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DOE OSTI · 3002379

Enhancing The Thermal Resistivity of Rigid Polyisocyanurate Foam Insulation

Abstract

The development of rigid polyurethane foam insulation has garnered considerable attention because of its promising applications in the buildings and construction industry. Its low thermal conductivity makes it an attractive choice for improving energy performance in buildings. Current Rigid Polyurethane foams have thermal resistivity (R-value/in.) 5.5 to 6.5 h.ft2F/BTU/in.· that could be further improved by diminishing the heat transfer through the foam matrix. Nevertheless, minimizing both conduction (through gas and solid) and radiation simultaneously in porous solids is a significant challenge due to the trade-off between these two mechanisms. This study focuses on improving the R-value of the insulation foams via several strategies: such as type and the amount of the surfactants, blowing agent content and precooling and premixing polyol mixture. These methods optimized thermal properties of the PIR foams, achieving R/in. as high as 8.3. This excellent R/in. is anticipated to be a critical factor in significantly advancing the thermal insulation performance of rigid polyurethane cellular foams, thereby enhancing their efficacy in energy-efficient building applications.

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Wanasinghe Mudiyanselage Pahala Gedara, Shiwanka Vidarshi Wanasinghe [ORNL], Tamraparni, Achutha [ORNL] (ORCID:0000000299658544), Shrestha, Som [ORNL] (ORCID:0000000183993797), Demchuk, Zoriana [ORNL] (ORCID:0000000326292235), Feng, Tianli [The University of Utah], Hun, Diana E [ORNL] (ORCID:0000000164746002). 2025-10-01. Enhancing The Thermal Resistivity of Rigid Polyisocyanurate Foam Insulation. https://www.osti.gov/biblio/3002379

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