Engineering PapersSearch

DOE OSTI · 3676772

Landmark Publications in Analytical Atomic Spectrometry: Fundamentals and Instrumentation Development

Abstract

The almost-two-centuries history of spectrochemical analysis has generated a body of literature so vast that it has become nearly intractable for experts, much less for those wishing to enter the field. Authoritative, focused reviews help to address this problem but become so granular that the overall directions of the field are lost. This broader perspective can be provided partially by general overviews but then the thinking, experimental details, theoretical underpinnings, and instrumental innovations of the original work must be sacrificed. In the present compilation, this dilemma is overcome by assembling the most impactful publications in the area of analytical atomic spectrometry. Each entry was proposed by at least one current expert in the field and supported by a narrative that justifies its inclusion. The entries were then assembled into a coherent sequence and returned to contributors for a round-robin review. A total of 48 scientists participated in this endeavor, contributing a combined list of 1055 individual articles spanning 17 sub-disciplines of spectrochemical analysis into what the current community views as “key” publications. Of these cited articles, 60 received nominations from four or more scientists, establishing them as the most indispensable reading materials. The outcome of this collaborative effort is intended to serve as a valuable resource not only for current practitioners in atomic spectroscopy but also for present and future students who represent coming generations of analytical atomic spectroscopists.

Explore related subjects

Keep this discovery

BibTeXRIS

Chan, George, Hieftje, Gary, Omenetto, Nicoló, Axner, Ove, Bengtson, Arne, Bings, Nicolas, Blades, Michael, Bogaerts, Annemie, Bolshov, Mikhail, Broekaert, José, Chan, WingTat, Costa-Fernández, José, Crouch, Stanley, De Giacomo, Alessandro, D’Ulivo, Alessandro, Engelhard, Carsten, Falk, Heinz, Farnsworth, Paul, Florek, Stefan, Gamez, Gerardo, Gornushkin, Igor, Günther, Detlef, Hahn, David, Hang, Wei, Hoffmann, Volker, Jakubowski, Norbert, Karanassios, Vassili, Koppenaal, David, Marcus, R., Noll, Reinhard, Olesik, John, Palleschi, Vincenzo, Panne, Ulrich, Pisonero, Jorge, Ray, Steven, Resano, Martín, Russo, Richard, Scheeline, Alexander, Smith, Benjamin, Sturgeon, Ralph, Todolí, José-Luis, Tognoni, Elisabetta, Vanhaecke, Frank, Webb, Michael, Winefordner, James, Yang, Lu, Yu, Jin, Zhang, Zhanxia. 2024-06-16. Landmark Publications in Analytical Atomic Spectrometry: Fundamentals and Instrumentation Development. https://doi.org/10.1177/00037028241263567

Cite the original work for its findings. Save a collection to share your selection of sources.

Discover connections

Connections use source metadata and explicit phrase matches, not verified experimental comparisons.

KEEP EXPLORING

Related reports

Advanced Non-Intrusive Instrumentation for Propulsion Engines

Changes in engine technology such as higher temperatures, higher tip speeds, new metal/composite/ceramic materials together with radical changes in design philosophy will require amongst other prerequisites the ability to measure and to monitor key internal gas and structural characteristics. The symposium papers presented non-intrusive measurement and analysis technologies in the following categories: Laser Point Measurements (11); Absorption and Infrared Techniques (4); Paints - Surface Sensors (6); Laser Induced Fluorescence (6); Mechanical (7); Films (5); Laser Planar Measurement (9); and a Keynote Address.

Propulsion

Autonomous Detection and Classification of Lunar Minerals Using a Convolutional Neural Network Based Framework for the SUCR DALI Project

NASA’s long-term goal is to deploy humans to the Moon and, from there, advance human exploration to Mars, with Artemis missions as pivotal milestones. Raman spectroscopy can uniquely identify minerals, compounds, water states, and other materials, providing distinctive fingerprints for classification. A Raman instrument has been successfully deployed and utilized on the Mars surface via the Perseverance rover, but has not yet been utilized at the lunar surface The SUCR DALI project is working towards developing a Raman spectroscopy instrument to be applied in various lunar mission concepts, including within the Artemis program. The objective of my research is to assist in the maturation of the proposed SUCR DALI lunar Raman instrument through the development of an autonomous detection and classification model capable of identifying minerals and water states on the Moon’s surface.

Convolutional Neural Networks

Passive Confirmation of the Presence Of High-Explosive Material Via Neutron Transmission Spectroscopy

The goal of this project was to explore a novel approach for identifying presence and potential types of high explosives (HE) in treaty-controlled items with passive neutron sources by using passive neutron transmission spectroscopy. We predominantly look to measure relative elemental abundance of Carbon, Hydrogen, Oxygen, and Nitrogen (CHON) since most relevant materials are certain mix of these elements, as shown in Table 1. Previously, most studies exploring potential identification of CHON elemental content of targets in the vicinity of passive neutron source were focused solely on gamma spectroscopy using high resolution gamma detectors. Using neutron transmission spectroscopy with pulse-shape discrimination (PSD) capable organic scintillators is not only a novel idea in of itself, but arguably necessary for accurate identification of the CHON elemental content of an interrogated target. While high resolution gamma spectroscopy in principle can determine a presence of hydrogen and nitrogen, it is effectively blind to a quantitatively measuring areal densities of C, O. The initially proposed approach, described in detail in the project proposal, was to leverage previous Monte Carlo study on neutron transmission spectroscopy using slab shaped target interrogated with well-collimated (“pencil”) neutron beam. In this study, a simulated test CO 2 target was interrogated by a pencil neutron beam and transmitted neutron spectra were measured using PSD capable organic scintillator using MLEM based unfolding technique. To establish relative elemental content of carbon and oxygen, the unfolded neutron spectrum was fit with a parametrized combination of their respective elemental spectral templates. The individual spectral template was calculated by convoluting ENDF neutron crosssection with the known resolution of the PSD detector used in the study. This approach in the studied configuration successfully quantitatively established relative elemental composition of carbon and oxygen.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND