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DOE OSTI · 1355628

Materials Data on CeBi2SeO4 by Materials Project

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Abstract

CeBi2SeO4 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Ce4+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Ce–O bond lengths are 2.38 Å. Bi3+ is bonded in a 4-coordinate geometry to four equivalent Se2- and four equivalent O2- atoms. All Bi–Se bond lengths are 3.32 Å. All Bi–O bond lengths are 2.33 Å. Se2- is bonded in a distorted body-centered cubic geometry to eight equivalent Bi3+ atoms. O2- is bonded to two equivalent Ce4+ and two equivalent Bi3+ atoms to form a mixture of edge and corner-sharing OCe2Bi2 tetrahedra.

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36 MATERIALS SCIENCEBi-Ce-O-SeCeBi2SeO4crystal structure

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2020-07-23. Materials Data on CeBi2SeO4 by Materials Project. https://doi.org/10.17188/1355628

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