Materials Data on TbPPd by Materials Project

Abstract

TbPdP crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Tb is bonded in a 11-coordinate geometry to six equivalent Pd and five equivalent P atoms. There are a spread of Tb–Pd bond distances ranging from 3.02–3.27 Å. There are a spread of Tb–P bond distances ranging from 2.86–2.93 Å. Pd is bonded in a 12-coordinate geometry to six equivalent Tb, two equivalent Pd, and four equivalent P atoms. Both Pd–Pd bond lengths are 3.06 Å. There are three shorter (2.56 Å) and one longer (2.80 Å) Pd–P bond lengths. P is bonded in a 9-coordinate geometry to five equivalent Tb and four equivalent Pd atoms.