Predicting EBW detonator failure using DSC data

Abstract

Exploding bridgewire detonators (EBWs) containing pentaerythritol tetranitrate (PETN) exposed to high temperatures may not function following discharge of the design electrical firing signal from a charged capacitor. Knowing functionality of these arbitrarily facing EBWs is crucial when making safety assessments of detonators in accidental fires. Orientation effects are only significant when the PETN is partially melted. Here, the melting temperature can be measured with a differential scanning calorimeter. Nonmelting EBWs will be fully functional provided the detonator never exceeds 406 K (133 °C) for at least 1 h. Conversely, EBWs will not be functional once the average input pellet temperature exceeds 414 K (141 °C) for a least 1 min which is long enough to cause the PETN input pellet to completely melt. Functionality of the EBWs at temperatures between 406 and 414 K will depend on orientation and can be predicted using a stratification model for downward facing detonators but is more complex for arbitrary orientations. A conservative rule of thumb would be to assume that the EBWs are fully functional unless the PETN input pellet has completely melted.