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NASA NTRS2004

Transport of Biomass Burning Emissions from Southern Africa

The transport of biomass burning emissions from southern Africa to the neighboring Atlantic and Indian Oceans during the dry season (May-October) of 2000 is characterized using ground, ozonesonde, and aircraft measurements of carbon monoxide (CO) and ozone (O3) in and around southern Africa, together with the GEOS-CHEM global model of tropospheric chemistry. The model shows a positive bias of approximately 20% for CO and a negative bias of approximately 10-25% for O3 at oceanic sites downwind of fire emissions. Near areas of active fire emissions the model shows a negative bias of approximately 60% and approximately 30% for CO and O3, respectively, likely due to the coarse spatial (2 deg. x 2.5 deg.) and temporal (monthly) resolution of the model compared to that of active fires. On average, from 1994 to 2000, approximately 60 Tg of carbon monoxide (CO) from biomass burning in southern Africa was transported eastward to the Indian Ocean across the latitude band 0 deg. -60 S during the 6 months of the dry season. Over the same time period, approximately 40 Tg of CO from southern African biomass burning was transported westward to the Atlantic Ocean over the latitudes 0 deg. -20 S during the 6-month dry season, but most of that amount was transported back eastward over higher latitudes to the south (21 deg. -60 S). Eastward transport of biomass burning emissions from southern Africa enhances CO concentrations by approximately 4- 13 ppbv per month over the southern subtropical Indian Ocean during the dry season, with peak enhancements in September. Carbon monoxide from southern African and South American biomass burning is seen in the model simulations as far away as Australia, contributing approximately 8 ppbv and approximately 12-15 ppbv CO, respectively, and thus explaining the approximately 20- 25 ppbv observed enhancement of CO over Melbourne in mid-September 2000.

Sinha, Parikhit↗

NASA NTRS2010

Heat Effects of Promoters and Determination of Burn Criterion in Promoted Combustion Testing

Promoted ignition testing (NASA Test 17) [1] is used to determine the relative flammability of metal rods in oxygen-enriched atmospheres. A promoter is used to ignite a metal sample rod, initiating sample burning. If a predetermined length of the sample burns, beyond the promoter, the material is considered flammable at the condition tested. Historically, this burn length has been somewhat arbitrary. Experiments were performed to better understand this test by obtaining insight into the effect a burning promoter has on the preheating of a test sample. Test samples of several metallic materials were prepared and coupled to fast-responding thermocouples along their length. Thermocouple measurements and test video were synchronized to determine temperature increase with respect to time and length along each test sample. A recommended flammability burn length, based on a sample preheat of 500 F, was determined based on the preheated zone measured from these tests. This length was determined to be 30 mm (1.18 in.). Validation of this length and its rationale are presented.

Sparks, Kyle M.↗

NASA NTRS2003

Promoted Ignition and Burning Tests of Stainless Steel in Flowing and Nonflowing Oxygen

The Industry-Sponsored Metals Combustion Test Program 96-1 was coordinated through Wendell Hull & Associates, Inc. on behalf of several contributing companies, and all design and testing was performed at the NASA White Sands Test Facility. Phase I of this test program studied the threshold pressure for self-sustained burning of various types and sizes of stain less steel rods in nonflowing oxygen, as observed in Standard Test Method for Determining the Combustion Behavior of Metallic Materials in Oxygen-Enriched Atmospheres (ASTM G 124-95). Phase II studied the ignition and propagation of burning of 316L stainless steel rods and pipe in flowing gaseous oxygen. The test sample configurations were chosen to replicate previous promoted ignition and burning tests as well as to represent geometries and cross-sectional thicknesses common in industrial piping applications. The gas pressw'es and velocities for the test matrix were selected to generally compare with CGA G-4.4 guidelines for the use of stain less steel in oxygen service. This paper summarizes the results from the Phase I nonflowing oxygen tests and presents in detail the results of the Phase II flowing oxygen tests. The maximum sample burn-length is shown as a function of test pressure in Phase 1 and also as a function of gas velocity in Phase IT. These results indicate that flowing oxygen, under the given test conditions, significantly affects maximum sample burn length as compared to nonflowing oxygen. Supplementary flowing oxygen test data on stainless steel rods from a follow-up test program are consistent with these results and are presented herein.

Forsyth, Elliot T.↗

NASA NTRS2003

Burn-Resistant, Strong Metal-Matrix Composites

Ceramic particulate fillers increase the specific strengths and burn resistances of metals: This is the conclusion drawn by researchers at Johnson Space Center's White Sands Test Facility. The researchers had theorized that the inclusion of ceramic particles in metal tools and other metal objects used in oxygen-rich atmospheres (e.g., in hyperbaric chambers and spacecraft) could reduce the risk of fire and the consequent injury or death of personnel. In such atmospheres, metal objects act as ignition sources, creating fire hazards. However, not all metals are equally hazardous: some are more burn-resistant than others are. It was the researchers purpose to identify a burn-resistant, high-specific-strength ceramic-particle/metal-matrix composite that could be used in oxygen-rich atmospheres. The researchers studied several metals. Nickel and cobalt alloys exhibit high burn resistances and are dense. The researchers next turned to ceramics, which they knew do not act as ignition sources. Unlike metals, ceramics are naturally burn-resistant. Unfortunately, they also exhibit low fracture toughnesses.

Stoltzfus, Joel M.↗

NASA NTRS2012

Technologies and Concepts for Reducing the Fuel Burn of Subsonic Transport Aircraft

There are many technologies under development that have the potential to enable large fuel burn reductions in the 2025 timeframe for subsonic transport aircraft relative to the current fleet. This paper identifies a potential technology suite and analyzes the fuel burn reduction potential of these technologies when integrated into advanced subsonic transport concepts. Advanced tube-and-wing concepts are developed in the single aisle and large twin aisle class, and a hybrid-wing-body concept is developed for the large twin aisle class. The resulting fuel burn reductions for the advanced tube-and-wing concepts range from a 42% reduction relative to the 777-200 to a 44% reduction relative to the 737-800. In addition, the hybrid-wingbody design resulted in a 47% fuel burn reduction relative to the 777-200. Of course, to achieve these fuel burn reduction levels, a significant amount of technology and concept maturation is required between now and 2025. A methodology for capturing and tracking concept maturity is also developed and presented in this paper.

Nickol, Craig L.↗

NASA NTRSDate not supplied

Optimized Trajectory Correction Burn Placement for the NASA Artemis II Mission

The NASA Artemis II mission represents the first time humans plan to return to the lunar vicinity in over 50 years with a crew traveling to the Moon in the Orion spacecraft on a free return trajectory. This first crewed mission of the Artemis program will evaluate human-rated elements of Orion in preparation to sending astronauts to the lunar surface. The selected free-return cislunar trajectory profile that is reminiscent of the Apollo 8 mission that nominally requires no additional translational burns following the trans-lunar injection (TLI) burn. Due to crew activity, maneuver execution errors, navigation uncertainty, orbit insertion errors, disturbance accelerations, and other system limitations; periodic trajectory corrections burns are necessary to ensure proper entry interface (EI) conditions are satisfied for a safe return to Earth. Robust trajectory optimization techniques are utilized to determine the optimized placements for the Artemis II trajectory correction burns that accounts for the crew schedule, both the primary and backup navigation systems, targeting strategies and burn plan configurations, spacecraft venting, thruster selection, and the integrated GN&C performance.

Linear Covariance Analysis↗

NASA NTRS2024

Increased Atmospheric PM 2.5 Events Due to Open Waste Burning in Qaanaaq, Greenland, Summer of 2022

High levels of particulate matter (PM) are relevant to severe air pollution and can adversely impact human health. Maintaining healthy air quality for the residents of the Arctic region is essential to satisfy the no-one-left-behind policy of the Sustainable Development Goals (SDGs) by the United Nations. In this study, we installed a PM 2.5 measurement system in Qaanaaq, Greenland, and obtained the first continuous PM 2.5 measurements from 20 July to 13 August, 2022. We observed several increased PM2.5 events; relatively high PM 2.5 levels persisted from 8 August 2022. On the same day, visible black smoke emitted from the Qaanaaq dump site originated from open waste burning. By confirming less transboundary air pollution contributions from remote aerosol source regions to Qaanaaq during the measurement period using NOAA’s HYSPLIT backward trajectory analysis and NASA’s MERRA-2 aerosol re-analysis, we confirmed that the increased PM 2.5 was primarily due to local open waste burning with less contributions from transboundary air pollution. However, small contributions from biomass burning outside Greenland were plausible during the early measurement period. Additionally, NOAA’s HYSPLIT dispersion calculations suggested possible aerosol depositions from local open waste burning to nearby sea areas, such as Baffin Bay. Although the hourly mean PM 2.5 mass concentration was not alarmingly high during the measurement period, future studies should incorporate longer-term continuous PM 2.5 measurements along with other atmospheric chemical analyses to identify possible local air pollution sources in detail to ensure clean ambient air for the future in the Arctic. Our study provides quantitative evidence of the impact of open waste burning on air quality at a study site in Greenland, which could be crucial in developing air quality policies for this region in the Arctic.

aerosols↗

NASA NTRS2025

Nevada Wildland Fires: Mapping Historical Burned Areas and Identifying Drivers of Fuel Load Growth to Inform Desert Tortoise Habitat Management in Southern Nevada

Wildfire frequency and intensity in the Mojave desert are increasing, driven by invasive grasses that outcompete native vegetation not well-adapted to wildfire. These grasses, primarily cheatgrass (Bromus tectorum) and red brome (Bromus rubens), and the wildfires that occur when the grasses ignite, are a serious threat to the critically endangered Mojave desert tortoise (Gopherus agassizii). Declining Mojave desert tortoise populations are of great concern to project partners, the Bureau of Land Management Southern Nevada District Office, the US Forest Service’s Rocky Mountain Research Station, and the US Department of Agriculture Agricultural Research Service’s Arid Lands Ecology Lab, who currently lack the resources for fire recovery studies essential for informed fire and invasive grass management. To address this gap, the team utilized NASA Earth observations including Aqua Moderate Resolution Imaging Spectroradiometer (MODIS), Terra MODIS, Landsat 5 Thematic Mapper (TM), and Landsat 8 Operational Land Imager (OLI), to analyze trends in burned areas over the past 20 years through historic burn maps and to examine fuel load growth drivers, with a focus on invasive vegetation. These historical burn maps revealed a pattern of precipitation anomalies that strongly correlate with higher Normalized Difference Vegetation Index (NDVI) values. Years with significant precipitation and NDVI spikes led to greater fuel load in the dry season and larger burns. Additionally, El Niño years correlated significantly with precipitation anomalies which may provide our partners with insights into burn trends and enable better allocation of fuel load treatment practices. However, while identifying drivers of fuel load growth proved feasible, a lack of in situ data hindered attempts to analyze pre-fire growth of invasive grasses compared with native grasses. Despite this limitation, the project demonstrated the feasibility of using Earth observations for wildfire and habitat management, ultimately benefiting conservation efforts for the Mojave desert tortoise.

fuel load↗

DOE OSTI2023

Ultrahigh performance LC/FT-MS non-targeted screening for biomass burning organic aerosol with MZmine2 and MFAssignR

In recent years, ultrahigh performance liquid chromatography Fourier transform mass spectrometry (LC/FT-MS) based non-targeted screening (NTS) methods have become increasingly popular for comprehensive analysis of complex organic mixtures. However, applying these methods for environmental complex mixture analysis is challenging due to the extreme complexity of natural samples and a lack of standard samples or surrogates for environmental complex mixtures. Furthermore, limited molecular markers in the databases and insufficient data processing software workflows make the application of these methods more challenging for environmental complex mixtures. In this work, we implement a new NTS data processing workflow to process data collected from ultrahigh performance liquid chromatography and Fourier transform Orbitrap Elite Mass Spectrometry (LC/FT-MS) by combining MZmine2 and MFAssignR, two opensource data processing tools and commercial Mesquite liquid smoke as a surrogate for biomass burning organic aerosol. MZmine2.53 data extraction followed MFAssignR molecular formula assignment offered noise free and highly accurate 1733 individual molecular formulas presented in liquid smoke with 4906 molecular species, including isomers. The results of this new approach were consistent with the results of direct infusion FT-MS analysis confirming its reliability. Over 90% of the molecular formulas presented in mesquite liquid smoke were matched with the molecular formulas of ambient biomass burning organic aerosol. This suggests the potential use of commercial liquid smoke as a surrogate for biomass burning organic aerosol research. Furthermore, the presented method significantly improves the identification of the molecular composition of biomass burning organic aerosol by successfully addressing some of the limitations related to the data analysis and giving a semi quantitative insight into the analysis.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Data reduction considerations for the burning velocity of spherical constant volume flames of R32 (CH 2 F 2 ) with air

Here, the present work explores data reduction techniques for the measurement of the laminar burning velocities of R32(CH 2 F 2 )-air mixtures using a constant volume combustion device, in which the pressure-time history is the only measured parameter. To allow clear assessment of the accuracy of the data reduction methods, the pressure-time histories used for analysis are synthetically generated via a detailed numerical simulation employing full kinetics and with and without an optically-thin radiation model. Various data reduction models are employed, including a two-zone model and two multi-zone models, and these are compared with the results from the burning velocity obtained from the output of the numerical simulation. The data reduction schemes are shown to be accurate if the same radiation model is employed in the data reduction as was used in the flame simulation to generate the pressure trace used for post-processing. If the incorrect radiation model is employed, however, the errors can be quite large. The effects of stretch, radiation, and different data post-processing methodologies are explored and the errors quantified. Stretch is shown to be important for the early stages and the selected data range that is used for extrapolation has a significant effect on the extrapolated burning velocity. However, with an appropriate choice of data considered for extrapolation, the prediction of the unstretched burning velocity can be quite accurate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Control-oriented core-SOL-divertor model to address integrated burn and divertor control challenges in ITER

The real-time regulation of a burning plasma’s temperature and density, or burn control, will be necessary to produce high fusion power in future tokamaks like ITER. This is made more challenging due to the plasma’s nonlinear characteristics and the interdependence between the core-plasma and edge-plasma regions. For example, a raising plasma temperature leads to increasing reactivity and therefore to more alpha-particle heating, which further increases temperature. Furthermore, a raise of the fusion power increases the heat flow through the scrape-off-layer (SOL), which can compromise the integrity of the divertor without proper safeguards. For control design, a model-based approach is attractive because it can directly incorporate the nonlinear, coupled, burning-plasma dynamics into the design. To facilitate this design approach, a control-oriented core-SOL-divertor (CSD) model is presented in this work. In this CSD model, a core-plasma model captures the nonlinear dynamics of the core’s density and temperature, and a SOL-divertor model defines the plasma conditions at the separatrix and divertor including the heat load on the target plates. The core-plasma and SOL-divertor models are coupled through the exchange of various variables. In particular, the SOL-divertor model yields the separatrix temperature and the influx of recycled particles into the core-plasma. Further, these variables influence the power and particle balances captured by the core-plasma model. In return, the core-plasma model determines the intensity of the heat and particles fluxes across the separatrix, and this outflow strongly impacts the SOL-divertor model. Therefore, the power and density of the core-plasma, which can be readily modulated through external heating systems and pellet injection, can be viewed as control knobs for the SOL-divertor region in addition to the gas puffing. In simulations of the CSD model, it is demonstrated how external actuation can be utilized to meet burn control and divertor control objectives simultaneously.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2025

Evaluating post-fire watershed response to varying burn severity and precipitation regimes using fully-distributed and integrated hydrologic models

Wildfires can cause significant changes in vegetation and soil, which may lead to increased surface runoff and soil erosion, thereby affecting water cycling within ecosystems. This study uses the Advanced Terrestrial Simulator (ATS), an integrated and fully distributed hydrologic model at the watershed scale, to examine post-fire hydrologic responses in selected watersheds with varying burn severities in the Pacific Northwest region of the United States. The model integrates surface overland flow, subsurface flow, and canopy biophysical processes. We have developed a new fire module in ATS to account for changes in soil hydraulic properties caused by fire in the topsoil layer. Modeling results indicate that, in the year following a high-severity burn, watershed-averaged evapotranspiration decreases by 25%. Additionally, post-fire peak flows increase by 18-29% in watersheds burned with medium to high severity due to changes in soil properties. Conversely, a low-severity burn results in less than a 1% increase in post-fire peak flow. Furthermore, a high-severity fire causes a 38% reduction in the infiltration rate within the affected watershed during the first post-fire wet season. Hypothetical numerical experiments with varying precipitation regimes after a high-severity fire show that post-fire peak flows can increase by 1-29% due to fire-induced changes in soil hydraulic properties. This study highlights the importance of using fully distributed hydrologic models to quantify disturbance-feedback loops, which are essential for understanding the complexities brought about by spatial heterogeneity in post-fire landscapes.

ATS↗

DOE OSTI2024

Characterizing PM 2.5 Emissions and Temporal Evolution of Organic Composition from Incense Burning in a California Residence

The chemical composition of incense-generated organic aerosol in residential indoor air has received limited attention in Western literature. In this study, we conducted incense burning experiments in a single-family California residence during vacancy. Here, we report the chemical composition of organic fine particulate matter (PM 2.5 ), associated emission factors (EFs), and gas-particle phase partitioning for indoor semivolatile organic compounds (SVOCs). Speciated organic PM 2.5 measurements were made using two-dimensional gas chromatography coupled with high-resolution time-of-flight mass spectrometry (GC×GC-HR-ToF-MS) and semivolatile thermal desorption aerosol gas chromatography (SV-TAG). Organic PM 2.5 EFs ranged from 7 to 31 mg g –1 for burned incense and were largely comprised of polar and oxygenated species, with high abundance of biomass-burning tracers such as levoglucosan. Differences in PM 2.5 EFs and chemical profiles were observed in relation to the type of incense burned. Nine indoor SVOCs considered to originate from sources other than incense combustion were enhanced during incense events. Time-resolved concentrations of these SVOCs correlated well with PM 2.5 mass (R 2 > 0.75), suggesting that low-volatility SVOCs such as bis(2-ethylhexyl)phthalate and butyl benzyl phthalate partitioned to incense-generated PM 2.5 . Both direct emissions and enhanced partitioning of low-volatility indoor SVOCs to incense-generated PM 2.5 can influence inhalation exposures during and after indoor incense use.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Progress in pedestal and edge physics: Chapter 3 of the special issue: on the path to tokamak burning plasma operation

This paper describes the extensive progress that has been made in the understanding of tokamak pedestal physics since the 2007 publication of ‘Progress in the ITER Physics Basis’ (Ikeda 2007 Nucl. Fusion 47 E01–S500). It serves as Chapter 3 of the 2025 Nuclear Fusion Special Issue titled ‘On the Path to Tokamak Burning Plasma Operation’ (Campbell et al 2025 Nucl. Fusion ). This review was compiled by the pedestal and edge physics (PEP) community affiliated with the International Tokamak Physics Activity organization. It attempts to collect in one place citations to the majority of published literature on the pedestal physics topics that will be most important for the operation of a future power producing burning plasma tokamak. These include citations to publications describing the physics of the pedestal plasmas in many operating tokamaks worldwide and the pedestal physics projections for several near-term future devices including ITER. Descriptions of experimental results, interpretive modeling and predictive extrapolations are integrated together and comprehensive references are provided. This review is organized around four primary technical sections, viz.: pedestal structure, edge localized mode (ELM) characteristics, ELM control and regimes without large ELMs. Key results from many of the references are described briefly and set into the tokamak burning plasma power plant context. In addition, different perspectives on pedestal physics topics that are currently under debate within the community are also described, to provide guidance on needs for future research. Finally, attempts are made to describe conclusions from all of this progress consistent with discussions by the pedestal physics community at this time. The goal of this review is to provide a useful reference document for pedestal physics researchers going forward toward operation of a burning tokamak fusion plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2022

Estimation of China Fusion Engineering Test Reactor performance and burning fraction in different pellet fueling scenarios by a multi-species radial transport model

Tritium self-sufficiency in future deuterium–tritium fusion reactors is a crucial challenge. As an engineering test reactor, the China Fusion Engineering Test Reactor requires a burning fraction of 3% for the goal to test the accessibility to the future fusion plant. To self-consistently simulate burning plasmas with profile changes in pellet injection scenarios and to estimate the corresponding burning fraction, a one-dimensional multi-species radial transport model is developed in the BOUT++ framework. Here several pellet-fueling scenarios are then tested in the model. The results show that the increased fueling depth improves the burning fraction by particle confinement improvement and fusion power increase. Nevertheless, by increasing the depth, the pellet cooling-down may significantly lower the temperature in the core region. Taking the density perturbation into consideration, the reasonable parameters of the fueling scenario in these simulations are estimated as pellet radius ${r}_{{\rm{p}}}=3\,{\rm{mm}},$ injection rate $=\,4\,\mathrm{Hz},$ and pellet injection velocity $=\,1000\mbox{-}2000\,{\rm{m}}\,{{\rm{s}}}^{-1}$ without drift or $450\,{\rm{m}}\,{{\rm{s}}}^{-1}$ with high-field-side drift.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2024

Support of US Burning Plasma Organization (Final Technical Report)

The objective of the project described here was to support and increase the effectiveness of the US Burning Plasma Organization. This a national organization of scientists and engineers in magnetic fusion energy, established in 2005 at the request of the DOE Office of Fusion Energy Sciences, which serves to “Advance the scientific understanding of burning plasmas and ensure the greatest benefit from a burning plasma experiment by coordinating relevant U.S. fusion research with broad community participation.” It has grown to over 420 members from over 70 institutions, primarily across the US but with some associate members from other countries. The project was divided into two tasks. The first supported leadership activities in the USBPO by the Deputy Director, Dr. Amanda Hubbard. Responsibilities included chairing regular meetings of the USBPO Research Committee, communicating with the USBPO membership via emails and web seminars, forming and overseeing activities of Task Groups, and ensuring good communication about activities of the International Tokamak Physics Activity. A task group report on ‘Recommendations for ITER Experimental Operation, U.S. Team Formation and Participation’ was completed. Hubbard organized a series of highly popular web seminars for the burning plasma community, on a range of topics attracting a large number of participants from diverse institutions. Hubbard ended her term as Deputy Director in May, 2020. She subsequently received the Secretary of Energy’s Appreciation award for her service to USBPO. The second task supported the communications functions of the USBPO, led by Communications Coordinator, Mark London. Communications are critical for the effective operation of the USBPO, given it consists of members at many widely scattered institutions, and conducts its business almost entirely using remote tools. MIT has hosted and maintained the USBPO website, mailing lists, and discussion forums and provided member support, and videoconferencing support. MIT has continued this support following this grant, with funding incorporated into a broader Cooperative Agreement.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1963

PARTICIPATION OF THE SOLID PHASE IN THE OSCILLATORY BURNING OF SOLID ROCKET PROPELLANTS

An experimental study of the interaction between the solid and gas phases during oscillatory burning of solid propellants has been undertaken with the objective of exploring the validity of the complex theory describing the phenomenon. The apparatus employed was a side-vented, cylindrical vessel with an end-burning propellant grain closely fitted in one end and provision for maintaining the burning zone at a fixed position. Pressure oscillations both at the gas-zone end plate and beneath the grain were recorded. Energy dissipation in the solid propellant, isolated from other losses in the system, was determined from the growth rate constants of the amplitudes of pressure oscillation for grains of varying lengths. The efficiency of acoustical energy or absorption by the grain was found to be maximum when the oscillations are at frequencies close to the natural frequency of the grain. These results confirm the description of oscillatory burning by the acoustical theory in its broad generalizations.

GAS PHASE↗

NASA NTRS1963

AN AEROTHERMOCHENMCAL ANALYSIS OF EROSIVE BURNING OF SOLID PROPELLANT

In a solid propellant rocket of a side burning type, the flow rate of the hot combustion gases parallel to the burning surface is approximately proportional to the distance from the leading edge of the propellant. In the present paper, therefore, the erosive burning of the solid propellant is analyzed by tile boundary-layer approximation in aerothermochemistry for the case where the velocity, u ∞ , of the hot combustion gas stream outside the boundary layer increases linearly with the distance, x, from the leading edge of the propellant, i.e., u ∞ = Gx, and the effects of the hot gas stream on the burning rate of the propellant are examined.

GAS STREAM↗