Catalytic Porphyrin Framework Compounds

Feng, Liang; Wang, Kun-Yu; Joseph, Elizabeth; Zhou, Hong-Cai

doi:10.1016/j.trechm.2020.01.003

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DOE OSTI · 1801401

Catalytic Porphyrin Framework Compounds

Feng, Liang·Wang, Kun-Yu·Joseph, Elizabeth·Zhou, Hong-Cai

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Abstract

Porphyrins are frequently observed in nature and play a vital role in many biological functions, including light-harvesting, oxygen transport, and catalytic transformations. The rigid, robust, and multifunctional features of porphyrins enable the construction of framework compounds such as metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) for use in several important applications. This short review here summarizes the types of porphyrin building blocks with varying connectivity, their assembly into framework compounds, and key structural factors governing porphyrin ligand design. Furthermore, we highlight emerging catalytic applications of these porphyrin framework compounds as Lewis acid catalysts, oxidation catalysts, photocatalysts, and electrocatalysts. Together, this review supplies a timely update on porphyrin ligand design and framework compound synthesis and guides the future development of porphyrin framework compounds with diverse functionalities for efficient catalysis.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Chemistry Covalent-organic frameworks Heterogeneous catalysis Metal-organic frameworks Porphyrin Structures Synthesis

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Feng, Liang, Wang, Kun-Yu, Joseph, Elizabeth, Zhou, Hong-Cai. 2020-02-08. Catalytic Porphyrin Framework Compounds. https://doi.org/10.1016/j.trechm.2020.01.003

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