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DOE OSTI · 1743881

Materials Data on Te10Rh7 by Materials Project

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Abstract

Rh7Te10 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are seven inequivalent Rh sites. In the first Rh site, Rh is bonded to six Te atoms to form a mixture of edge and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 48–55°. There are a spread of Rh–Te bond distances ranging from 2.63–2.72 Å. In the second Rh site, Rh is bonded to six Te atoms to form a mixture of distorted edge, face, and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 47–56°. There are a spread of Rh–Te bond distances ranging from 2.63–2.76 Å. In the third Rh site, Rh is bonded to six Te atoms to form a mixture of distorted edge, face, and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 48–55°. There are a spread of Rh–Te bond distances ranging from 2.62–2.77 Å. In the fourth Rh site, Rh is bonded to six Te atoms to form a mixture of distorted edge, face, and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 48–55°. There are a spread of Rh–Te bond distances ranging from 2.63–2.78 Å. In the fifth Rh site, Rh is bonded to six Te atoms to form a mixture of distorted edge, face, and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 48–56°. There are a spread of Rh–Te bond distances ranging from 2.62–2.81 Å. In the sixth Rh site, Rh is bonded to six Te atoms to form a mixture of distorted edge, face, and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 47–56°. There are a spread of Rh–Te bond distances ranging from 2.71–2.74 Å. In the seventh Rh site, Rh is bonded to six Te atoms to form a mixture of distorted edge, face, and corner-sharing RhTe6 octahedra. The corner-sharing octahedra tilt angles range from 48–56°. There are a spread of Rh–Te bond distances ranging from 2.71–2.74 Å. There are ten inequivalent Te sites. In the first Te site, Te is bonded to four Rh atoms to form a mixture of distorted edge and corner-sharing TeRh4 trigonal pyramids. In the second Te site, Te is bonded in a distorted rectangular see-saw-like geometry to four Rh atoms. In the third Te site, Te is bonded in a distorted rectangular see-saw-like geometry to four Rh atoms. In the fourth Te site, Te is bonded to four Rh atoms to form a mixture of distorted edge and corner-sharing TeRh4 trigonal pyramids. In the fifth Te site, Te is bonded in a 3-coordinate geometry to three Rh atoms. In the sixth Te site, Te is bonded in a 5-coordinate geometry to five Rh atoms. In the seventh Te site, Te is bonded to four Rh atoms to form a mixture of distorted edge and corner-sharing TeRh4 trigonal pyramids. In the eighth Te site, Te is bonded to four Rh atoms to form a mixture of distorted edge and corner-sharing TeRh4 trigonal pyramids. In the ninth Te site, Te is bonded in a 5-coordinate geometry to five Rh atoms. In the tenth Te site, Te is bonded in a 5-coordinate geometry to five Rh atoms.

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36 MATERIALS SCIENCEcrystal structureRh-TeTe10Rh7

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2020-04-30. Materials Data on Te10Rh7 by Materials Project. https://doi.org/10.17188/1743881

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36 MATERIALS SCIENCE↗