Materials Data on SN by Materials Project

Abstract

NS crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 1,3,5,7,2,4,6,8-tetrathiatetrazocane molecules. there are three inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a bent 150 degrees geometry to two equivalent S1- atoms. Both N–S bond lengths are 1.59 Å. In the second N1+ site, N1+ is bonded in a bent 150 degrees geometry to two equivalent S1- atoms. Both N–S bond lengths are 1.60 Å. In the third N1+ site, N1+ is bonded in a bent 150 degrees geometry to two S1- atoms. There is one shorter (1.59 Å) and one longer (1.60 Å) N–S bond length. There are two inequivalent S1- sites. In the first S1- site, S1- is bonded in a bent 120 degrees geometry to two N1+ atoms. In the second S1- site, S1- is bonded in a bent 120 degrees geometry to two N1+ atoms.