DOE OSTI · 3014224
Advanced PEM Electrolyzer Membrane for Hydrogen Crossover Mitigation
Abstract
An unintended reaction in the electrochemical conversion of water to hydrogen in proton exchange membrane (PEM) electrolyzers is the crossover of hydrogen from the anode to the oxygen-containing cathode through the membrane, creating hydrogen losses and safety concerns. Efforts to date have focused on embedding platinum catalysts in perfluorosulfonic (PFSA) membranes to convert H 2 to protons. The objective of this project is to design and develop hydrocarbon (HC) proton exchange membranes (PEMs) that can help overcome the risk of high H 2 crossover in current PEM electrolyzer (ELX) stacks by designing and optimizing the gas recombination catalyst (GRC) within the membrane and membrane electrode assembly (MEA) structure.
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Yang, Fan [Plug Power Inc., Latham, NY (United States)] (ORCID:0000000298000206), Sun, Qiang [Plug Power Inc., Latham, NY (United States)]. 2026-01-26. Advanced PEM Electrolyzer Membrane for Hydrogen Crossover Mitigation. https://doi.org/10.2172/3014224
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