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DOE OSTI · 1758446

Materials Data on Cd(BrO2)2 by Materials Project

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Abstract

Cd(O2Br)2 crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. Cd is bonded in a distorted linear geometry to two equivalent O and four equivalent Br atoms. Both Cd–O bond lengths are 2.16 Å. All Cd–Br bond lengths are 2.97 Å. There are two inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to two equivalent O and one Br atom. Both O–O bond lengths are 1.94 Å. The O–Br bond length is 1.97 Å. In the second O site, O is bonded in a 2-coordinate geometry to one Cd, two equivalent O, and one Br atom. The O–Br bond length is 2.13 Å. Br is bonded in a 2-coordinate geometry to two equivalent Cd and two O atoms.

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36 MATERIALS SCIENCEBr-Cd-OCd(BrO2)2crystal structure

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2020-09-03. Materials Data on Cd(BrO2)2 by Materials Project. https://doi.org/10.17188/1758446

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