Developing Novel Electrode Materials for Aqueous Battery

Abstract

Aqueous rechargeable batteries (ARBs) are particularly interesting for large-scale energy storage due to their inherent safety, superior rate capability and environmental friendliness. However, ARBs are not widely explored as yet, so we proposed designing, preparing, and testing new intercalation materials for ARBs. Development of these electrodes will enrich the electrode chemistry of existing ARBs, open up new avenues for high-performance electrode and system design, offer opportunities to improve energy efficiency of water purification, and inform future development of controls strategies and management systems for stationary aqueous energy storage. Researchers from Bosch and LBNL collaborated on relevant materials to pursue and the general design of experiments to implement. Bosch researchers prepared and fabricated the electrodes and used various characterization facilities at LBNL to evaluate electrode performance in-device. The research collaboration resulted in identifying electrode materials capable of Na + and Ca 2+ intercalation in aqueous systems, and their application for desalination was explored using testing platform available at LBNL. Besides the specific materials and their performance, the data collected during the study was also used to inform a broader techno-economic analysis to compare intercalation-desalination technique to commercially available capacitive desalination approach. Outcomes of this research effort will be published in peer-reviewed journals.