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All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Human and Robotic Space Mission Use Cases for High-Performance Spaceflight Computing

Spaceflight computing is a key resource in NASA space missions and a core determining factor of spacecraft capability, with ripple effects throughout the spacecraft, end-to-end system, and mission. Onboard computing can be aptly viewed as a "technology multiplier" in that advances provide direct dramatic improvements in flight functions and capabilities across the NASA mission classes, and enable new flight capabilities and mission scenarios, increasing science and exploration return. Space-qualified computing technology, however, has not advanced significantly in well over ten years and the current state of the practice fails to meet the near- to mid-term needs of NASA missions. Recognizing this gap, the NASA Game Changing Development Program (GCDP), under the auspices of the NASA Space Technology Mission Directorate, commissioned a study on space-based computing needs, looking out 15-20 years. The study resulted in a recommendation to pursue high-performance spaceflight computing (HPSC) for next-generation missions, and a decision to partner with the Air Force Research Lab (AFRL) in this development.

use cases↗
NASA NTRS2014

IT Security Support for the Spaceport Command Control Systems Development Ground Support Development Operations

Security is one of the most if not the most important areas today. After the several attacks on the United States, security everywhere has heightened from airports to the communication among the military branches legionnaires. With advanced persistent threats (APT's) on the rise following Stuxnet, government branches and agencies are required, more than ever, to follow several standards, policies and procedures to reduce the likelihood of a breach. Attack vectors today are very advanced and are going to continue to get more and more advanced as security controls advance. This creates a need for networks and systems to be in an updated and secured state in a launch control system environment. FISMA is a law that is mandated by the government to follow when government agencies secure networks and devices. My role on this project is to ensure network devices and systems are in compliance with NIST, as outlined in FISMA. I will achieve this by providing assistance with security plan documentation and collection, system hardware and software inventory, malicious code and malware scanning, and configuration of network devices i.e. routers and IDS's/IPS's. In addition, I will be completing security assessments on software and hardware, vulnerability assessments and reporting, and conducting patch management and risk assessments. A guideline that will help with compliance with NIST is the SANS Top 20 Critical Controls. SANS Top 20 Critical Controls as well as numerous security tools, security software and the conduction of research will be used to successfully complete the tasks given to me. This will ensure compliance with FISMA and NIST, secure systems and a secured network. By the end of this project, I hope to have carried out the tasks stated above as well as gain an immense knowledge about compliance, security tools, networks and network devices, as well as policies and procedures.

security↗
NASA NTRS2015

Addressing Software Security

Historically security within organizations was thought of as an IT function (web sites/servers, email, workstation patching, etc.) Threat landscape has evolved (Script Kiddies, Hackers, Advanced Persistent Threat (APT), Nation States, etc.) Attack surface has expanded -Networks interconnected!! Some security posture factors Network Layer (Routers, Firewalls, etc.) Computer Network Defense (IPS/IDS, Sensors, Continuous Monitoring, etc.) Industrial Control Systems (ICS) Software Security (COTS, FOSS, Custom, etc.)

software↗
NASA NTRS2017

JWST NIRCam Time Series Observations

We explain how to make time-series observations with the Near-Infrared camera (NIRCam) science instrument of the James Webb Space Telescope. Both photometric and spectroscopic observations are described. We present the basic capabilities and performance of NIRCam and show examples of how to set its observing parameters using the Space Telescope Science Institute's Astronomer's Proposal Tool (APT).

science instruments↗
NASA NTRS2017

Parametric Evaluation of Interstellar Exploration Mission Concepts

One persistent difficulty in evaluating the myriad advanced propulsion concepts proposed over the last 60 years is a true apples to apples comparison of the expected gain in performance. This analysis is complicated by numerous factors including, multiple missions of interest to the advanced propulsion community, the lack of a credible closed form solution to 'medium thrust' trajectories, and lack of detailed design data for most proposed concepts that lend credibility to engine performance estimates. This paper describes a process on how to make fair comparisons of different propulsion concepts for multiple missions over a wide range of performance values. The figure below illustrates this process. This paper describes in detail the process and outlines the status so far in compiling the required data. Parametric data for several missions are calculated and plotted against specific power-specific impulse scatter plots of expected propulsion system performance. The overlay between required performance as defined by the trajectory parametrics and expected performance as defined in the literature for major categories of propulsion systems clearly defines which propulsion systems are the most apt for a given mission. The application of the Buckingham Pi theorem to general parameters for interstellar exploration ( mission time, mass, specific impulse, specific power, distance, propulsion source energy/mass, etc.) yields a number of dimensionless variables. The relationships of these variables can then be explored before application to a particular mission. Like in the fields of fluid mechanics and heat transfer, the use of the Buckingham Pi theorem results in new variables to make apples to apples comparisons.

Adams, Robert B.↗
NASA NTRS2016

Microstructural and Creep Properties of Boron- and Zirconium-Containing Cobalt-Based Superalloys

The effects of micro-additions of boron and zirconium on grain-boundary (GB) structure and strength inpolycrystalline γ(f.c.c.) plus γ’(L12) strengthened Co-9.5Al-7.5W-X at. % alloys (X=0-Ternary, 0.05B, 0.01B,0.05Zr, and 0.005B-0.05Zr at. %) are studied. Creep tests performed at 850 °C demonstrate that GB strength and cohesion limit the creep resistance and ductility of the ternary B- and Zr-free alloy due to intergranular fracture. Alloys with 0.05B and 0.005B-0.05Zr both exhibit improved creep strength due to enhanced GB cohesion,compared to the baseline ternary Co-9.5Al-7.5W alloy, but alloys containing 0.01B or 0.05Zr additions displayed no benefit. Atom-probe tomography (APT) is utilized to measure GB segregation, where B and Zr are demonstrated to segregate at GBs. A Gibbsian interfacial excess of 5.57 ± 1.04 atoms nm(exp) -2 was found for B at aGB in the 0.01B alloy and 2.88 ± 0.81 and 2.40 ± 0.84 atoms nm2 for B and Zr, respectively, for the 0.005B-0.05Zr alloy. The GBs in the highest B-containing (0.05B) alloy exhibit micrometer-sized boride precipitates with adjacent precipitate denuded-zones (PDZs), whereas secondary precipitation at the GBs is absent in theother four alloys. The 0.05B alloy has the smallest room temperature yield strength, by 6%, which is attributedto the PDZs, but it exhibits the largest increase in creep strength (with an ~2.5 order of magnitude decrease inthe minimum strain rate for a given stress at 850 °C) over the baseline Co-9.5Al-7.5W alloy.

Creep↗
NASA NTRS2020

Autonomous Assessment and Predictive Capabilities for Low-Altitude Urban Flight Operations

The integration of unmanned aerial vehicles in the national airspace will introduce new vehicle types, technologies, and operational paradigms for which safety must be maintained and hazards mitigated. One approach is to attempt to design for possible hazards and unsafe incidents that can occur at different phases of flight (pre-flight, in-flight, and post-flight) and during ground operations. Another is to mitigate safety incidents by implementing changes to policies, procedures, regulations, and design to cover personnel, equipment, and aircraft during operations. These and other techniques, not described herein, are typically conservative or adhoc in that they reduce the likelihood of risk after safety incidents have occurred. In this work, the goal is to develop a more predictive capability to monitor and mitigate risk and hazards to safety “in-time” enough for decisions to be made. In line with NASA’s Aeronautics Mission Directorate Strategic Thrust 5 [1] (In-Time System-Wide Safety Assurance), the System-Wide Safety (SWS) project under which this work falls, is developing and demonstrating innovative and safety-oriented solutions that enable modernization and aviation transformation. To that effect, this work will detail data-driven efforts on the SWS project to develop a number of safety-critical services for in-time monitoring and mitigation of hazards to low-altitude flight operations. First, hazards to these operations are identified based on previous work by NASA [2,3] and others in the aerospace industry. These hazards include (i) unsafe proximity to other vehicles, property, and people on the ground, (ii) critical system failures such as communication signal/GPS loss, unexpected propulsion system degradation, engine/power failure, and (iii) operational/environmental issues such as severe weather and gusty winds. For these hazards, safety metrics, which can be quantified and assessed are defined, models to monitor and predict them are developed, and flight test data is generated to develop, validate, and test these models, considering the complex interplay of the different hazards that define them [4-6]. In addition, the uncertainty in the non-deterministic effects that cannot be modeled nor predicted and unknown unknowns that arise after design/testing and during operations must be handled in rigorous manner. As a result, for each of the developed safety metrics, their dependencies on one another are characterized and a framework for handling the uncertainties inherent in the modeling, algorithms, and measurements required for prediction is also developed [7]. To that effect, this presentation will describe the safety metrics and services already developed and underway under the System-Wide Safety project that utilize data-driven techniques for the identification of anomalies, precursors, and trends (APTs) to monitor and mitigate hazards to safety, in-time, for urban flight operations in low-altitude airspace.

Okolo, Wendy A.↗
NASA NTRSDate not supplied

Standardizing Algorithm Documentation For Improved Scientific Data Understanding: The Algorithm Publication Tool Prototype

Algorithm Theoretical Basis Documents (ATBDs) are documents which accompany Earth observation data products generated from algorithms. While ATBDs are essential to scientific reproducibility, these key documents are not standardized and are often difficult to find. In this paper, we present the prototype Algorithm Publication Tool (APT), a cloud-based ATBD authoring and editing tool for NASA’s Earth science data systems. A standardized ATBD information model is also described as well as lessons learned from developing the prototype tool.

Kaylin Bugbee↗
NASA NTRSDate not supplied

Weather Guidance for UAS Urban Medical Transport Missions

Unmanned aircraft will revolutionize healthcare services by providing efficient and expeditious delivery of life-saving transplant organs and supplies to hospitals in urban environments, where road traffic and congestion can slow delivery times and endanger lives. Bell has developed the Autonomous Pod Transport (APT) vehicle to serve this market, with entry into service in mid-2020s. Adverse weather conditions can introduce risks and inefficiencies in urban environments leading to flight delays and cancellations. In 2018, National Aeronautics and Space Administration (NASA) and Bell entered into a cooperative agreement, under the Systems Integration and Operationalization (SIO) program to tackle key challenges to enable future commercial unmanned aircraft operations. The Center for Collaborative Adaptive Sensing of the Atmosphere (CASA) at the University of Massachusetts, Amherst, joined this team to demonstrate weather avoidance technologies for remotely piloted and autonomous vehicles. CASA has developed the ‘City Warn’ hazard alerting platform to gather weather information from various weather sensors and models, and based on user (or mission) preferences for alerting and on user (or unmanned aircraft) locations, the platform shares timely weather intelligence with users and the systems used by them for remote operations. This presentation discusses the weather avoidance solution developed during this project, leading up to the demonstration of the end-to-end system in Fall 2020. The presentation will cover the following topics: 1) goals related to weather avoidance 2) the design requirements process, including the results of pilot interviews, 3) weather observation and avoidance needs 4) selection of regional and national weather data sets 5) design of the weather graphical interface and 6) considerations for real-time weather alerting. The end-to-end system that was developed will be discussed, along with the results from the demonstration flight. The presentation will conclude with insights from the project team on lessons learned and best practices on weather avoidance technologies for the industry going ahead.

weather avoidance↗
NASA NTRS2021

Weather Guidance for UAS Urban Medical Transport Missions

Unmanned aircraft will revolutionize healthcare services by providing efficient and expeditious delivery of life-saving transplant organs and supplies to hospitals in urban environments, where road traffic and congestion can slow delivery times and endanger lives. Bell has developed the Autonomous Pod Transport (APT) vehicle to serve this market, with entry into service in mid-2020s. Adverse weather conditions can introduce risks and inefficiencies in urban environments leading to flight delays and cancellations. In 2018, National Aeronautics and Space Administration (NASA) and Bell entered into a cooperative agreement, under the Systems Integration and Operationalization (SIO) program to tackle key challenges to enable future commercial unmanned aircraft operations. The Center for Collaborative Adaptive Sensing of the Atmosphere (CASA) at the University of Massachusetts, Amherst, joined this team to demonstrate weather avoidance technologies for remotely piloted and autonomous vehicles. CASA has developed the ‘City Warn’ hazard alerting platform to gather weather information from various weather sensors and models, and based on user (or mission) preferences for alerting and on user (or unmanned aircraft) locations, the platform shares timely weather intelligence with users and the systems used by them for remote operations. This presentation discusses the weather avoidance solution developed during this project, leading up to the demonstration of the end-to-end system in Fall 2020. The presentation will cover the following topics: 1) goals related to weather avoidance 2) the design requirements process, including the results of pilot interviews, 3) weather observation and avoidance needs 4) selection of regional and national weather data sets 5) design of the weather graphical interface and 6) considerations for real-time weather alerting. The end-to-end system that was developed will be discussed, along with the results from the demonstration flight. The presentation will conclude with insights from the project team on lessons learned and best practices on weather avoidance technologies for the industry going ahead.

weather avoidance↗
NASA NTRS2021

Terra and Aqua MODIS Thermal Emissive Bands Calibration and RVS Stability Assessments Using an In Situ Ocean Target

MODIS, whose openly-public data have been used for over two decades to monitor and address global issues, has 16 Thermal Emissive Bands (TEBs) with central wavelengths that range from 3.7 μm to 14.4 μm, and are calibrated on-orbit using observations from its on-board blackbody. In order to maintain MODIS’ rich, well-calibrated archive of multispectral imagery and data, Earth targets are regularly used to track its long-term stability, as well as the consistency between the two sensors onboard the Terra and Aqua satellites. Moreover, these scenes can be used to compare MODIS Earth view data over the complete scan-angle range and evaluate the on-orbit performance of the TEBs response-versus-scan-angle (RVS) over mission lifetime. This manuscript focuses on evaluating the MODIS TEBs Collection (C6.1) radiometric calibration stability for both instruments using an in situ ocean target as reference (hereafter referred to as in situ sea surface temperature (SST)). Furthermore, it will assess the calibration consistency between the MODIS sensors. Lastly, it will analyze the on-orbit RVS stability for Terra and Aqua MODIS. Only cloud-free, nighttime MODIS TEB retrievals were used for the study. A normalization methodology is applied to standardize the MODIS data to the in situ SST. Additionally, spectral corrections were derived between some of the Terra and Aqua MODIS TEBs by using a combination of the MODIS Atmospheric Profile product and MODerate resolution atmospheric TRANsmission (MODTRAN) simulations. Results indicate that most MODIS TEBs exhibit mission-long trends of ±0.50 K – with Terra band 30 presenting the largest downward drift due to residual electronic cross-talk effects. Moreover, the calibration consistency analysis over a warm ocean target demonstrated that the average Terra-to-Aqua MODIS bias for most bands is well within ±0.50 K (bands 27 and 30 show the largest - electronic crosstalk-related - biases). Lastly, the MODIS TEBs RVS trends display changes of ±0.50 K (except for bands 25 and 27 at the end-of-scan angles) for both instruments. Overall, the MODIS TEBs remain well-calibrated and their RVSs aptly-characterized.

MODIS↗
NASA NTRS2022

Application of Compressive Sensing for Gravitational Microlensing Events

Compressive sensing is a novel mathematical technique for simultaneous data acquisition and compression. This technique is particularly apt for time-series photometric measurements. In this work we apply compressive sensing to time-series photometric measurements specifically obtained due to gravitational microlensing events. We show through simulation modelling the error sensitivity for detecting microlensing event parameters. Particularly, we show the relation of the amount of error and its impact on the microlensing parameters of interest. We derive statistical error bounds to apply those as a baseline for analyzing the effectiveness of compressive sensing application. Our results conclude that for single and binary microlensing events we can obtain error less than 1% over a 3-pixel radius of the center of the microlensing star by using 25% Nyquist rate measurements.

Compressive Sensing↗
NASA NTRS2022

Simultaneous Retrieval of Selected Optical Water Quality Indicators From Landsat-8, Sentinel-2, and Sentinel-3

Constructing multi-source satellite-derived water quality (WQ) products in inland and nearshore coastal waters from the past, present, and future missions is a long-standing challenge. Despite inherent differences in sensors’ spectral capability, spatial sampling, and radiometric performance, research efforts focused on formulating, implementing, and validating universal WQ algorithms continue to evolve. This research extends a recently developed machine-learning (ML) model, i.e., Mixture Density Networks (MDNs) (Pahlevan et al., 2020; Smith et al., 2021), to the inverse problem of simultaneously retrieving WQ indicators, including chlorophyll-a (Chla), Total Suspended Solids (TSS), and the absorption by Colored Dissolved Organic Matter at 440 nm (a cdom (440)), across a wide array of aquatic ecosystems. We use a database of in situ measurements to train and optimize MDN models developed for the relevant spectral measurements (400–800 nm) of the Operational Land Imager (OLI), MultiSpectral Instrument (MSI), and Ocean and Land Color Instrument (OLCI) aboard the Landsat-8, Sentinel-2, and Sentinel-3 missions, respectively. Our two performance assessment approaches, namely hold-out and leave-one-out, suggest significant, albeit varying degrees of improvements with respect to second-best algorithms, depending on the sensor and WQ indicator (e.g., 68%, 75%, 117% improvements based on the hold-out method for Chla, TSS, and a cdom (440), respectively from MSI-like spectra). Using these two assessment methods, we provide theoretical upper and lower bounds on model performance when evaluating similar and/or out-of-sample datasets. To evaluate multi-mission product consistency across broad spatial scales, map products are demonstrated for three near-concurrent OLI, MSI, and OLCI acquisitions. Overall, estimated TSS and a cdom (440) from these three missions are consistent within the uncertainty of the model, but Chla maps from MSI and OLCI achieve greater accuracy than those from OLI. By applying two different atmospheric correction processors to OLI and MSI images, we also conduct matchup analyses to quantify the sensitivity of the MDN model and best-practice algorithms to uncertainties in reflectance products. Our model is less or equally sensitive to these uncertainties compared to other algorithms. Recognizing their uncertainties, MDN models can be applied as a global algorithm to enable harmonized retrievals of Chla, TSS, and a cdom (440) in various aquatic ecosystems from multi-source satellite imagery. Local and/or regional ML models tuned with an apt data distribution (e.g., a subset of our dataset) should nevertheless be expected to outperform our global model.

Machine learning↗
NASA NTRS2022

What's in a Name? On the Use and Significance of the Term “Polar Vortex”

Mainstream and popular science media are rife with misunderstandings about what a “polar vortex” is. The term most aptly describes the stratospheric polar vortex, a single feature dominating the cool-season circulation from ∼15–50 km. Regional jet stream variations dominate the tropospheric circulation, which is not well-described as a polar vortex; indeed, there is no single consistent definition of a tropospheric polar vortex in the literature. Stratospheric polar vortex disturbances profoundly influence extreme weather events, including cold air outbreaks (CAOs). How the stratospheric polar vortex affects tropospheric jets, whose local excursions drive CAOs, is not fully understood. Public facing parts of publications describing research on this topic are not always clear about how the “polar vortex” is defined; greater clarity could improve communications both within the community and with non-specialist audiences.

Stratospheric Polar Vortex↗
NASA NTRS2023

Orion Cabin Lighting System: Filter Workaround for Maintaining Crew Circadian Entrainment

Introduction: Suboptimal crew circadian entrainment (CCE) is common and results in cumulative fatigue and reduced cognitive function. This may promote use of psychostimulants and hypnotics. The Orion Cabin Lighting System (OCLS) consists of 15 dimmable lamps circuited to several zones. The OCLS monochromatic white lamp design is insufficient for maintaining CCE. While blue light (480-nm) elicits peak wake-cycle response, it is a powerful disruptor of CCE. We propose OCLS lamp filters (OLFs) as a workaround for maintaining CCE. Methods: Preliminary OLFs testing utilized a tunable-white LED to serve as a baseline lamp in the NASA Lighting Lab’s controlled environment (prototype OCLS lamps were unavailable). Illuminance and spectral irradiances were measured with the NASA Lighting Lab’s spectroradiometer. ConOps is proposed for OLFs. Results: OLFs markedly attenuated 480-nm light and illumination with minimal mass/volume requirements. ConOps includes in-flight deployment of OLFs and reducing OCLS lamp intensity prior to bedtime. Pros: minimal mass/volume, no added power, and a simplistic design. Cons: manual twice-daily articulation of OLFs, undetermined frangibility/flammability/off-gassing and effects on thermal regulation, and untested task illumination or color fidelity in the Orion cabin. Discussion: While OLFs aptly attenuate 480-nm light from our tunable LED lamp in the Lighting Lab’s controlled environment, they remain untested within the Orion cabin on OCLS lamps. Future tests include Orion cabin illumination optimization for appropriate Lux delivery and ensuring task/color fidelity with OLFs deployed. Adequate OCLS cooling should be similarly assessed. Other safety testing includes OLF frangibility/flammability/off-gassing in an enriched-O 2 /hypobaric environment. Together, these data will demonstrate OLFs provide a viable workaround for maintaining CCE further ensuring mission safety and success.

Carlos Rene Dostal↗
NASA NTRS2023

Parameterization of Features on Spherical Surfaces

NASA’s Planetary Systems Laboratory (PSL) at the Goddard Spaceflight Center in Greenbelt, Maryland is tasked with the study of solar system objects. This work is frequently based on analysis of imagery from visiting spacecraft, orbiting telescopes, and ground-based sensors. A consequence of this mission is the need to characterize features on the spherical surface of planets and moons, such characterization including the overall area of the feature, its center, its moments of inertia, its perimeter, its compactness, its major axis, its bounding box, its aspect ratio and its North-South orientation. Accurate assessment of these measures from a “flat” two-dimensional image is a challenge, since the scale of distance observed at the center of a spherical object distorts in any direction towards the horizon. PSL has developed a technique to guarantee accurate and automated measurement at any point on the visible surface, by overlaying an imaginary grid of equal-area cells onto the two-dimensional image of the sphere. The technique is named Grid-Oriented Normalization for Analysis of Spherical Areas (GONASA). This paper discusses the construction of the normalization grid and describes specific algorithms for feature parameterization. The algorithms are implemented in an accompanying Excel spreadsheet, both for clarity and ease of adoption, and to emphasize their aptness for automation. Finally, a concrete use case is offered where the GONASA grid and algorithms are used to characterize methane clouds on the Saturnian moon Titan.

Planetary science↗
NASA NTRSDate not supplied

Quantative Measurements of Trace Elements and Three-Dimensional Atomic Scale Characterisation of Presolar O-rich Oxides and Silicates: An Atom Probe Tomography Approach

Presolar grains are recordsof a single moment in stellar evolution which have survived nebula and parent body processingwithin our Solar System. These grains condensed within a range of stellar envi-ronments including asymptotic giant branch stars, red giant branch stars, nova, supernova (SN) and hydrogen burning electron capture supernova(ECSN)[1,2]. Iso-topic and chemical compositions can be used to unravel details about environmental conditions at the time of their condensation and physical and chemical processes occurring at the time. For example,nucleosynthesis, stellar evolution, physical properties of stellar atmos-pheres, mixing from inner core to outer envelope, galac-tic chemical evolution, interstellar medium and parent body processing.NanoSIMS enables detailed characterisation of iso-topic compositions and rapid in situidentification of O-rich presolar oxides and silicates using their character-istic 17O/16O and 18O/16O isotopic ratios.Spectroscopic techniques e.g., auger spectroscopyand transmission electron microscopy, have provided additional details on major and minor chemical signatures. However, due tospatial resolution limitations,interaction volumes and interferencesfrom surrounding grains for in situtech-niques, attaining quantative characterisation of trace el-ements,hasproved challenging[1,3]. As the most sensitive geochemical tracers of envi-ronmental changes, trace elements are essential to un-ravelling the geochemical record of their parent stellar environments and evolutionary pathways[4].We car-ried out correlated in situisotopic and chemical analyses of 13 presolar grains to better understand stellar evolu-tion. In this work, we achieved this using a custom ap-proach, coordinating NanoSIMS, Scanning Electron Microscopy Energy Dispersive X-Ray Spectroscopy (SEM-EDX)and Atom Probe Tomography(APT).Our objective was to develop an approach which could ena-ble precise targeting of presolar grains for atom probe tomography and successfully execute atomic scale anal-yses of presolar oxides and silicates, to achieve quantative analysis of their trace elements for the first time.We also aimed to test the capability for Atom Probe tomography to measure isotopic compositions and stoichiometries of presolar oxide and silicate grains.

N D Nevill↗
NASA NTRSDate not supplied

4.32 Billion Year Old Impact Melts at Apollo 14: Dating the Procellarum Basin?

Introduction: Recent work has improved our understanding of lunar crustal structure and basin evolution on the Moon, but its early impact history and implications for solar system dynamics remain poorly established [1,2]. In particular, there is a derth of absolute ages, especially for the period >4.0 Ga, that could be related to basin-forming events. Here we present U-Pb isotopic data for Zr-rich minerals found in impact-melt fragments from Apollo 14 soil sample 14163 that, when combined with previously published data, dates an impact event at 4324±15 Ma. The compositions and ages of these impact-melt fragments provide unique information about the timing of early impact events and the composition of the lunar crust. Results: Fourteen rocklets ranging in size from 1 to 3 mm were extracted from soil 14163. Most are impactmelt rocks with 10-30% clasts of mostly pyroxene and plagioclase (100 to 500 μm) in a crystalline matrix. Textures of the matrix vary from subophitic, formed by intergrowths of 10-20 μm plagioclase and pyroxene crystals, to poikilitic, with plagioclase and pyroxene reaching 20-50 μm size. Some fragments that contain no visible clasts have similar textures are also interpreted as impact-melt rocks. All fragments contain notably large proportions of euhedral to subhedral ilmenite, zircon, apatite/merrillite and less abundant zirconolite and baddeleyite in the melt matrices. These grains often form intricate intergrowths with each other and rock-forming minerals, indicating their crystallization from the melt (Fig. 1). However, some slightly larger (~50 μm) zircon and phosphate grains can be interpreted as relict clasts based on their granular textures and relationships with the surrounding phases (Fig. 1). This implies that zircon and phosphate minerals were present in the target rocks. Some of these grains were profoundly remelted during the impact, which resulted in an oversaturation of the melt in Zr and P and crystallization of new grains of Zrrich minerals and phosphates during melt solidification. The presence of zircon and phosphates indicates that the melts were significantly enriched in KREEP components and ties their provenance to the Procellarum- KREEP Terrane (PKT) [3]. Combined U-Pb zircon data obtained for all fragments form two main clusters on a concordia diagram (Fig. 2), between about 4.3 and 3.9 Ga. Phosphate data mostly concentrate on the younger end of this age range but some analyses are almost as old as the older zircon grains (Fig. 2). Figure 1: Zircon (Zr) and phosphate (Apt; Mer) grains in impact melt fragments from Apollo 14 soil 14161. A-zircon grains crystallized from impact melt; B-phosphate grain inherited from the target; C- granular zircon grains Our interpretation of these data is that all U-rich minerals experienced variable resetting of the U-Pb system, with phosphate, where closure temperature is significantly lower than that in zircon, affected more profoundly by Pb loss than zircon. Our best estimate of the time of formation of zircon and phosphate is based on statistically valid analysis of grains interpreted texturally as grown from the impact melt (Fig. 2). Ten of these analyses define an age of 4324±15 Ma (MSWD=3.0, probability of fit P=0.002). Our best estimate for the time of resetting is obtained by combining data from phosphates that are statistically indistinguishable from 3.9 Ga within the analytical uncertainties. This group is represented by 18 analyses of 15 phosphate grains from different fragments (Fig. 2) and defines an age of 3922±6 Ma (MSWD=1.2, P=0.23). Conversely, a minimum age of the target lithologies, remelted in the impact that produced the rocklets studied here (Fig. 2), can be determined from the five oldest analyses of zircon clasts at 4338±13 Ma (MSWD=1.5, P=0.2), which is indistinguishable from the age of the impact melt within the uncertainties. The obtained ages, combined with textural evidence, imply that the impact melt was formed at 4324±15 Ma, and that it occurred in a zircon-rich target with a minimum age of 4338±13 Ma. Further reworking occurred during a second impact event at 3922±6 Ma. Discussion: The younger age of 3922±6 Ma can be interpreted as the time of the Imbrium impact. The older age of 4324±15 Ma would then be the time of formation of the impact melt, which was then caught in the Imbrium ejecta either at the Apollo 14 landing site or within the target rocks of the Imbrium impact. The presence of abundant accessory phases such as zircons and phosphates is consistent with a substantial KREEP component in the analyzed particles. The current distribution of KREEP on the lunar surface appears to be strongly influenced by Imbrum ejecta [4] so interpretation of the 4.32 Ga age depends in part on assumed structure of the pre-impact crust and distribution of KREEP within the crust. If KREEP was present only in the deep crust at 4.32 Ga, then a basin-scale impact possibly analogous to Imbrium or larger may be necessary to excavate a KREEPy impact melt at this time. However, if KREEPy materials were present closer to the surface perhaps due to redistribution related to Mg-suite magmatism, then smaller impacts might be able to rework KREEPy compositions at shallower depths. The coherence of the data on the particles analysed here suggests a large volume of melt that has been preserved since 4.32 Ga, consistent with a large impact event. Relict zircons and mineral clasts suggests that the igneous crust in the vicinity of this impact was well developed by at least 4.34 Ga, similar to the model age of KREEP and older than the isochron ages of many Mg-suite cumulates [5]. A problem that confronts all lunar sample studies using the current collection is that the pre-Imbrium geology of the PKT (the source of these 4.32 Ga impact melts) is not well constrained. The South Pole-Aitken basin contains regions that are moderately enriched in Th, but its ejecta is Th-poor [6]; therefore these A14 fragments are probably not SPA ejecta. Alternatively, these fragments may represent formation of a hypothesized Procellarum basin [7] although the lack of a clearly defined basin ejecta signature is a potential problem with that interpretation. In any case, they provide a younger limit on the age of lunar differentiation and formation of KREEP within the lunar crust. Figure 2: U-Pb data for zircon and phosphate grains from impact melt fragments. A-all data; B-data used for age calculations. References: [1] Orgel C., Michael G., Fassett C. I., van der Bogert C. H., Riedel C., Kneissl T., and Hiesinger H. (2018) J. Geophys. Res. Planets 123, 748- 762. [2] Evans A. J., Andrews-Hanna J. C., Head J. W., Soderblom J. M., Solomon S. C., and Zuber M. T. (2018) J. Geophys. Planets. 123, 1596-1617. [3] Jolliff, B.L., Gillis, J.J., Haskin, L.A., Korotev, R.L. and Wieczorek, M.A. (2000) J. Geophys. Res: Planets 105, 4197-4216. [4] Haskin L. A. (1998) J. Geophys. Res. Planets 103, 1679-1689. [5] Borg L.E., Gaffney A.M., and Shearer C.K. (2015) MAPS 50, 715-732. [6] Moriarty, D.P., Watkins, R.N., Valencia, S.N., Kendall, J.D., Evans, A.J., Dygert, N. and Petro, N.E. (2021) J. Geophys. Res. Planets 126. [7] Zhu, M.H., Wünnemann, K., Potter, R.W., Kleine, T. and Morbidelli, A. (2019) J. Geophys. Res: Planets 124, 2117-2140

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