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DOE OSTI · 1675836

Materials Data on BSbO3 by Materials Project

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Abstract

BSbO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. B3+ is bonded to six equivalent O2- atoms to form BO6 octahedra that share corners with six equivalent BO6 octahedra and faces with eight equivalent SbO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All B–O bond lengths are 1.76 Å. Sb3+ is bonded to twelve equivalent O2- atoms to form SbO12 cuboctahedra that share corners with twelve equivalent SbO12 cuboctahedra, faces with six equivalent SbO12 cuboctahedra, and faces with eight equivalent BO6 octahedra. All Sb–O bond lengths are 2.49 Å. O2- is bonded in a distorted linear geometry to two equivalent B3+ and four equivalent Sb3+ atoms.

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36 MATERIALS SCIENCEB-O-SbBSbO3crystal structure

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2020-05-02. Materials Data on BSbO3 by Materials Project. https://doi.org/10.17188/1675836

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