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DOE OSTI · 3683986

Navigating Large Chemical Spaces Using Graph Theory and Integer Programming

Abstract

Navigating and analyzing large chemical spaces are necessary to accelerate the design and discovery of new molecules and chemical processes. In this work, we introduce a computational framework that integrates graph theory and integer programming to enable the efficient navigation of large chemical spaces. Our framework represents the chemical space as a graph, wherein nodes represent molecules and edges represent the degree of similarity or connectivity based on domain-specific information. Using the graph representation, we identify representative molecules by computing the so-called minimum dominating set (MDS), which in our context is the minimum set of molecules that is connected to all other molecules. We present a suite of solution strategies for the MDS problem including heuristic and rigorous integer programming (IP) approaches. We show that these approaches allow us to capture physicochemical properties and domain-specific logic and constraints, facilitating the identification of molecules with the target properties. We demonstrate the effectiveness of the proposed approach by navigating the chemical space of per- and polyfluoroalkyl substances (PFAS); this comprises approximately 15,000 molecular structures. We compare our framework against traditional dimensionality reduction and clustering methods such as t-SNE and K-means clustering.

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BibTeXRIS

Ikegwu, Ugochukwu M. [University of Wisconsin─Madison, WI (United States)] (ORCID:0000000298068067), Van Lehn, Reid C. [University of Wisconsin─Madison, WI (United States)] (ORCID:0000000348856599), Zavala, Victor M. [University of Wisconsin─Madison, WI (United States)] (ORCID:0000000257447378). 2026-09-07. Navigating Large Chemical Spaces Using Graph Theory and Integer Programming. https://doi.org/10.1021/acs.jcim.6c01810

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