Metal decoration of Si particles via high-energy milling for lithium-ion battery anodes

Araño, Khryslyn G. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA]; Armstrong, Beth L. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA]; Sacci, Robert L. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA] (ORCID:0000000200735221); Chambers, Matthew S. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA] (ORCID:0000000278939603); Jiang, Chun-Sheng [Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401, USA] (ORCID:0000000302307500); Quinn, Joseph [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99354, USA]; Meyer, Harry M. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA]; Tomich, Anton W. [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439-4837, USA]; Musgrove, Amanda [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA]; Lam, Steven [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA]; Toups, Elena [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA]; Wang, Chongmin [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99354, USA] (ORCID:0000000333270958); Johnson, Christopher S. [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439-4837, USA] (ORCID:0000000343576889); Veith, Gabriel M. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA] (ORCID:0000000251864461)

doi:10.1039/d4lf00393d

DOE OSTI · 2510922

Metal decoration of Si particles via high-energy milling for lithium-ion battery anodes

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Abstract

We demonstrate an approach to lower desolvation energy and increase rate performance through the introduction of a metal to the silicon surface.

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25 ENERGY STORAGE lithium-ion batteries silicon anodes zeta potential

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Araño, Khryslyn G. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA], Armstrong, Beth L. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA], Sacci, Robert L. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA] (ORCID:0000000200735221), Chambers, Matthew S. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA] (ORCID:0000000278939603), Jiang, Chun-Sheng [Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401, USA] (ORCID:0000000302307500), Quinn, Joseph [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99354, USA], Meyer, Harry M. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA], Tomich, Anton W. [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439-4837, USA], Musgrove, Amanda [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA], Lam, Steven [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA], Toups, Elena [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA], Wang, Chongmin [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99354, USA] (ORCID:0000000333270958), Johnson, Christopher S. [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439-4837, USA] (ORCID:0000000343576889), Veith, Gabriel M. [Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA] (ORCID:0000000251864461). 2025-05-14. Metal decoration of Si particles via high-energy milling for lithium-ion battery anodes. https://doi.org/10.1039/d4lf00393d

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