DOE OSTI · 3532188
Reduced salen in a monomeric Fe complex
Abstract
We report the first monomeric formally M I transition metal salen complex without ion pairing. A combination of spectroscopy, crystallography, and computations indicates that reduction of an Fe II salen complex gives substantial reduced ligand character. We also present a computational method for accurately predicting 57 Fe Mössbauer parameters of Fe salen complexes.
Keep this discovery
Explore connections, maps & timelines
Feldman, Dana M. [Yale University, New Haven, CT (United States)] (ORCID:0009000827396574), Suhr, Simon C. B. [Yale University, New Haven, CT (United States)] (ORCID:0009000301300427), Gerard, Theodore J. [Yale University, New Haven, CT (United States)] (ORCID:0000000216331731), Krajewski, Sebastian M. [Yale University, New Haven, CT (United States)] (ORCID:0000000297552375), Holland, Patrick L. [Yale University, New Haven, CT (United States)] (ORCID:0000000228832031). 2026-01-01. Reduced salen in a monomeric Fe complex. https://doi.org/10.1039/d6cc03437c
Cite the original work for its findings. Save a collection to share your selection of sources.