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DOE OSTI · 1688024

Materials Data on VCl4 by Materials Project

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Abstract

VCl4 is Silicon tetrafluoride-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four vanadium(iv) chloride molecules. V4+ is bonded in a tetrahedral geometry to four Cl1- atoms. All V–Cl bond lengths are 2.14 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom.

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36 MATERIALS SCIENCECl-Vcrystal structureVCl4

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2020-05-02. Materials Data on VCl4 by Materials Project. https://doi.org/10.17188/1688024

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