtone vibration-rotation bands of CN

A previous measurement of the transition moment of the fundamental vibration-rotation band of CN is combined with theoretical calculations of relative vibrational transition probabilities in order to compute absorption coefficients for the CN fundamental and first-overtone bands. Line strengths for 121 lines in each branch of all fundamental and first-overtone bands with upper-transition states not greater than 6 are calculated for temperatures of 2000, 3000, and 4000 K; these line strengths are presented as averaged over 8-kayser intervals. The relative vibrational transition moments are placed on an absolute scale, and the wavenumbers of the band origins and heads are given

Bailey, W. L.↗
NASA NTRS1984

Ultraviolet and optical spectroscopy of Cn 1-1 (= HDE 330036)

Ultraviolet and optical spectra of Cn 1-1 are presented. This stellar object has strong emission lines superposed on the absorption spectrum of an F5 III-IV star. It has been called both a symbolic star and a planetary nebula. Optical spectra taken over a period of two years do not show any variations in radial velocities. The radial velocities of the absorptionand emission-line spectra appear to be the same. The ultraviolet and optical spectra did not show variations in appearance over the period of observations. The interstellar extinction and distance are estimated by various methods, and values of c = 0.4 and d = 450 pc are adopted. The emission-line region is characterized by high-electron density and temperature and by enhancements over solar values in C/O and N/O. It is proposed that Cn 1-1 is a dense planetary nebula involved in a binary system. If so, the enhancements in abundances derived from the observations suggest that the planetary nebula is associated with a relatively massive progenitor star.

Lutz, J. H.↗
NASA NTRS1985

Photodissociation rates of OH, OD, and CN by the interstellar radiation field

The photoabsorption cross sections for OH, OD, and CN in the vacuum ultraviolet region are measured. The cross sections for the hydroxyl radicals are of the order of 10 to the -17th sq cm, but the photoabsorption for CN is so low that only an upper limit of 2 x 10 to the -18th sq cm is obtained. The molecular photodissociative processes are discussed. The photodissociation cross sections are inferred from the photoabsorption cross sections. On the basis of the measured data, the photodissociation rates by the interstellar radiation field are computed and discussed.

Nee, J. B.↗
NASA NTRS1985

A precise measurement of the cosmic microwave background temperature from optical observations of interstellar CN

Very precise observations (with S/N greater than 2000) of the 3874-angstrom band of interstellar CN toward zeta Per and omicron Per are presented. In the zeta Oph, zeta Per, and omicron Per lines of sight, the saturation-corrected CN line strengths yield respective excitation temperatures of 2.72 plus or minus 0.05 K, 2.76 plus or minus 0.05 K, and 2.78 plus or minus 0.07 K for the J = 0-1 rotational transition at 2.64 mm. By confirming the blackbody character of the cosmic microwave background spectrum at wavelengths near the peak of its flux, the simplest explanation of the background as primeval fireball radiation from a hot bang is reinforced.

Meyer, D. M.↗
NASA NTRS1986

CN jets of Comet P/Halley: Rotational properties

An analysis of CCD images of CN jets of comet P/Halley observed during April 16 to 29 1986 is discussed. The analysis questions the 53 hr rotation period and favors a rotational period of 7.37 days, as suggested by Millis and Schleicher (1986). It is shown that a change in rotation period, at least from one apparition to the next, is also possible. A lower limit for the ejection velocity of dust grains (which emit CN) in the jet is established to be 0.5 km/sec with an uncertainty of 50%. The constraints on the direction of the rotation axis as inferred from the geometry of the jets are considered.

Samarasinha, Nalin H.↗
NASA NTRS1986

Detection of CN emission in Comet P/Halley

The first detection of the CN 3883 A band in emission in Comet P/Halley (1982) in February 1985 is reported. The detection technique, which is described, used blind offsets from secondary reference stars to the comet's predicted position, and involved plotting the comet's track on an enlargement of an appropriate section of the Palomar Sky Survey E plates. The strong solar continuum in the resulting cometary spectrum demonstrates the dominance of the dust reflection spectrum and the reflection from the nucleus. The 3883 A feature is identified with the v = 0 band sequence of the blue system of CN; no other significant features were identified in the spectrum.

Wyckoff, S.↗
NASA NTRS1988

Theoretical study of the dissociation energy and the red and violet band systems of CN

The dissociation energy D0 is determined here for the CN ground-state and radiative lifetimes for the A 2Pi and B 2Sigma(+) states. D0 is found to be 7.65 + or - 0.06 eV, corresponding to Delta Hf (CN) = 105.3 + or - 1.5 kcal/mole. These results are compared with current experimental estimates and with previous theoretical calculations.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1988

The IUE spectrum of Cn 1-2 (= PK 326-10 deg 1) - A southern counterpart to V1016 Cygni and HM Sagittae?

Low-dispersion IUE spectra confirm that the emission-line object Cn 1-2 is a symbiotic star and not a planetary nebula. The UV spectrum of Cn 1-2 strongly resembles those of V1016 Cyg and HM Sge. The object is correctly identified in the finder field of Allen's Catalogue of Symbiotic Stars (1984) but misidentified in the Catalogue of Galactic Planetary Nebulae by Perek and Kohoutek (1967).

Feibelman, Walter A.↗
NASA NTRS1989

Theoretical study of the dipole moment function of the X2Sigma(+) state of CN

The X2Sigma(+) state dipole moment function of CN is determined from accurate ab initio calculations. The calculated Einstein coefficient of 13.0 /s for the fundamental 1-0 vibrational band is in excellent agreement with the value measured by Treffers (1975) using a King furnace. The theoretical vibrational band strengths should be valuable in interpreting the fluorescence spectrum of CN in comets.

Langhoff, Stephen R.↗
NASA NTRS1991

The states of carbon and nitrogen atoms after photodissociation of CN, CH, CH(+), C2, C3, and CO in comets

The photodissociation of carbon compounds by solar UV radiation at a heliocentric distance of 1 AU is examined, comparing published observational data with the predictions of theoretical models and results from laboratory experiments. It is shown that species other than CO, including CN, CH, CH(+), C2, and C3, can contribute to the observed brightness of the VUV lines of C I (156.1, 165.7, and 193.1 nm) and C II (133.5 nm) in comet comae. CN photodissociation is also found to produce metastable 2D0 and 2P0 N I atoms, possibly leading (at heliocentric distances less than 0.25 AU) to 143.9-nm emission via resonance fluorescence.

Singh, P. D.↗
NASA NTRS1992

CN radical reactions with hydrogen cyanide and cyanogen - Comparison of theory and experiment

The method of laser photolysis/laser-induced fluorescence is used to obtain absolute rate constants for CN radical reactions with HCN and C2N2. The rate constants were found to be temperature-dependent in the range 300-740 K and pressure independent in the range 100-600 Torr. Rice-Remsperger-Kassel-Marcus theory for both reactions employing the transition state parameters obtained by the BAC-MP4 method are made. These calculations yielded reasonable results for the CN + HCN reaction, predicting both the temperature dependence and pressure independence. No pressure effect was observed in the pressure range 100-1000 Torr at temperatures below 900 K, confirming the experimental results.

Yang, D. L.↗
NASA NTRS1993

C2, CN and dust in Comet Wilson (1987VII)

Column density profiles in C2 and CN as well as in blue and red continuum (BC and RC) were constructed from two dimensional images of the coma of Comet Wilson (1987VII). The authors' analysis showed that the continuum profiles decrease with the nuclear distance rho as 1/rho. From the C2 and CN profiles the authors determined the parent and the daughter lifetimes as well as the production rates in terms of the vectorial model.

Schulz, R.↗
NASA NTRS1994

Observation of CH A->X, Cn B->X, and NH A->X Emissions in Gas-phase Collisions of Fast O ((sup 3)P) Atoms with Hydrazines

Optical emissions in single-collision reactions of fast (20 eV laboratory translational energy) O((sup 3)P) atoms with hydrazine, methylhydrazine, and 1,1-dimethylhydrazine have been measured in a crossed-beams geometry. The emissions were observed in the wavelength range 325-440 nm, and were identified as the CH (A 2(sub A))-->X(sup 2)pi(sub r), (for methylhydrazine), CN (B sup 2) Sigma(sup +) --> X(sup 2) Sigma(sup +) (for methylhydrazine)and NH(A(sup 3)pi --> X(sup3 Sigma) transitions (for all three hydraz vibration-rotation bands were fit to a synthetic spectrum of CH, CN and NH with given vibrational and rotational temperatures.

chemical reactions↗
DOE OSTI2020

Materials Data on K2Pd(CN)4 by Materials Project

K2Pd(CN)4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. K1+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of K–N bond distances ranging from 2.83–3.34 Å. Pd2+ is bonded in a square co-planar geometry to four C2+ atoms. There is two shorter (1.99 Å) and two longer (2.00 Å) Pd–C bond length. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a distorted single-bond geometry to one Pd2+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a distorted single-bond geometry to one Pd2+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent K1+ and one C2+ atom. In the second N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent K1+ and one C2+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on CN by Materials Project

CN is alpha carbon monoxide-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight hydrogen cyanide molecules. C3+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a single-bond geometry to one C3+ atom.

36 MATERIALS SCIENCE↗