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DOE OSTI · 1663175

AMPP Newsletter (Sep 2020)

Mondragon, Krystal L.
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Abstract

I am excited to introduce the third 2020 issue of Actinide Materials Processing and Power Division’s quarterly newsletter, with a focus on “excellence in mission operations.” Excellence in mission operations requires the execution of sustained operations that are reliable and responsive to mission needs across all work being performed in AMPP. For all of us, adherence to Conduct of Operations principles and strong work planning and execution is essential to achieving a safe and productive environment that enables overall excellence. Since the beginning of the COVID-19 pandemic response, you have all shown how AMPP has a division exemplifies this focus area. Highlights of our outstanding operational work under the threat of COVID-19 have been featured in our weekly newsletters.

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36 MATERIALS SCIENCE

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Mondragon, Krystal L.. 2020-08-01. AMPP Newsletter (Sep 2020). https://doi.org/10.2172/1663175

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DOE OSTI2026

Cyclic moisture reactivation of calcium sorbents for long duration thermochemical energy storage

The transition to a flexible and reliable energy infrastructure, using electro-thermal energy generation technologies such as geothermal, concentrated solar power, and nuclear, usually demands simultaneous advancement of thermal energy storage (TES) to support on-demand electricity generation and industrial applications while mitigating the inherent intermittency of renewable energy sources and power outages from direct energy generation. Among TES technologies, thermochemical energy storage (TCES) based on calcium looping emerges as a compelling high-power energy storage candidate due to its high reaction enthalpy, compatibility with elevated operating temperatures, and abundance of low-cost materials. However, the long-term durability of calcium-based sorbents for TCES is hindered by surface sintering and particle aggregation, leading to performance degradation over repeated thermal cycles. This study explores a moisture hydration-based strategy to regenerate a degraded calcium sorbent and mitigate performance degradation for long duration TCES. The addition of moisture transforms calcium oxide into calcium hydroxide and produces intercalation water layers, associated with a regenerated surface area and reduced calcium oxide crystallite size. Both these effects are beneficial in restoring the sorbents' reactivity for carbonization. Additionally, an optimized hydration-assisted reactivation protocol balances the recovered energy storage capacity with heating penalty required for moisture removal from hydrated samples, resulting in an enhanced energy storage capacity up to 176% compared to benchmark sorbents that undergo cycling without reactivation after 60 cycles. In conclusion, these results highlight the potential of hydration-assisted reactivation to enhance the long-term performance of TCES, providing an effective pathway to advancing electro-thermal storage technologies.

36 MATERIALS SCIENCE↗