Materials Data on Eu3Pd2 by Materials Project

Abstract

Eu3Pd2 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are three inequivalent Eu sites. In the first Eu site, Eu is bonded in an octahedral geometry to six equivalent Pd atoms. All Eu–Pd bond lengths are 3.17 Å. In the second Eu site, Eu is bonded in a 6-coordinate geometry to six equivalent Pd atoms. There are three shorter (3.05 Å) and three longer (3.22 Å) Eu–Pd bond lengths. In the third Eu site, Eu is bonded in a 5-coordinate geometry to five equivalent Pd atoms. There are a spread of Eu–Pd bond distances ranging from 3.08–3.58 Å. Pd is bonded in a 9-coordinate geometry to eight Eu and one Pd atom. The Pd–Pd bond length is 2.95 Å.