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DOE OSTI · 3517103

Invisible water in subducted crust: Lawsonite velocity anomalies under mantle conditions

Abstract

Subduction zones transport significant amounts of water into Earth’s mantle, primarily through hydrous minerals such as lawsonite. However, the seismic detectability of lawsonite-bearing oceanic crust at mantle depths remains uncertain. To address this issue, we measured sound velocities of lawsonite up to 7.4 GPa and 600 °C. Both P- and S-wave velocities exhibited unexpected increases with temperature under high-pressure conditions. Our result suggest that hydrous oceanic crust exhibits higher seismic velocities than the surrounding mantle at depths of 150 to 250 km, resulting in high-velocity anomalies rather than the previously assumed low-velocity anomalies. Furthermore, the seismic velocity difference between hydrous and dry oceanic crust is less than 2%, making it challenging to distinguish between them using seismic velocities. This limitation may hinder the detection of the hydration state in subducted crust. In addition, lawsonite remains stable in 90% of subduction zones, and thus, such “seismically invisible water” may exist in most subducted slabs around the world.

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Chen, Sibo [Stony Brook University, NY (United States); Arizona State University, Tempe, AZ (United States)] (ORCID:000000020300108X), Wang, Siheng [Stony Brook University, NY (United States)] (ORCID:0000000342541430), Qi, Xintong [Stony Brook University, NY (United States)], Xu, Man [University of Chicago, IL (United States)], Yu, Tony [University of Chicago, IL (United States)], Wang, Yanbin [University of Chicago, IL (United States)], Li, Baosheng [Stony Brook University, NY (United States)] (ORCID:0000000179828262). 2025-12-05. Invisible water in subducted crust: Lawsonite velocity anomalies under mantle conditions. https://doi.org/10.1073/pnas.2506548122

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